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Zirconium dioxide

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Name

Zirconium dioxide

EINECS 215-227-2
CAS No. 1314-23-4 Density 5.89 g/mL at 25 °C(lit.)
PSA 0.00000 LogP -0.23760
Solubility insoluble in water Melting Point 2700 °C(lit.)
Formula ZrO2 Boiling Point 4300 °C
Molecular Weight 123.223 Flash Point 5000°C
Transport Information UN 1993 Appearance White to yellow-brown Powder
Safety 26-36/37-39 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 1314-23-4 (Zirconium dioxide) Hazard Symbols IrritantXi
Synonyms

Norton 9839;Nissan Zirconia Sol NZS 20A;NZS 30A;ZD 100;NSC 12958;E 101;CCRIS 6601;CC 10;CAP (oxide);C.I. Pigment White 12;Zirconium oxide;Zirox Zt 35;Zirconium White;Zirconic anhydride;Zircoa 5027;Torayceram;Pigment White 12;PCS (filler);Nyacol Zr (acetate);

Article Data 18

Zirconium dioxide Synthetic route

7440-67-7

zirconium

6909-54-2

hydrogen peroxide

A

1314-23-4

zirconium(IV) oxide

B

(2)HZrO

C

872215-17-3

Zr(O(2)H)2

D

(2)HZr(O)(O(2)H)

E

872207-76-6

Zr(O(2)H)4

Conditions
ConditionsYield
In neat (no solvent) laser ablated Zr co-deposited with D2O2 in excess Ar onto a 10K CsI window, annealed at 22-28 K; not isolated, detected by IR;
7440-67-7

zirconium

7722-84-1

dihydrogen peroxide

A

1314-23-4

zirconium(IV) oxide

B

HZrO

C

42037-27-4

zirconium dihydroxide

D

HZr(O)OH

E

756456-88-9, 14475-63-9

zirconium tetrahydroxide

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O; Irradiation (UV/VIS); laser ablated Zr co-deposited with H2O2 in excess Ar onto a 10K CsI window, UV irradiated, annealed at 22-30 K; not isolated, detected by IR;
In neat (no solvent) byproducts: H2O; Irradiation (UV/VIS); (further products), laser ablated Zr co-deposited with H2O2 in excess Aronto a 10K CsI window, UV irradiated, annealed at 24-30 K; not isolated, detected by IR;
1314-23-4

zirconium(IV) oxide

rhodium (III) acetate

Reaxys ID: 11558544

Reaxys ID: 11558544

Conditions
ConditionsYield
Stage #1: zirconium(IV) oxide; rhodium (III) acetate; oxygen In water at 20 - 120℃; for 2.5h;
Stage #2: at 970℃; for 2h;
108-31-6

maleic anhydride

1314-23-4

zirconium(IV) oxide

p-phosphoric acid

p-phosphoric acid

108-91-8

cyclohexylamine

1631-25-0

N-cyclohexylmaleimide

Conditions
ConditionsYield
In 5,5-dimethyl-1,3-cyclohexadiene
108-31-6

maleic anhydride

1314-23-4

zirconium(IV) oxide

109-73-9

N-butylamine

1631-25-0

N-cyclohexylmaleimide

Conditions
ConditionsYield
With sulfuric acid In toluene
1314-23-4

zirconium(IV) oxide

1885-14-9

phenyl chloroformate

102-09-0

bis(phenyl) carbonate

1314-23-4

zirconium(IV) oxide

108-95-2

phenol

102-09-0

bis(phenyl) carbonate

1314-23-4

zirconium(IV) oxide

iron(III) oxide

788133-24-4

vanadium(V) oxide

16752-60-6

phosphorus pentoxide

A

(FePO4)0.20(FeVO4)080

Reaxys ID: 27627915

Reaxys ID: 27627915

Conditions
ConditionsYield
Stage #1: zirconium(IV) oxide; iron(III) oxide; vanadium(V) oxide; phosphorus pentoxide for 3h; Milling;
Stage #2: at 749.84℃; for 8h;
1314-23-4

zirconium(IV) oxide

iron(III) oxide

788133-24-4

vanadium(V) oxide

16752-60-6

phosphorus pentoxide

Reaxys ID: 27627912

Reaxys ID: 27627912

Conditions
ConditionsYield
Stage #1: zirconium(IV) oxide; iron(III) oxide; vanadium(V) oxide; phosphorus pentoxide for 3h; Milling;
Stage #2: at 749.84℃; for 8h;
1314-23-4

zirconium(IV) oxide

iron(III) oxide

788133-24-4

vanadium(V) oxide

16752-60-6

phosphorus pentoxide

Reaxys ID: 27627913

Reaxys ID: 27627913

Conditions
ConditionsYield
Stage #1: zirconium(IV) oxide; iron(III) oxide; vanadium(V) oxide; phosphorus pentoxide for 3h; Milling;
Stage #2: at 749.84℃; for 8h;

Zirconium dioxide Chemical Properties

IUPAC Name: dioxozirconium
Synonyms: AI3-29087 ; C.I. 77990 ; C.I. Pigment White 12 ; CAP (oxide) ; CC 10 ; CCRIS 6601 ; E 101 ; NSC 12958 ; NZS 30A ; Nissan Zirconia Sol NZS 20A ; Norton 9839 ; Nyacol Zr (acetate) ; PCS (filler) ; Pigment White 12 ; Rhuligel ; TZ 3YTSK ; Torayceram ; Sol ZS-OA ; ZD 100 ; Zircoa 5027 ; Zirconic anhydride ; Zirconium White ; Zirconium oxide ; Zirconium oxide (VAN) ; Zirox Zt 35 
Molecular Weight: 123.2228 [g/mol]
Molecular Formula: O2Zr
H-Bond Donor: 0
H-Bond Acceptor: 2 
EINECS: 215-227-2
Canonical SMILES: O=[Zr]=O
InChI: InChI=1S/2O.Zr
InChIKey: MCMNRKCIXSYSNV-UHFFFAOYSA-N
Density: 5.89 g/mL at 25 °C(lit.)
Melting Point: 2700 °C(lit.)
Flash Point: 5000°C
Boiling Point: 5000 °C(lit.)
Solubility: insoluble 
Water Solubility: insoluble
Stability: Stable
Product Categories: Inorganics;Biocompatible CeramicsMaterials Science;Biocompatible/Biodegradable Materials;40: Zr;Catalysis and Inorganic Chemistry;Materials Science;Nanomaterials;Nanoparticles: Oxides, Nitrides, and Other CeramicsChemical Synthesis;Nanopowders and Nanoparticle Dispersions;Oxides;ZirconiumMetal and Ceramic Science;ZirconiumNanomaterials
Following is the molecular structure of Zirconium dioxide (CAS NO.1314-23-4) is:

Zirconium dioxide Uses

 Zirconium dioxide (CAS NO.1314-23-4) can be instead of lime for the oxyhydrogen light.

Zirconium dioxide Safety Profile

Safty information about Zirconium dioxide (CAS NO.1314-23-4) is:
Hazard Codes:
IrritantXi
Risk Statements:
R36/37/38:Irritating to eyes, respiratory system and skin. 
R36/37:Irritating to eyes and respiratory system.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37:Wear suitable protective clothing and gloves. 
S39:Wear eye / face protection. 
S36:Wear suitable protective clothing.
RIDADR: UN1993
WGK Germany: 1
RTECS: ZH8800000
HazardClass: 3
PackingGroup: III
HS Code: 28256000

Zirconium dioxide Specification

 Zirconium dioxide (CAS NO.1314-23-4) ,also can be known as zirconia (not to be confused with zircon), it is a white crystalline. Its most naturally occurring form, with a monoclinic crystalline structure, is the rare mineral, baddeleyite. It is one of the most studied ceramic materials. Pure ZrO2 has a monoclinic crystal structure at room temperature and transitions to tetragonal and cubic at increasing temperatures. Its expansion caused by the cubic to tetragonal to monoclinic transformation induces very large stresses, and will cause pure ZrO2 to crack upon cooling from high temperatures.

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