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Cas Database |
| Name |
Rhenium(IV) chloride |
EINECS | 236-989-2 |
| CAS No. | 13569-71-6 | Density | 4900 kg /m3 |
| PSA | 0.00000 | LogP | 2.75800 |
| Solubility | decompose in water, soluble in hydrochloric acid | Melting Point |
300oC |
| Formula | Cl4Re | Boiling Point | 500 °C at 760 mmHg |
| Molecular Weight | 328.019 | Flash Point | N/A |
| Transport Information | N/A | Appearance | Black or dark purple crystals |
| Safety | 26-37/39 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Rhenium chloride(ReCl4);Rhenium tetrachloride; |
Article Data | 14 |
Rhenium(IV) chloride Synthetic route
A
- 31234-26-1
rhenium hexachloride
B
- 13569-71-6
rhenium tetrachloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) vapour of Re and Cl;; | |
| In neat (no solvent) vapour of Re and Cl;; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) | |
| In neat (no solvent) heating Re in Cl2;; | |
| In neat (no solvent) |
| Conditions | Yield |
|---|---|
| A 0% B 0% | |
| A 0% B 0% |
| Conditions | Yield |
|---|---|
| A n/a B <1 | |
| A n/a B <1 |
| Conditions | Yield |
|---|---|
| In neat (no solvent) heating Re in Cl2;; | A n/a B 0% |
- 13596-35-5
rhenium(V) chloride
- 10025-91-9
antimony(III) chloride
A
- 13569-71-6
rhenium tetrachloride
B
- 7647-18-9
antimonypentachloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: Re3Cl9; distiln. (vac.), sublimation; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) heating to 300 °C in high vac.;; product mixt.impured with Cl2 and oxide chloride obtained;; | A n/a B 0% C n/a |
A
- 13596-35-5
rhenium(V) chloride
B
- 13569-71-6
rhenium tetrachloride
C
- 10545-99-0
sulfur dichloride
D
- 7782-50-5
chlorine
| Conditions | Yield |
|---|---|
| In neat (no solvent) 160-210°C; |
- 13569-71-6
rhenium tetrachloride
- 10026-13-8, 874483-75-7
phosphorus pentachloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) vac.; equimolar amts., heating (300°C); | 100% |
| Conditions | Yield |
|---|---|
| In ethyl acetate byproducts: LiCl; addn. of LiS2 to ReCl4 in ethyl acetate with stirring, stirred for 4 h; filtered, treated for 2 h in H2S or 15 % H2S/H2 at 400°C for 2 h, washed with 12 % acetic acid, elem. anal.; |
Rhenium(IV) chloride Specification
The Rhenium(IV) chloride, with the CAS registry number 13569-71-6, is also known as Rhenium tetrachloride. Its EINECS number is 236-989-2. This chemical's molecular formula is Cl4Re and molecular weight is 328.01. What's more, its systematic name is rhenium(+3) cation tetrachloride. This chemical can be prepared by fresh rhenium dioxide and thionyl chloride.
When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing and gloves.
You can still convert the following datas into molecular structure:
(1)SMILES: [Re+3].[Cl-].[Cl-].[Cl-].[Cl-]
(2)Std. InChI: InChI=1S/4ClH.Re/h4*1H;/q;;;;+3/p-4
(3)Std. InChIKey: SBJRVPUDRNGLRB-UHFFFAOYSA-J
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