methyl (R)-(-)-2-acetyloxy-2-phenylacetate

Base Information

Chemical Name:methyl (R)-(-)-2-acetyloxy-2-phenylacetate
CAS No.:82078-97-5
Molecular Formula:C₁₁H₁₂O₄
Molecular Weight:208.214
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (R)-(-)-2-acetyloxy-2-phenylacetate

Chemical Property:

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Technology Process of methyl (R)-(-)-2-acetyloxy-2-phenylacetate

There total 20 articles about methyl (R)-(-)-2-acetyloxy-2-phenylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 86561-27-5
methyl O-acetylmandalate

: 21210-43-5
(S)-Methyl mandelate

: 79416-45-8
(+)-methyl (S)-α-acetoxyphenylacetate

: 947-94-4,79416-45-8,86561-27-5,82078-97-5
methyl (R)-(-)-2-acetyloxy-2-phenylacetate

Guidance literature:: With AmanoPS lipase; water; In Petroleum ether; benzene; at 25 ℃; for 144h; Yields of byproduct given; pH 7.0 (aq. sodium phosphate buffer); further solvents and period of time;

Reference yield:

: 108-05-4,9003-20-7
vinyl acetate

: 4358-87-6
(RS)-methyl mandelate

: 20698-91-3
(R)-methyl mandelate

: 79416-45-8
(+)-methyl (S)-α-acetoxyphenylacetate

: 947-94-4,79416-45-8,86561-27-5,82078-97-5
methyl (R)-(-)-2-acetyloxy-2-phenylacetate

Guidance literature:: With Burkholderia cepacia lipase; In tert-butyl methyl ether; at 20 ℃; for 36h; enantioselective reaction; Enzymatic reaction;
DOI:10.1002/ejoc.201700161

Reference yield:

: 868532-34-7
acetic acid 2-oxo-1-phenyl-2-(2-thioxo-oxazolidin-3-yl)-ethyl ester

: 67-56-1
methanol

: Acetic acid (R)-2-oxo-1-phenyl-2-(2-thioxo-oxazolidin-3-yl)-ethyl ester

: Acetic acid (S)-2-oxo-1-phenyl-2-(2-thioxo-oxazolidin-3-yl)-ethyl ester

: 79416-45-8
(+)-methyl (S)-α-acetoxyphenylacetate

: 947-94-4,79416-45-8,86561-27-5,82078-97-5
methyl (R)-(-)-2-acetyloxy-2-phenylacetate

Guidance literature:: With (1R)-1-{2-[(1S)-1-(NMe₂)ethyl]phenyl}-2,2,2-trifluoroethanol; In toluene; at 0 ℃; for 67h; Title compound not separated from byproducts;
DOI:10.1021/ja053743z