- Rhenium
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- Rhenium fluoride(ReF6), (OC-6-11)-
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Cas Database |
| Name |
Rhenium fluoride(ReF6), (OC-6-11)- |
EINECS | 233-172-2 |
| CAS No. | 10049-17-9 | Density | 6 g/cm3 |
| PSA | 0.00000 | LogP | 2.52120 |
| Solubility | soluble HNO3; soluble 1.75mol/1000g anhydrous HF [MER06] | Melting Point |
18.8 °C |
| Formula | F6Re | Boiling Point | 47.6 °C |
| Molecular Weight | 300.197 | Flash Point | N/A |
| Transport Information | UN 3390 6.1/PG 1 | Appearance | Yellow feather crystal |
| Safety | 53-9-23-30-36/37/39-43-45 | Risk Codes | 14-32-35 |
| Molecular Structure |
|
Hazard Symbols |
 C
|
| Synonyms |
Rheniumfluoride (ReF6) (6CI,7CI,8CI);Hexafluororhenium;Rhenium hexafluoride;Rhenium hexafluoride 99%;AC1L24X3; |
Article Data | 20 |
Rhenium fluoride(ReF6), (OC-6-11)- Synthetic route
| Conditions | Yield |
|---|---|
| In hydrogen fluoride uncomplete reaction at -78°C or under reflux;; ReF4 or ReF6 in soln. obtained;; | |
| In hydrogen fluoride HF (liquid); uncomplete reaction at -78°C or under reflux;; ReF4 or ReF6 in soln. obtained;; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) at 300°C;; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) F2 and powdered Re at about 125°C;; | |
| In neat (no solvent) heating Re in fluorspar boat with Cl2-free F2 in fluorspar tube/copper tube to 125 °C for 1/2 h at reduced pressure, exclusion of O2 and moisture;; condensing vapour in quartz trap at -60 °C, ReOCl4-free, pure product;; | |
| In neat (no solvent) heating Re in fluorspar boat with F2 in fluorspar tube to 125 °C for 1/2 h, exclusion of O2 and moisture;; condensing vapour in quartz trap at -60 °C, product contg. ReOF4;; |
| Conditions | Yield |
|---|---|
| With HF In hydrogen fluoride HF (liquid); vac. line; large excess of HF; |
- 10049-17-9
rhenium hexafluoride
| Conditions | Yield |
|---|---|
| With F2 In neat (no solvent) sublimation; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) | A n/a B 0% |
| In neat (no solvent) | A n/a B 0% |
- 17029-21-9
rhenium heptafluoride
- 10049-17-9
rhenium hexafluoride
| Conditions | Yield |
|---|---|
| With dichloromethane In dichloromethane byproducts: CH2ClF, CHClF2, CHCl2F; inert atmosphere; excess of CH2Cl2, warming to room temp., 4 h; further byproduct; |
- 23377-53-9
rhenium oxide pentafluoride
A
- 10049-17-9
rhenium hexafluoride
| Conditions | Yield |
|---|---|
| With H2 In neat (no solvent) anhydrous atmosphere; activation of Re by static hydrogenation (573 K), then heating with ReOF5 (stainless-steel autoclave, 473 K, 16 h); cooling to room temp., removal of volatiles (vac.); |
| Conditions | Yield |
|---|---|
| In neat (no solvent) anhydrous conditions, prefluorinated Ni apparatus; 525 K; removal of volatiles (room temp.), vac. sublimation; |
- 14285-68-8
decacarbonyldirhenium(0)
A
- 10049-17-9
rhenium hexafluoride
| Conditions | Yield |
|---|---|
| With HF In hydrogen fluoride byproducts: CO, Xe; HF (liquid); vac. line; addn. of 4-5 molar equiv. of XeF2 to Re-complex; evapn. (vac.); unchanged Re2(CO)10 present in product with molar ratio of educts 1:1 and 1:2; |
Rhenium fluoride(ReF6), (OC-6-11)- Specification
The Rhenium fluoride(ReF6), (OC-6-11)- with CAS registry number of 10049-17-9 is also known as Rhenium(6+) hexafluoride. The IUPAC name is Hexafluororhenium. Its EINECS registry number is 233-172-2. In addition, the formula is F6Re and the molecular weight is 300.20. This chemical is a yellow feather crystal and is prepared by reaction of rhenium powder and fluorine gas.
Physical properties about Rhenium fluoride(ReF6), (OC-6-11)- are: (1)H-Bond Acceptor: 6; (2)Exact Mass: 300.94617; (3)MonoIsotopic Mass: 300.94617; (4)Heavy Atom Count: 7; (5)Complexity: 62.7; (6)Covalently-Bonded Unit Count: 1.
When you are using this chemical, please be cautious about it. As a chemical, it contacts with acids liberates very toxic gas and reacts violently with water. Besides, it may cause severe burns. During using it, wear suitable protective clothing, gloves and eye/face protection. Avoid exposure that keep container in a well-ventilated place. Do not breathe gas/fumes/vapour/spray and never add water to this product. In case of accident or if you feel unwell seek medical advice immediately. What's more, should be carefull about fire.
You can still convert the following datas into molecular structure:
1. Canonical SMILES: F[Re](F)(F)(F)(F)F
2. InChI: InChI=1S/6FH.Re/h6*1H;/q;;;;;;+6/p-6
3. InChIKey: YUCDNKHFHNORTO-UHFFFAOYSA-H
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