Mesityltrimethylsilane

Base Information

• Chemical Name: Mesityltrimethylsilane
• CAS No.: 2060-91-5
• Molecular Formula: C12H20Si
• Molecular Weight: 192.376
• DSSTox Substance ID: DTXSID301269519
• Nikkaji Number: J689.425I

Synonyms:Mesityltrimethylsilane;2060-91-5;trimethyl(2,4,6-trimethylphenyl)silane;1-(Trimethylsilyl)-2,4,6-trimethylbenzene;starbld0011509;DTXSID301269519;AKOS006324749;trimethyl-(2,4,6-trimethylphenyl)silane;1,3,5-Trimethyl-2-(trimethylsilyl)benzene;trimethyl-(2,4,6-trimethyl-phenyl)-silane

Chemical Property of Mesityltrimethylsilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 192.133427172
• Heavy Atom Count: 13
• Complexity: 157

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)[Si](C)(C)C)C

Technology Process of Mesityltrimethylsilane

There total 10 articles about Mesityltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

1,1,1,2,2,2-hexamethyldisilane (1450-14-2) + 2,4,6-trimethylphenyl bromide (576-83-0) → 2-trimethylsilyl-1,3,5-trimethylbenzene (2060-91-5) + 1,3,5-trimethyl-benzene (108-67-8)

Guidance literature:

With sodium methylate; In N,N,N,N,N,N-hexamethylphosphoric triamide;

DOI:10.1021/ol015666s

Reference yield:

dimesitylbis(trimethylsilyl)germane (111655-80-2) → 1,1-bis(trimethylsilyl)-4,6-dimethyl-1-germadihydro-benzocyclobutene (1000368-79-5) + 2-trimethylsilyl-1,3,5-trimethylbenzene (2060-91-5) + 1,3,5-trimethyl-benzene (108-67-8)

Guidance literature:

In hexane; at -70 ℃; for 48h; UV-irradiation;

DOI:10.1139/V07-039

Reference yield:

dimesitylbis(trimethylsilyl)germane (111655-80-2) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → 1-dimesityl-3,4-dimethyl-1-(trimethylsilyl)-1-germacyclopent-3-ene (1000368-81-9) + 1,1-bis(2,4,6-trimethylphenyl)-3,4-dimethylgermacyclopent-3-ene (83686-73-1) + 2-trimethylsilyl-1,3,5-trimethylbenzene (2060-91-5) + 1,3,5-trimethyl-benzene (108-67-8)

Guidance literature:

In hexane; at -70 ℃; for 20h; UV-irradiation;

DOI:10.1139/V07-039

upstream raw materials:

chloro-trimethyl-silane

2,4,6-trimethylphenyl bromide

(2E,4E)-hexa-2,4-diene

2,2-dimesitylhexamethyltrisilane

Downstream raw materials:

Trimethylsilanol

1,1,1,3,3,3-hexamethyl-disilazane

1,3,5-trimethyl-benzene

bis(2,4,6-trimethylphenyl)iodonium triflate

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