Mercury, bromopropyl-

Base Information

• Chemical Name: Mercury, bromopropyl-
• CAS No.: 18257-68-6
• Molecular Formula: C3H7 Br Hg
• Molecular Weight: 323.583
• DSSTox Substance ID: DTXSID501100375
• Mol file: 18257-68-6.mol

Synonyms:Mercury, bromopropyl-;18257-68-6;bromo(propyl)mercury;propylmercury bromide;DTXSID501100375

Chemical Property of Mercury, bromopropyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 323.94376
• Heavy Atom Count: 5
• Complexity: 16.4

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC[Hg]Br

Technology Process of Mercury, bromopropyl-

There total 3 articles about Mercury, bromopropyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

silver tetrafluoroborate (14104-20-2) + di-n-propylmercury (628-85-3) + diphenylchloromethane (90-99-3) → 1,1-Diphenylmethanol (91-01-0) + Diphenylmethane (101-81-5) + N-(diphenylmethyl)acetamide (5267-35-6) + propylmercury (1+); bromide (18257-68-6)

Guidance literature:

With potassium bromide; In acetonitrile; Ar atmosphere and absence of light and moisture; addn. of AgBF4 in nitromethane to soln. of alkylmercury, portionwise addn. of Ph2CHCl in nitromethane (20°C, TLC monitoring), washing with soln. of KBr; TLC;

DOI:10.1007/BF00955985

Reference yield: 19.8%

tri-n-propylaluminum (102-67-0) + mercury dibromide → di-n-propylmercury (628-85-3) + propylmercury (1+); bromide (18257-68-6)

Guidance literature:

In diethyl ether;

Reference yield:

propyl bromide (106-94-5) → di-n-propylmercury (628-85-3) + propylmercury (1+); bromide (18257-68-6)

Guidance literature:

With sodium amalgam; acetic acid ester;

upstream raw materials:

propyl bromide

tri-n-propylaluminum

silver tetrafluoroborate

di-n-propylmercury

Downstream raw materials:

Propylmercurihydroxid