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13569-75-0

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Basic Information
CAS No.: 13569-75-0
Name: CHROMIUM (IC) IODIDE
Article Data: 39
Molecular Structure:
Molecular Structure of 13569-75-0 (CHROMIUM (IC) IODIDE)
Formula: CrI3
Molecular Weight: 432.709
Synonyms: Chromiumtriiodide
Density: g/cm3
Melting Point: >600°C
Boiling Point: °Cat760mmHg
Flash Point: °C
PSA: 0.00000
LogP: 2.65710
Related products
Synthetic route
7440-47-3

chromium

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
With iodine
With iodine
7440-47-3

chromium

10034-85-2

hydrogen iodide

A

chromium(II) iodide

B

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
In water byproducts: H2; Cr dissolves at room temp. in aq. HI at concns. 2.2-2.4 Mol/l; at elevated temps. the concn. may be 1.70-2.00 Mol/l; the products CrI2 and CrI3 form an equilibrium.; no products isolated;;
min. concn. of HI for dissolution of Cr in cold and warm given;
min. concn. of HI for dissolution of Cr in cold and warm given;
In water byproducts: H2; Cr dissolves at room temp. in aq. HI at concns. 2.2-2.4 Mol/l; at elevated temps. the concn. may be 1.70-2.00 Mol/l; the products CrI2 and CrI3 form an equilibrium.; no products isolated;;
...Expand

chromium(III) sulphide

7784-23-8

aluminium(III) iodide

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
In neat (no solvent) byproducts: Al2S3; react. at 350 °C. 48 h;; extraction with H2O;;
In neat (no solvent) byproducts: Al2S3; react. at 350 °C. 48 h;; extraction with H2O;;
7440-47-3

chromium

7553-56-2

iodine

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
In neat (no solvent) enclosing Cr and I2 under high vac. in a sublimation tube; heating Cr up to 475 °C; react. with I2 vapor (formed by heating I2 up to 225 °C), 24h;;
In neat (no solvent) enclosing Cr and I2 under high vac. in a sublimation tube; heating Cr up to 475 °C; react. with I2 vapor (formed by heating I2 up to 225 °C), 24h;;
In neat (no solvent) react. of gaseous I2 (in carrier gas N2) with Cr at 1200 °C;;
In neat (no solvent, solid phase) High Pressure; Cr and I2 were heated for 12 h in sealed, evaculated tube at 170-450°C;

chromium(II) iodide

7553-56-2

iodine

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
In neat (no solvent) react. of CrI2 with I2 vapor (1 atm) at 500 °C;;
In neat (no solvent) react. of CrI2 with I2 vapor (1 atm) at 500 °C;;

potassium iodochromat(VI)

10034-85-2

hydrogen iodide

A

13569-75-0

chromium(III) iodide

B

7553-56-2

iodine

Conditions
ConditionsYield
In water byproducts: KI; decompn. by boiling HI soln.;;
In water byproducts: KI; decompn. by boiling HI soln.;;
...Expand

4Cr(3+)*2H(1+)*7SO4(2-)=Cr4H2(SO4)7

10034-85-2

hydrogen iodide

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
In further solvent(s) byproducts: H2S, H2O, I2; boiling with HI soln.;;
In further solvent(s) byproducts: H2S, H2O, I2; boiling with HI soln.;;
27303-69-1

tris(η3-allyl)chromium

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
With I2 In tetrahydrofuran byproducts: C3H5I;>99

chromium(II) iodide

10034-85-2

hydrogen iodide

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
In not given byproducts: H2; equilibrium;;
In not given byproducts: H2; equilibrium;;
10034-85-2

hydrogen iodide

10025-73-7

chromium(III) chloride

13569-75-0

chromium(III) iodide

Conditions
ConditionsYield
In further solvent(s) react. of CrCl3 and concd. HI soln. (D=1.70);; not isolated;;
In further solvent(s) react. of CrCl3 and concd. HI soln. (D=1.70);; not isolated;;
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