(η5-C5H5)Ru(II)(PPh3)(η1-dppm)I

Base Information

• Chemical Name: (η5-C5H5)Ru(II)(PPh3)(η1-dppm)I
• CAS No.: 677725-92-7
• Molecular Formula: C₄₈H₄₂IP₃Ru
• Molecular Weight: 939.757
• Mol file: 677725-92-7.mol

Synonyms:

Chemical Property of (η5-C5H5)Ru(II)(PPh3)(η1-dppm)I

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-C5H5)Ru(II)(PPh3)(η1-dppm)I

There total 1 articles about (η5-C5H5)Ru(II)(PPh3)(η1-dppm)I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[ruthenium(II)I(η5-C5H5)(P(C6H5)3)2] (34692-10-9) + bis-diphenylphosphinomethane (2071-20-7) → (η5-C5H5)Ru(II)(PPh3)(η1-dppm)I (677725-92-7)

Guidance literature:

In benzene; standard Schlenk-vac. techniques; Ru complex and ligand (molar ratio 1:1.06) dissolved in benzene; heated to 65°C; stirred for 6 h; cooled to room temp.; filtered; ppt. collected;

DOI:10.1039/b307990b

Reference yield: 90.0%

copper(l) iodide (7681-65-4) + (η5-C5H5)Ru(II)(PPh3)(η1-dppm)I (677725-92-7) → (η5-C5H5)(PPh3)Ru(II)(μ-I)(μ-dppm)Cu(I)I

Guidance literature:

In dichloromethane; standard Schlenk-vac. techniques; Ru complex and CuI (molar ratio 1:5) dissolved in CH2Cl2; stirred at room temp. overnight; filtrate condenced under vac.; pentane added; filtered (medium swivel frit); solid washed with pentane; dried under vac.; elem. anal.;

DOI:10.1039/b307990b

Reference yield: 90.0%

(1,5-cylooctadiene)di-iodoplatinum(II) (12266-72-7) + (η5-C5H5)Ru(II)(PPh3)(η1-dppm)I (677725-92-7) → (η5-C5H5)(PPh3)Ru(II)(μ-I)(μ-dppm)Pt(II)I2 (677725-85-8)

Guidance literature:

In dichloromethane; standard Schlenk-vac. techniques; Ru complex and Pt complex (molar ratio1:1) dissolved in CH2Cl2; stirred at room temp. overnight; condenced under vac.; pentane added; filtered (medium swivel frit); solid washed with hexanes; dried under vac.; recrystd. from CH2Cl2-pentane; elem. anal.;

DOI:10.1039/b307990b

upstream raw materials:

[ruthenium(II)I(η5-C5H5)(P(C6H5)3)2]

bis-diphenylphosphinomethane

Downstream raw materials:

(η5-C5H5)(PPh3)Ru(II)(μ-I)(μ-dppm)Pd(II)Cl2

(η5-C5H5)(PPh3)Ru(II)(μ-I)(μ-dppm)Pt(II)Cl2

(η5-C5H5)(PPh3)Ru(II)(μ-I)(μ-dppm)Pt(II)I2