CESIUM BICARBONATE, PURE, 99.9%

Base Information

• Chemical Name: CESIUM BICARBONATE, PURE, 99.9%
• CAS No.: 15519-28-5
• Molecular Formula: CH2 O3 . Cs
• Molecular Weight: 193.923
• Hs Code.: 28369990
• European Community (EC) Number: 239-554-5,249-784-8
• DSSTox Substance ID: DTXSID70165852
• Nikkaji Number: J8.579K
• Wikipedia: Caesium carbonate,Caesium bicarbonate,Caesium_bicarbonate
• Wikidata: Q5017043
• Mol file: 15519-28-5.mol

Synonyms:Carbonicacid, monocesium salt (8CI,9CI); Cesium bicarbonate; Cesium hydrogen carbonate;Cesium hydrogen carbonate (CsHCO3)

Chemical Property of CESIUM BICARBONATE, PURE, 99.9%

Chemical Property:

• Vapor Pressure: 2.58E-05mmHg at 25°C
• Boiling Point: 333.6°Cat760mmHg
• Flash Point: 169.8°C
• PSA: 60.36000
• Density: g/cm³
• LogP: -1.11230
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 193.89802085
• Heavy Atom Count: 5
• Complexity: 33.9

Purity/Quality:

99.9% ^*data from raw suppliers

Cesium bicarbonate 99+.9% ^*data from reagent suppliers

Safty Information:

• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: C(=O)(O)[O-].[Cs+]

Technology Process of CESIUM BICARBONATE, PURE, 99.9%

There total 7 articles about CESIUM BICARBONATE, PURE, 99.9% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methanol (67-56-1) + carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (201230-82-2) + caesium carbonate (534-17-8) → Dimethyl oxalate (553-90-2) + cesium bicarbonate (15519-28-5) + cesium formate (3495-36-1)

Guidance literature:

carbon dioxide; carbon monoxide; caesium carbonate; With silica gel; pyrographite; at 325 ℃; under 15001.5 - 33753.4 Torr;

methanol; at 200 ℃; for 2h; under 30003 Torr; Reagent/catalyst; Temperature; Pressure;

Reference yield: 22.4%

carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (201230-82-2) + caesium carbonate (534-17-8) → cesium bicarbonate (15519-28-5) + cesium oxalate (1068-63-9) + cesium formate (3495-36-1)

Guidance literature:

In neat (no solvent); High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC;

DOI:10.1039/c39950000633

Reference yield: 4.4%

carbon monoxide (201230-82-2) + caesium carbonate (534-17-8) → cesium bicarbonate (15519-28-5) + cesium oxalate (1068-63-9) + cesium formate (3495-36-1)

Guidance literature:

In neat (no solvent); High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC;

DOI:10.1039/c39950000633

upstream raw materials:

caesium carbonate

carbon monoxide

carbon dioxide

methanol

Downstream raw materials:

caesium carbonate

4-Phenyl-1,3-dioxolan-2-one

cesium formate

Refernces

• 1、 -. "PRODUCTION OF CESIUM OXALATE FROM CESIUM CARBONATE". Paragraph 0060; 0061; 0062. . Retrieved 2018/08/20.
• 2、 Kudo, Kiyoshi,Ikoma, Futoshi,Mori, Sadayuki,Komatsu, Koichi,Sugita, Nobuyuki. "Novel Synthesis of Oxalate from Carbon Dioxide and Carbon Monoxide in the Presence of Caesium Carbonate". . p. 633 - 634. Retrieved 2007/10/02.