Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
di(rhodium)tetracarbonyl dichloride In ethanol at 115℃; under 37503 Torr; for 1.5h; | 100% |
propylamine
ethene
carbon monoxide
A
tri-n-propylamine
B
di-n-propylamine
Conditions | Yield |
---|---|
di(rhodium)tetracarbonyl dichloride In ethanol at 119℃; under 44253.5 Torr; for 1h; | A 1% B 99% |
di(rhodium)tetracarbonyl dichloride In ethanol at 119℃; under 44253.5 Torr; for 1h; | A 2% B 98% |
propan-1-ol
octanol
propiononitrile
A
tri-n-propylamine
B
Dipropyloctylamin
Conditions | Yield |
---|---|
With hydrogen; copper at 240℃; under 7600 Torr; | A n/a B 95% |
Conditions | Yield |
---|---|
With hydrogen; copper at 240℃; under 7600 Torr; | A n/a B 90% |
propiononitrile
A
tri-n-propylamine
B
N-propylidenepropylamine
C
di-n-propylamine
Conditions | Yield |
---|---|
With hydrogen at 220℃; | A 8.5% B 2.5% C 89% |
With hydrogen at 240℃; Temperature; Flow reactor; | A 13% B 2.5% C 80% |
propan-1-ol
1-Decanol
propiononitrile
A
tri-n-propylamine
B
N,N-dipropyldecylamine
Conditions | Yield |
---|---|
With hydrogen; copper at 240℃; under 7600 Torr; | A n/a B 86% |
Conditions | Yield |
---|---|
With hydrogen; copper at 240℃; under 7600 Torr; | A n/a B 80% |
propan-1-ol
1-dodecyl alcohol
propiononitrile
A
tri-n-propylamine
B
N,N-Dipropyl-dodecyl amine
Conditions | Yield |
---|---|
With hydrogen; copper at 240℃; under 7600 Torr; | A n/a B 80% |
Conditions | Yield |
---|---|
With hydrogen; copper at 240℃; under 7600 Torr; | A n/a B 76% |
Conditions | Yield |
---|---|
With hydrogen; copper at 240℃; under 7600 Torr; | A n/a B 75% |
The Tripropylamine is an organic compound with the formula C9H21N. The IUPAC name of this chemical is N,N-dipropylpropan-1-amine. With the CAS registry number 102-69-2, it is also named as 1-propanamine, N,N-dipropyl-. The product's categories are Amines; C9 to C10; Nitrogen Compounds. Besides, it is colourless liquid, which is used for producting drugs, pesticides, rubber and fiber processing aids, etc.
Physical properties about Tripropylamine are: (1)ACD/LogP: 3.25; (2)ACD/LogD (pH 5.5): 0.17; (3)ACD/LogD (pH 7.4): 0.78; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 1.16; (7)ACD/KOC (pH 7.4): 4.71; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 6; (10)Polar Surface Area: 3.24 Å2; (11)Index of Refraction: 1.428; (12)Molar Refractivity: 47.46 cm3; (13)Molar Volume: 184.3 cm3; (14)Polarizability: 18.81×10-24cm3; (15)Surface Tension: 25.9 dyne/cm; (16)Density: 0.777 g/cm3; (17)Flash Point: 36.7 °C; (18)Enthalpy of Vaporization: 39.48 kJ/mol; (19)Boiling Point: 158.1 °C at 760 mmHg; (20)Vapour Pressure: 2.66 mmHg at 25°C.
Preparation: this chemical can be prepared by 1-nitro-propane. This reaction will need reagent CO, H2O, catalyst Rh6(CO)16-amine polymer and solvent 2-ethoxy-ethanol. The reaction time is 48 hours with reaction temperature of 40 °C. The yield is about 32%.
Uses of Tripropylamine: it can be used to produce ethyl-tripropyl-ammonium; iodide by heating. It will need reagent butan-2-one with reaction time of 2 hours. The yield is about 40%.
When you are using this chemical, please be cautious about it as the following:
It is flammable and harmful by inhalation and in contact with skin. It is toxic by inhalation and if swallowed and can cause burns. Please keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: N(CCC)(CCC)CCC
(2)InChI: InChI=1/C9H21N/c1-4-7-10(8-5-2)9-6-3/h4-9H2,1-3H3
(3)InChIKey: YFTHZRPMJXBUME-UHFFFAOYAE
(4)Std. InChI: InChI=1S/C9H21N/c1-4-7-10(8-5-2)9-6-3/h4-9H2,1-3H3
(5)Std. InChIKey: YFTHZRPMJXBUME-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mammal (species unspecified) | LC50 | inhalation | 5100mg/m3 (5100mg/m3) | Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975. | |
mammal (species unspecified) | LD50 | unreported | 740mg/kg (740mg/kg) | Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975. | |
mouse | LC50 | inhalation | 3800mg/m3/2H (3800mg/m3) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 118, 1982. | |
rabbit | LD50 | skin | 570uL/kg (0.57mL/kg) | American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969. | |
rat | LC50 | inhalation | 5100mg/m3/4H (5100mg/m3) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 118, 1982. | |
rat | LD50 | oral | 96mg/kg (96mg/kg) | American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969. |