(1,10-phenanthroline) rhenium tricarbonyl PPh₂

Base Information

Chemical Name:(1,10-phenanthroline) rhenium tricarbonyl PPh₂
CAS No.:431875-06-8
Molecular Formula:C₂₇H₁₈N₂O₃PRe
Molecular Weight:635.632
Hs Code.:

(1,10-phenanthroline) rhenium tricarbonyl PPh<sub>2</sub>

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Chemical Property of (1,10-phenanthroline) rhenium tricarbonyl PPh₂

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Technology Process of (1,10-phenanthroline) rhenium tricarbonyl PPh₂

There total 1 articles about (1,10-phenanthroline) rhenium tricarbonyl PPh₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 431874-98-5
fac-tricarbonyl(1,10-phenanthroline)(4-methylphenylamido)rhenium(I)

: 829-85-6
diphenylphosphane

: 431875-06-8
tricarbonyl(1,10-phenanthroline)(diphenylphosphido)rhenium(I)

Guidance literature:: In tetrahydrofuran; byproducts: 4-CH3C6H4NH2; under N2, standard Schlenk techniques; ligand (1.1 equiv.) added to soln. of Re complex in THF; stirred at room temp. for 30 min; solvent removed under vac.; washed with hexane; elem. anal.;
DOI:10.1021/om0110383

Reference yield: 81.0%

: 431875-06-8
(1,10-phenanthroline) rhenium tricarbonyl PPh₂

: 922-67-8
propynoic acid methyl ester

: 847025-60-9
(C₁₂H₈N₂CCO₂MeCHPPh₂) rhenium tricarbonyl

Guidance literature:: In tetrahydrofuran; ligand added to Re complex in THF, stirred for 5 min; pptd.(hexane), dissolved (CH2Cl2), filtered (alumina), concd.(vac.), crystd.(hexane, -20°C), elem. anal.;
DOI:10.1039/b412447b

Reference yield: 81.0%

: 75-09-2
dichloromethane

: 431875-06-8
(1,10-phenanthroline) rhenium tricarbonyl PPh₂

: 762-42-5
dimethyl acetylenedicarboxylate

: [Re(CO)3((C₆H₅)2PC(CO₂CH₃)C(CO₂CH₃)NC₅H₃CHCHC₅H₃N)]*0.5CH₂Cl₂

Guidance literature:: In tetrahydrofuran; alkyne (1 equiv.) was added to soln. of Re complex (1 equiv.) in THF; solvent removed (vac.); redissolved in CH2Cl2; filtered through alumina;concd.; layered with hexane; stored at -20°C; elem. anal.;
DOI:10.1021/om049019r