Peroxide, 1-methylethyl 1-methyl-1-phenylethyl

Base Information

• Chemical Name: Peroxide, 1-methylethyl 1-methyl-1-phenylethyl
• CAS No.: 28009-68-9
• Molecular Formula: C12H18O2
• Molecular Weight: 194.274
• DSSTox Substance ID: DTXSID00433117
• Nikkaji Number: J661.024B
• Wikidata: Q82247242
• Mol file: 28009-68-9.mol

Synonyms:Peroxide, 1-methylethyl 1-methyl-1-phenylethyl;28009-68-9;i-propyl cumyl peroxide;alpha-Cumylisopropyl peroxide;SCHEMBL5808591;DTXSID00433117

Chemical Property of Peroxide, 1-methylethyl 1-methyl-1-phenylethyl

Chemical Property:

• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 194.130679813
• Heavy Atom Count: 14
• Complexity: 158

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)OOC(C)(C)C1=CC=CC=C1

Technology Process of Peroxide, 1-methylethyl 1-methyl-1-phenylethyl

There total 2 articles about Peroxide, 1-methylethyl 1-methyl-1-phenylethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Cumene hydroperoxide (80-15-9) + isopropyl bromide (75-26-3) → (1-phenyl-1-methylethyl) 2-propyl peroxide (28009-68-9)

Guidance literature:

With potassium hydroxide; In cyclohexane; water; at 50 ℃; for 1.5h; Sonication; Green chemistry;

DOI:10.3390/molecules25010118

Reference yield:

Cumene hydroperoxide (80-15-9) + 2-diazopropane (2684-60-8) → (1-phenyl-1-methylethyl) 2-propyl peroxide (28009-68-9)

Guidance literature:

DOI:10.1016/S0040-4020(01)92907-2

Reference yield:

(1-phenyl-1-methylethyl) 2-propyl peroxide (28009-68-9) → 1-methyl-1-phenylethyl alcohol (617-94-7) + acetophenone (98-86-2)

Guidance literature:

With hexaaquairon(II) perchlorate; 2-pentanol; In pyridine; at 25 ℃; Product distribution; Kinetics;

DOI:10.1016/S0040-4020(97)01063-6

upstream raw materials:

Cumene hydroperoxide

2-diazopropane

isopropyl bromide

Downstream raw materials:

1-methyl-1-phenylethyl alcohol

acetophenone