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Cas Database |
| Name |
Silver benzoate |
EINECS | 208-533-2 |
| CAS No. | 532-31-0 | Density | 1.103g/mLat 25°C(lit.) |
| PSA | 26.30000 | LogP | 1.30770 |
| Solubility | Insoluble in water. | Melting Point |
7-8°C(lit.) |
| Formula | C7H6AgO2 | Boiling Point | 249.3 °C at 760 mmHg |
| Molecular Weight | 228.984 | Flash Point | 111.4 °C |
| Transport Information | N/A | Appearance | Off-White Crystalline Powder |
| Safety | 24/25 | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Silver-benzoic acid (1:1); |
Article Data | 12 |
Silver benzoate Synthetic route
| Conditions | Yield |
|---|---|
| With NaOH In water; acetonitrile to aq. soln. of acid aq. soln. of NaOH added with stirring, then soln. of AgNO3 in CH3CN added under stirring; soln. slowly evapd. in air for 48 h, ppt. filtered, washed (H2O), dried (avc.); elem. anal.; | 95% |
| With NaOH; acetic acid In water dissolving NaOH in water, addn. of acetic acid (several drops) and benzoic acid, addn. of resulting soln. to a satd. aq. soln. of AgNO3 in the dark; filtration, washing the residue, drying in vac.; | 80% |
| With acetic acid; sodium hydroxide In water | 59% |
| Conditions | Yield |
|---|---|
| In water dropwise addn. of a satd. aq. soln. of AgNO3 to an aq. soln. of ammonium benzoate; pptn., cooling in ice, filtration, washing (cold water, cold ethanol, ether), drying by suction; | 90% |
| Conditions | Yield |
|---|---|
| In acetonitrile at 20℃; for 24h; Darkness; | 79% |
A
- 253177-44-5
1-benzyl-2-phenyl-ethyl isocyanate
B
- 532-31-0
silver benzoate
| Conditions | Yield |
|---|---|
| at 143℃; |
| Conditions | Yield |
|---|---|
| In water pH 6-7; |
| Conditions | Yield |
|---|---|
| With silver nitrate; sodium hydroxide In water |
| Conditions | Yield |
|---|---|
| In dichloromethane silver aroate was added to suspn. PdITol(bpy) in CH2Cl2 and stirred for 15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo; | 100% |
- 532-31-0
silver benzoate
| Conditions | Yield |
|---|---|
| In dichloromethane byproducts: silver bromide; under N2; react. of Ti-Cu complex with equimolar amt. of silver carboxylate in CH2Cl2 at 25°C; | 99% |
- 532-31-0
silver benzoate
- 675201-49-7
Pd(O2CPh)Me(N,N,N',N'-tetramethylethylenediamine)
| Conditions | Yield |
|---|---|
| In dichloromethane silver aroate was added to suspn. PdIMe(tmeda) in CH2Cl2 and stirred for15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo; | 99% |
- 532-31-0
silver benzoate
- 675201-57-7
Pd(O2CPh)Tol(N,N,N',N'-tetramethylethylenediamine)
| Conditions | Yield |
|---|---|
| In dichloromethane silver aroate was added to suspn. PdITol(tmeda) in CH2Cl2 and stirred for 15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo; | 99% |
Silver benzoate Specification
The Silver benzoate, with the CAS registry number 532-31-0, is also known as Silver-benzoic acid (1:1). This chemical's molecular formula is C7H6AgO2 and molecular weight is 229.9895. What's more, its IUPAC name is called Benzoic acid; silver.
Physical properties about Silver benzoate are: (1)ACD/LogP: 1.90; (2)#of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.58; (4)ACD/LogD (pH 7.4): -0.98; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 12.43; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 26.3Å2; (13)Flash Point: 111.4 °C; (14)Enthalpy of Vaporization: 51.4 kJ/mol; (15)Boiling Point: 249.3 °C at 760 mmHg; (16)Vapour Pressure: 0.0122 mmHg at 25 °C.
You can still convert the following datas into molecular structure:
(1) SMILES: [Ag].O=C(O)c1ccccc1
(2) InChI: InChI=1/C7H6O2.Ag/c8-7(9)6-4-2-1-3-5-6;/h1-5H,(H,8,9);
(3) InChIKey: GQCYXEOBZQXHPO-UHFFFAOYAJ
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