Radical Arylation

Involves the introduction of an aryl group into a molecule through the formation of a radical intermediate.

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Regioselectivity Yield Selectivity Cascade reaction Steric hindrance Chromatography Anilines Leaving group Steric Effects Chemoselectivity Electronic effects Substrate Scope Radical Addition Homolytic Cleavage Heterolytic Cleavage Visible-Light-Mediated Quenching Radical Coupling Intermolecular Radical Cyclization Photocatalysis Activation Energy Nucleophilicity Radical Initiation Spectroscopic Analysis Kinetic Control Thermodynamic Control Radical Chain Reaction Radical Alkylation Density Functional Theory (DFT) Calculations Isotope Labeling Electrophilicity Oxidation state Mechanistic study Transition state Arrhenius equation Spin Density Radical intermediate Chain propagation Radical polymerization Radical Propagation Radical Termination Radical amination Turnover frequency (TOF) Resonance stabilization Radical trap Radical clock Hammett plot Radical inhibitor Radical stabilization energy (RSE)

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