[Ru(xantphos)(CO)3]

Base Information

• Chemical Name: [Ru(xantphos)(CO)3]
• CAS No.: 1129491-65-1
• Molecular Formula: C₄₂H₃₂O₄P₂Ru
• Molecular Weight: 763.731
• Mol file: 1129491-65-1.mol

Synonyms:

Chemical Property of [Ru(xantphos)(CO)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(xantphos)(CO)3]

There total 2 articles about [Ru(xantphos)(CO)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + carbon monoxide (201230-82-2) + 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (161265-03-8) → [Ru(xantphos)(CO)3] (1129491-65-1)

Guidance literature:

In toluene; High Pressure; soln. Ru complex and xantphos in toluene was heated under CO atm. at 100°C for 72 h in stainless-steel autoclave; soln. was cooled to room temp., pressure released, solvent was removed, residue was recrystd. from benzene-hexane; elem. anal.;

DOI:10.1039/b813543f

Reference yield:

[Ru(xantphos)(PPh3)(CO)H2] + benzaldehyde (100-52-7) → [Ru(xantphos)(CO)3] (1129491-65-1) + [Ru(xantphos)(CO)2(Ph)H] (1129491-45-7) + [Ru(xantphos)(PPh3)(CO)2] (1129491-44-6)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: benzaldehyde, benzene; 120°C, 2 h; identified by NMR;

DOI:10.1039/b813543f

Reference yield: 76.0%

[Ru(xantphos)(CO)3] (1129491-65-1) + hydrogen (1333-74-0) → [Ru(xantphos)(CO)2H2]

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); soln. Ru complex in THF was photolysed (300 W Xe arc) at 0°C under H2 flow for 0.5 h; solvent was removed in vacuo, residue was washed with EtOH and hexane and recrystd. from THF-EtOH; elem. anal.;

DOI:10.1039/b813543f

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

carbon monoxide

4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

benzaldehyde