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Radical Alkylation

The resulting carbon-centered radical can then react with an alkylating agent (e.g., an alkyl halide or alkyl triflate), forming a new C-C bond. This step introduces the desired alkyl group onto the allylic or benzylic carbon atom.

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Articles of Radical Alkylation

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Regioselectivity Yield Catalyst Selectivity Cascade reaction Alkyl halides Steric hindrance Deprotonation Chromatography Leaving group Steric Effects Chemoselectivity Electronic effects Photoredox Catalysis Substrate Scope Radical Addition Solvent Effects Homolytic Cleavage Heterolytic Cleavage Quenching Radical Coupling Intermolecular Radical Cyclization Photocatalysis Activation Energy Radical Initiator Reaction Optimization Nucleophilicity Radical Initiation Spectroscopic Analysis Kinetic Control Thermodynamic Control Radical Chain Reaction Density Functional Theory (DFT) Calculations Isotope Labeling Electrophilicity Enolate Alkylation Transition Metal-Catalyzed Cross-Coupling Oxidation state Mechanistic study Transition state Arrhenius equation Spin Density Radical intermediate Chain propagation Vinyl Triflates Radical polymerization Radical Propagation Radical Termination Radical amination