1-Methyl-4-[2-(4-methylphenoxy)ethoxy]benzene

Base Information

• Chemical Name: 1-Methyl-4-[2-(4-methylphenoxy)ethoxy]benzene
• CAS No.: 15149-11-8
• Molecular Formula: C16H18 O2
• Molecular Weight: 242.318
• European Community (EC) Number: 653-244-0
• NSC Number: 128059
• DSSTox Substance ID: DTXSID30299081
• Wikidata: Q82041270
• Mol file: 15149-11-8.mol

Synonyms:15149-11-8;1-methyl-4-[2-(4-methylphenoxy)ethoxy]benzene;1,1'-[ethane-1,2-diylbis(oxy)]bis(4-methylbenzene);1,2-bis(4-methylphenoxy)ethane;1,2-DI-P-TOLYLOXYETHANE;NSC 128059;Benzene, 1,1'-[1,2-ethanediylbis(oxy)]bis[4-methyl-;NSC128059;SCHEMBL313373;DTXSID30299081;O(CCOc1ccc(C)cc1)c2ccc(C)cc2;STL378006;AKOS000411348;NSC-128059

Chemical Property of 1-Methyl-4-[2-(4-methylphenoxy)ethoxy]benzene

Chemical Property:

• Boiling Point: 378.4oC at 760 mmHg
• Flash Point: 150.1oC
• PSA: 18.46000
• Density: 1.049g/cm3
• LogP: 3.76120
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 242.130679813
• Heavy Atom Count: 18
• Complexity: 189

Purity/Quality:

99%min ^*data from raw suppliers

1,2-DI-P-TOLYLOXYETHANE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)OCCOC2=CC=C(C=C2)C

Technology Process of 1-Methyl-4-[2-(4-methylphenoxy)ethoxy]benzene

There total 11 articles about 1-Methyl-4-[2-(4-methylphenoxy)ethoxy]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.81%

p-cresol (106-44-5) + 1,2-dichloro-ethane (107-06-2,52399-93-6) → 1,1'-[ethane-1,2-diylbis(oxy)]bis(4-methylbenzene) (15149-11-8)

Guidance literature:

With sodium hydroxide; In water; at 75 - 80 ℃; for 8.3h; Inert atmosphere; Reflux; Green chemistry;

Reference yield: 64.0%

p-cresol (106-44-5) + ethylene dibromide (106-93-4) → 1,1'-[ethane-1,2-diylbis(oxy)]bis(4-methylbenzene) (15149-11-8)

Guidance literature:

With potassium carbonate; In acetonitrile; at 50 ℃; for 18h; Inert atmosphere;

DOI:10.1039/c1cc11211b

Reference yield:

potassium p-cresolate (1192-96-7) + ethylene dibromide (106-93-4) → 1,1'-[ethane-1,2-diylbis(oxy)]bis(4-methylbenzene) (15149-11-8)

Guidance literature:

upstream raw materials:

pyridine

2-(4-methylphenoxy)acetic acid

ethanol

1-bromo-2-(4'-methylphenoxy)ethane

Downstream raw materials:

2,2'-[ethane-1,2-diylbis(oxy)]bis(5-methylbenzenesulfonic acid)

1-<4-Carboxy-phenoxy>-2-<4-methyl-phenoxy>-aethan

1,2-bis(phenoxy)ethane-4,4'-dicarboxylic acid

1,2-bis(4-methoxycarbonylphenyl)-1,2-ethanediol

Refernces

• 1、 -. "A heat [...] wavelengths preparation method". Paragraph 0017; 0018; 0019. . Retrieved 2017/08/25.
• 2、 -. "1,2-BIS(3-METHYLPHENOXY)ETHANE COMPOSITION AND THERMAL RECORDING MEDIA MADE BY USING THE SAME". . . Retrieved 2008/06/13.