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Zirconyl nitrate

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Name

Zirconyl nitrate

EINECS 237-529-3
CAS No. 13826-66-9 Density 1.45g/mLat 25°C
PSA 154.83000 LogP 0.44940
Solubility Soluble in water Melting Point N/A
Formula N2O7Zr Boiling Point 83 °C at 760 mmHg
Molecular Weight 231.233 Flash Point N/A
Transport Information UN 3098 5.1/PG 2 Appearance N/A
Safety 17-26-36/37/39-45 Risk Codes 8-34
Molecular Structure Molecular Structure of 13826-66-9 (ZIRCONYL NITRATE) Hazard Symbols OxidizingO, CorrosiveC
Synonyms

Zirconium,bis(nitrato-O)oxo-;Zirconium, dinitratooxo- (8CI);Zirconyl nitrate (6CI,7CI);Bis(nitrato)oxozirconium;Bis(nitrato-kO)oxozirconium;Dinitratooxozirconium;NSC 148480;Zirconium dinitrate oxide;Zirconium nitrate oxide (ZrO(NO3)2);Zirconium oxidedinitrate;Zirconium oxide nitrate (ZrO(NO3)2);Zirconium oxynitrate;Zirconiumoxynitrate (ZrO(NO3)2);Zirconyl dinitrate;Zirconyl nitrate (ZrO(NO3)2);Zircosol ZN;

 

Zirconyl nitrate Synthetic route

13826-66-9

zirconyl nitrate

7664-41-7

ammonia

zirconium hydroxide

Conditions
ConditionsYield
at 65℃;
13826-66-9

zirconyl nitrate

chloroauric acid

Au/ZrO2

Au/ZrO2

Conditions
ConditionsYield
Stage #1: zirconyl nitrate; chloroauric acid With sodium carbonate In water at 65 - 70℃; for 4h;
Stage #2: With oxygen at 110 - 400℃; for 13h;
1336-21-6

ammonium hydroxide

13826-66-9

zirconyl nitrate

7440-67-7

zirconium(IV) oxide

Conditions
ConditionsYield
Stage #1: ammonium hydroxide; zirconyl nitrate at 20℃; for 0.5h;
Stage #2: at 499.84℃; for 6h; Calcination;
16774-21-3

ammonium cerium (IV) nitrate

13826-66-9

zirconyl nitrate

cerium-zirconium oxide

Conditions
ConditionsYield
Stage #1: ammonium cerium (IV) nitrate; zirconyl nitrate at 20℃; for 0.5h;
Stage #2: at 499.84℃; for 6h; Calcination;

Zirconyl nitrate Consensus Reports

Reported in EPA TSCA Inventory.

Zirconyl nitrate Standards and Recommendations

OSHA PEL: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3
ACGIH TLV: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3
DFG MAK: 1 mg(Zr)/m3

Zirconyl nitrate Specification

The Zirconium, bis(nitrato-kO)oxo-, with the CAS registry number 13826-66-9 and EINECS registry number 237-529-3, has the systematic name of oxozirconium - nitric acid (1:2). It belongs to the following product categories: Inorganics; Metal and Ceramic Science; Salts; Zirconium Salts. And the molecular formula of this chemical is N2O7Zr. What's more, it is always used for the determination of potassium or fluoride.

The physical properties of Zirconium, bis(nitrato-kO)oxo- are as followings: (1)ACD/LogP: -0.13; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.13; (4)ACD/LogD (pH 7.4): -0.13; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)#H bond acceptors: 4; (8)#H bond donors: 1; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 55.05 Å2.

You should be cautious while dealing with this chemical. If contact with combustible material, and may cause fire. And this chemical may cause burns. Therefore, you had better take the following instructions: Keep away from combustible material; Wear suitable protective clothing, gloves and eye/face protection, and in case of contact with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: O=[N+]([O-])O.[O-][N+](=O)O.O=[Zr]
(2)InChI: InChI=1/2HNO3.O.Zr/c2*2-1(3)4;;/h2*(H,2,3,4);;/r2HNO3.OZr/c2*2-1(3)4;1-2/h2*(H,2,3,4);
(3)InChIKey: UJVRJBAUJYZFIX-XSAJKTQWAD

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 intraperitoneal 1250mg/kg (1250mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Archives of Industrial Hygiene and Occupational Medicine. Vol. 1, Pg. 637, 1950.
rat LD50 oral 2500mg/kg (2500mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Archives of Industrial Hygiene and Occupational Medicine. Vol. 1, Pg. 637, 1950.

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