Radical Stability

The stability of the acyloxy radical itself is a critical factor. More stable radicals are less likely to undergo rapid decarboxylation.

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Regioselectivity Yield Catalyst Selectivity Steric hindrance Substituents Density functional theory (DFT) Ligand Design Steric Effects Oxidative Addition Reductive Elimination Reaction Mechanism Electronic effects Cyclic Voltammetry (CV) Substrate Scope Radical Addition Solvent Effects Substituent Effects Computational Modeling Radical Cyclization Oxidizing agent Solvent and Reaction Conditions Activation Energy Reaction Optimization Radical Initiation Stepwise Mechanism Concerted Mechanism Non-covalent Interactions Spectroscopic Analysis Kinetic Control Thermodynamic Control Electron Paramagnetic Resonance (EPR) Isotope Labeling Substrate Activation Spin State Oxidation state Mechanistic study Transition state Spin Density Radical intermediate electrode potential Solid-state NMR Radical polymerization Radical Propagation Radical Termination Nitrene Turnover frequency (TOF) Resonance stabilization Radical trap Steric bulk

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