2,2-dimethoxynorbornane

Base Information

• Chemical Name: 2,2-dimethoxynorbornane
• CAS No.: 10395-51-4
• Molecular Formula: C9H16 O2
• Molecular Weight: 156.225
• Hs Code.: 2911000000
• Mol file: 10395-51-4.mol

Synonyms:2-Norbornanone,dimethyl acetal (7CI,8CI); Norbornane, 2,2-dimethoxy- (8CI);2,2-Dimethoxynorbornane; 2-Norbornanone dimethyl ketal; Norbornanone dimethylketal; Norcamphor dimethyl ketal

Chemical Property of 2,2-dimethoxynorbornane

Chemical Property:

• Vapor Pressure: 1.14mmHg at 25°C
• Boiling Point: 181.8°Cat760mmHg
• Flash Point: 53.1°C
• PSA: 18.46000
• Density: 1.01g/cm³
• LogP: 1.79550

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2-dimethoxynorbornane

There total 9 articles about 2,2-dimethoxynorbornane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

methanol (67-56-1) + endo-methyl N-bicyclo[2.2.1]-2-heptyl-carbamate (86709-30-0) → norcamphor dimethyl ketal (10395-51-4)

Guidance literature:

With tetraethylammonium tosylate; electrolysis (10 F/mol, 0.5 A);

DOI:10.1021/jo00167a039

Reference yield:

norborn-2-ene (498-66-8) → 2,2-dimethoxybicyclo<2.2.1>heptane (10395-51-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 21.0 g / N-bromosuccinimide / H₂O / Ambient temperature

3: chromic acid

4: p-toluenesulfonic acid / methanol / Heating

With N-Bromosuccinimide; chromic acid; toluene-4-sulfonic acid; In methanol; water;

DOI:10.1021/jo00289a051

Reference yield:

Norborneol (497-36-9,497-37-0) → 2,2-dimethoxybicyclo<2.2.1>heptane (10395-51-4)

Guidance literature:

Multi-step reaction with 2 steps

1: chromic acid

2: p-toluenesulfonic acid / methanol / Heating

With chromic acid; toluene-4-sulfonic acid; In methanol;

DOI:10.1021/jo00289a051

upstream raw materials:

Norbornan-2-on

exo-3-methylnorboranone ketal

endo-3-methylnorboranone ketal

trimethyl orthoformate

Downstream raw materials:

methanol

Norbornan-2-on

2-methoxybicyclo<2.2.1>hept-2-ene