Allyloxy(diethylene oxide), Methyl ether, tech-95

Base Information

• Chemical Name: Allyloxy(diethylene oxide), Methyl ether, tech-95
• CAS No.: 13752-97-1
• Molecular Formula: C8H16O3
• Molecular Weight: 160.213
• Mol file: 13752-97-1.mol

Synonyms:1-Propene,3-[2-(2-methoxyethoxy)ethoxy];diethylene glycol allyl methyl ether;1-Allyloxy-2-(2'-methoxyethoxy)-ethane;4,7,10-undec-1-ene;3-[2-(2-Methoxyethoxy)ethoxy]-1-propene;3-<2-(2-Methoxyethoxy)ethoxy>propen;3-(2-(2-methoxyethoxy)-ethoxy)-propene;4,7,10-trioxaundec-1-ene;

Chemical Property of Allyloxy(diethylene oxide), Methyl ether, tech-95

Chemical Property:

• Boiling Point: 86 °C(Press: 15 Torr)
• PSA: 27.69000
• Density: 0.916±0.06 g/cm3(Predicted)
• LogP: 0.85200

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Allyloxy(diethylene oxide), Methyl ether, tech-95

There total 2 articles about Allyloxy(diethylene oxide), Methyl ether, tech-95 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2-(2-methoxyethoxy)ethyl alcohol (111-77-3,95507-80-5) + allyl bromide (106-95-6) → 3-<2-(2-Methoxyethoxy)ethoxy>propen (13752-97-1,27252-80-8)

Guidance literature:

With potassium hydroxide; at 60 ℃; for 3h;

DOI:10.1016/0022-328X(92)85025-R

Reference yield:

oxirane (75-21-8,99932-75-9) + methanol (67-56-1) + N-nitroso-N-cyclopropylurea (10575-90-3) → methylallylether (627-40-7) + monoethylene glycol methyl allyl ether (18854-48-3,27252-80-8) + cyclopropyl methyl ether (540-47-6) + 3-<2-(2-Methoxyethoxy)ethoxy>propen (13752-97-1,27252-80-8) + (2-Methoxyethoxy)cyclopropan

Guidance literature:

With sodium hydrogencarbonate; Product distribution; Ambient temperature; var. conc., further reactions with NaOCH₃, oxetane, tetrahydrofuran;

Reference yield: 95.0%

trimethoxysilane (2487-90-3) + 3-<2-(2-Methoxyethoxy)ethoxy>propen (13752-97-1,27252-80-8) → [3-[2-(2-methoxyethoxy)ethoxy]propyl]-trimethoxysilane (124087-62-3,190185-71-8,205044-13-9)

Guidance literature:

With ruthenium(II)(2,5-norbornadiene)Cl₂; In neat (no solvent); at 60 ℃; for 1h; Reagent/catalyst; Catalytic behavior; Inert atmosphere;

DOI:10.1016/j.tetlet.2019.151086

upstream raw materials:

oxirane

methanol

N-nitroso-N-cyclopropylurea

2-(2-methoxyethoxy)ethyl alcohol

Downstream raw materials:

Bis-{3-[2-(2-methoxy-ethoxy)-ethoxy]-propyl}-phenyl-phosphane

{3-[2-(2-Methoxy-ethoxy)-ethoxy]-propyl}-diphenyl-phosphane

2-(2-methoxyethoxy)ethyl alcohol

C₁₆H₃₆O₅Si