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Name |
Silicon sulfide |
EINECS | 237-344-8 |
CAS No. | 13759-10-9 | Density | 2,02 g/cm3 |
PSA | 64.18000 | LogP | 0.91560 |
Solubility | Decomposes in water | Melting Point |
1090 °C |
Formula | S2Si | Boiling Point | 1090°C |
Molecular Weight | 92.2175 | Flash Point | N/A |
Transport Information | N/A | Appearance | white, grey, or brown needels rotten egg smell white, grey, or brown needels |
Safety | Risk Codes | N/A | |
Molecular Structure | Hazard Symbols | N/A | |
Synonyms |
Silicondisulfide; |
Article Data | 4 |
Conditions | Yield |
---|---|
With H2S In neat (no solvent) Irradiation (UV/VIS); (Ar); H2S was passed over heated Si at about 1500 K, formed SiS and a mixt. of COS and Ar (200:1) was cocondensed about 30 min on a helium-cooled Cu surface and photolysed with a medium pressure Hg lamp (H2O filter); not isolated, detected IR spect.; |
Conditions | Yield |
---|---|
In solid matrix byproducts: CO; other Radiation; 20-25 K, CH4 matrix, photolysis (10 min, Hg lamp); not isolated, followed by Raman spectroscopy; |
silicon monosulfide
fluorine
A
silicon disulfide
B
difluorosilanethione
C
F3SiSH
E
silicon tetrafluoride
Conditions | Yield |
---|---|
In solid matrix Ar matrix; IR-monitoring; |
Conditions | Yield |
---|---|
at 600℃; for 30h; Sealed tube; |
Conditions | Yield |
---|---|
In gas heating mixt. of educts (1000°C, aluminium tube furnace, heating rate 2 °C/min, 5 Torr Ar); detd. by emission spectroscopy; |
Conditions | Yield |
---|---|
In neat (no solvent) heating (1300 K); |
tetraphosphorus decasulfide
silicon disulfide
phosphorus pentoxide
silica gel
Conditions | Yield |
---|---|
Stage #1: tetraphosphorus decasulfide; silicon disulfide; lithium sulfide; phosphorus pentoxide; silica gel for 1h; Milling; Glovebox; Inert atmosphere; Stage #2: at 549.84℃; under 75007.5 Torr; for 48h; Glovebox; Inert atmosphere; Sealed tube; |
The Silicon sulfide is an organic compound with the formula S2Si. The IUPAC name of this chemical is bis(sulfanylidene)silane. With the CAS registry number 13759-10-9, it is also named as Dithioxosilan. Besides, it should be stored in a closed cool and well-ventilated place.
Physical properties about Silicon sulfide are: (1)Exact Mass: 91.921068; (2)MonoIsotopic Mass: 91.921068; (3)Topological Polar Surface Area: 64.2; (4)Heavy Atom Count: 3; (5)Complexity: 18.3; (6)Covalently-Bonded Unit Count: 1.
Preparation: this chemical can be prepared by Aluminum and silicon sulfide. This reaction will need catalyst Nitrogen by heating.
You can still convert the following datas into molecular structure:
(1)SMILES: S=[Si]=S
(2)InChI: InChI=1/S2Si/c1-3-2
(3)InChIKey: KHDSWONFYIAAPE-UHFFFAOYAO
(4)Std. InChI: InChI=1S/S2Si/c1-3-2
(5)Std. InChIKey: KHDSWONFYIAAPE-UHFFFAOYSA-N