diphenylmercury

Base Information

• Chemical Name: diphenylmercury
• CAS No.: 1337-09-3
• Molecular Formula: C₁₂H₁₀Hg
• Molecular Weight: 354.801
• Mol file: 1337-09-3.mol

Synonyms:

Chemical Property of diphenylmercury

Chemical Property:

Purity/Quality:

Safty Information:

• Hazard Codes: T+:Very toxic
• Statements: R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed.; R33:Danger of cumulative effects.; R50
• Safety Statements: S13:Keep away from food, drink and animal foodstuffs.; S28:After contact with skin, wash immediately with plenty of soap-

MSDS Files:

Useful:

Technology Process of diphenylmercury

There total 119 articles about diphenylmercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

phenyltrifluorosilane (368-47-8) → diphenylmercury(II) (587-85-9,1337-09-3)

Guidance literature:

With mercury(II) oxide; In benzene; byproducts: F3SiOSiF3; addn. of trifluorophenylsilane to a suspn. of HgO in dry benzene, reacting at 25°C for 2 h, pptn.;

DOI:10.1016/0022-328X(88)89077-6

Reference yield: 91.0%

lithium tris(pentafluoroethyl)silylthiolate + phenylmercury(II) chloride (100-56-1) → C12H5F15HgSSi + diphenylmercury(II) (587-85-9,1337-09-3)

Guidance literature:

In diethyl ether; at 20 ℃;

DOI:10.1021/acs.inorgchem.1c02476

Reference yield: 85.0%

phenylmagnesium bromide (100-58-3) → bromo(phenyl)mercury (1192-89-8) + diphenylmercury(II) (587-85-9,1337-09-3) + phenylmercury(II) chloride (100-56-1)

Guidance literature:

With mercury dichloride; In diethyl ether; at 60°C;;

upstream raw materials:

diazomethane

diethyl ether

phenylmercury(II) chloride

bromobenzene

Downstream raw materials:

di-p-chlorophenylmercury

diphenyl sulphone

triphenylmethane

1-phenyl-2-p-tolyl-1H-arsinin-4-one

Refernces

• 1、 Glidewell, Christopher,Low, John N.,Wardell, James L.. "Diphenylmercury, redetermined at 120 K: Sheets built from a single C - H...π(arene) hydrogen bond". . p. m107-m108. Retrieved 2005.
• 2、 Guseva,Antina,Berezin,V'yugin. "Influence of metal cation on chromophore properties of complexes of some d metals with α,α-dipyrrolylmethene". . p. 1282 - 1285. Retrieved 2004.
• 3、 D?ring, Manfred,Hahn, Gabriela,Stoll, Michael,Wolski, Alexander C.. "Symmetrization of phenylmercuric hydroxides by the action of nickel(II) and cobalt(II) acetylacetonates. Isolation and structural characterization of an intermediate in this reaction". . p. 1879 - 1883. Retrieved 1997.
• 4、 Nicholson, Brian K.,Whitton, Alan J.. "PREPARATION AND X-RAY STRUCTURE OF BIS(PHENYLMERCURIC)OXONIUM TETRAFLUOROBORATE HYDRATE, *H2O". . p. 139 - 144. Retrieved 1986.
• 5、 Tiessen, Natalia,Schwarze, Nico,Stammler, Hans-Georg,Neumann, Beate,Hoge, Berthold. "Salts of Tris(pentafluoroethyl)silylchalcogenolates [Si(C2F5)3E]-with e = S, Se, and Te: Synthesis, Structure, and Reactivity". supporting information. p. 15112 - 15117. Retrieved 2021/10/20.