Silane, trimethyl(trifluoroethenyl)-

Base Information

• Chemical Name: Silane, trimethyl(trifluoroethenyl)-
• CAS No.: 1427-33-4
• Molecular Formula: C5H9F3Si
• Molecular Weight: 154.207
• DSSTox Substance ID: DTXSID30458636
• Nikkaji Number: J607.928H
• Mol file: 1427-33-4.mol

Synonyms:Silane, trimethyl(trifluoroethenyl)-;1427-33-4;trifluoro(trimethylsilyl)ethene;Trimethyl(trifluoroethenyl)silane;TRIMETHYL(1,2,2-TRIFLUOROETHENYL)SILANE;1,1,2-trifluoro-2-trimethylsilylethylene;Trifluorovinyltrimethylsilane;SCHEMBL4588957;DTXSID30458636;1,1,2-trifluoro-2-trimethylsilyl ethylene;EN300-1654529

Chemical Property of Silane, trimethyl(trifluoroethenyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 154.04256131
• Heavy Atom Count: 9
• Complexity: 130

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C(=C(F)F)F

Technology Process of Silane, trimethyl(trifluoroethenyl)-

There total 3 articles about Silane, trimethyl(trifluoroethenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + 1-bromo-1,2,2-trifluoroethene (598-73-2,55157-25-0) → trimethylsilyl fluoride (420-56-4) + 1,1,2-trifluoro-2-trimethylsilylethylene (1427-33-4)

Guidance literature:

1-bromo-1,2,2-trifluoroethene; With zinc; In N,N-dimethyl-formamide; at 20 ℃; for 3h;

chloro-trimethyl-silane; With copper(I) bromide; Title compound not separated from byproducts;

DOI:10.1016/S0022-1139(02)00339-1

Reference yield:

[chloro(difluoro)methyl]trimethylsilane (115262-00-5) → Hexamethyldisiloxane (107-46-0) + 1,1,2-trifluoro-2-trimethylsilylethylene (1427-33-4) + bis(trimethylsilyl)difluoromethane (86847-53-2)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; chloro-trimethyl-silane; tetrabutyl ammonium fluoride; tetrabutylammomium bromide; Multistep reaction. Yields of byproduct given; 1.) THF, electrolysis, Al anode, Ni cathode, 2.) THF;

DOI:10.1021/ja962990n

Reference yield:

chloro-trimethyl-silane (75-77-4) + [chloro(difluoro)methyl]trimethylsilane (115262-00-5) → Hexamethyldisiloxane (107-46-0) + 1,1,2-trifluoro-2-trimethylsilylethylene (1427-33-4) + trimethyl(difluoromethyl)silane (65864-64-4) + bis(trimethylsilyl)difluoromethane (86847-53-2)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; tetrabutyl ammonium fluoride; tetrabutylammomium bromide; Yield given. Multistep reaction. Further byproducts given; 1.) THF, electrolysis, Al anode, Ni cathode; other reagents: tris(3,6-dioxaheptyl)amine, magnesium, tetrabutylammonium hexafluorophosphate, 2.) THF;

DOI:10.1021/ja962990n

upstream raw materials:

chloro-trimethyl-silane

[chloro(difluoro)methyl]trimethylsilane

1-bromo-1,2,2-trifluoroethene

Downstream raw materials:

1,1,1,3,4,4-hexafluoro-1-trimethylsiloxy-1-phenyl-but-3-ene