CAS No.1336-21-6,Ammonium hydroxide Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	1336-21-6
Name:	Ammonium hydroxide
Article Data:	13
Cas Database

Formula:	H₅NO
Molecular Weight:	35.0458
Synonyms:	Ammonia aqueous;Ammonia solution;Ammonia water;Ammonia, monohydrate;Aqua ammonia;Aquammonia;Household ammonia;
EINECS:	215-647-6
Density:	0.91 g/mL at 20 °C
Melting Point:	-77 °C
Boiling Point:	165 °C at 760 mmHg
Solubility:	soluble in water
Appearance:	colorless aqueous solution
Hazard Symbols:	C,N
Risk Codes:	34-50
Safety:	26-36/37/39-45-61
Transport Information:	UN 2672 8/PG 3
PSA:	23.06000
LogP:	0.19940

Synthetic route

: 7631-99-4
sodium nitrate

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
With phosphoric acid; hydrogen; nitric acid; palladium on activated charcoal; germanium dioxide at 40℃; Product distribution / selectivity;

: 10043-11-5
ammonia borane complex

: 7732-18-5
water

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
Irradiation;

: 7664-41-7
ammonia

: silver nitrate

: 1310-73-2
sodium hydroxide

A: 1336-21-6
ammonium hydroxide

B: 15291-89-1, 72021-02-4
diamminesilver(I) hydroxide

Conditions

Conditions	Yield
In water

...Expand

: 7727-37-9
nitrogen

: 7732-18-5
water

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
With air; Zn0.12Mo0.12Cd0.9S1.14/graphitic carbon nitride (g-C3N4)(20 mass percent) In ethanol at 30℃; under 760.051 Torr; Reagent/catalyst; Irradiation;
With hydrogenated Bi5O7I (H-Bi5O7I) at 15℃; Catalytic behavior; Reagent/catalyst; UV-irradiation;
With Bi5O7Br In neat (no solvent) Catalytic behavior; Mechanism; Reagent/catalyst; UV-irradiation;
With potassium sulfate Catalytic behavior; Reagent/catalyst; Electrochemical reaction;
With methanol Catalytic behavior; Irradiation;

: 7727-37-9
nitrogen

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
With sulfuric acid In water at 20℃; for 20h; Kinetics; Catalytic behavior; Electrochemical reaction;

: 7631-99-4
sodium nitrate

: potassium hydroxide

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
With ruthenium oxychloride In water at 25℃; Kinetics; Inert atmosphere; Electrolysis;

: 13126-12-0
rubidium nitrate

: potassium hydroxide

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
With ruthenium oxychloride In water at 25℃; Kinetics; Inert atmosphere; Electrolysis;

: caesium nitrate

: potassium hydroxide

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
With ruthenium oxychloride In water at 25℃; Kinetics; Inert atmosphere; Electrolysis;

: potassium nitrate

: potassium hydroxide

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
With ruthenium oxychloride In water at 25℃; Kinetics; Mechanism; Reagent/catalyst; Concentration; Electrolysis; Inert atmosphere;

: lithium nitrate

: potassium hydroxide

: 1336-21-6
ammonium hydroxide

Conditions

Conditions	Yield
With ruthenium oxychloride In water at 25℃; Kinetics; Inert atmosphere; Electrolysis;

Raw Materials

Downstream Products

108-45-2

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Specification

Ammonium hydroxide with the CAS registry number 1336-21-6, is also named as Spirit of hartshorn. The product's categories are Industrial / Fine Chemicals; Inorganics, and the other registry numbers are 125888-87-1; 132103-60-7; 16393-49-0; 178115-93-0. Besides, it is colorless aqueous solution, which should be stored in tightly sealed containers in a cool, dry place. And you should ensure that the workplaces have good ventilation or exhaust devices. It is stable, but incompatible with copper, copper alloys, acids, galvanised iron, zinc, aluminium, bronze, dimethyl sulphate, mercury, alkali metals. In addition, its molecular formula is H₅NO and molecular weight is 35.04.

Properties about Ammonium hydroxide are: (1)H-Bond Donor: 2; (2)H-Bond Acceptor: 1; (3)Rotatable Bond Count: 0; (4)Exact Mass: 35.037114; (5)MonoIsotopic Mass: 35.037114; (6)Topological Polar Surface Area: 2; (7)Heavy Atom Count: 2; (8)Density: 0.91 g/mL at 20 °C; (9)Melting point: -77 °C; (10)Enthalpy of Vaporization: 23.33 kJ/mol; (11)Boiling Point: 165 °C at 760 mmHg; (12)Vapour Pressure: 5990 mmHg at 25 °C.

Preparation of Ammonium hydroxide: This chemical can be prepared by liquid ammonia. You can use it to dissolve in pure water. Then cool it by cold water. And you will obtain this chemcial.

Uses of Ammonium hydroxide: This chemical in water is an ingredient of cleaning agents. It is also used as a precursor to some alkyl amines in industry. Moreover, it was traditionally used to darken or stain wood containing tannic acid in furniture-making. And it cna be used in the meat packing industry. Furthermore, it is used as a complexant and base in traditional qualitative inorganic analysis in laboratory.

When you are using this chemical, please be cautious about it as the following: it may cause burns. It is also very toxic to aquatic organisms. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And you should wear suitable protective clothing, gloves and eye/face protection. Please avoid release to the environment. Refer to special instructions / safety data sheets. Moreover, in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

You can still convert the following datas into molecular structure:
(1)SMILES: [OH-].[NH4+]
(2)InChI: InChI=1/H3N.H2O/h1H3;1H2
(3)InChIKey: VHUUQVKOLVNVRT-UHFFFAOYAI

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
cat	LDLo	oral	750mg/kg (750mg/kg)		"Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
frog	LDLo	parenteral	2500mg/kg (2500mg/kg)		"Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 688, 1948.
human	LCLo	inhalation	5000ppm (5000ppm)		"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 95, 1969.
human	LDLo	oral	43mg/kg (43mg/kg)		"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 95, 1969.
human	TCLo	inhalation	408ppm (408ppm)	LUNGS, THORAX, OR RESPIRATION: "FIBROSIS, FOCAL (PNEUMOCONIOSIS)" LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA	Journal of the Iowa State Medical Society. Vol. 61, Pg. 271, 1971.
mouse	LD50	intravenous	91mg/kg (91mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION	Journal of Clinical Investigation. Vol. 37, Pg. 497, 1958.
mouse	LDLo	subcutaneous	160mg/kg (160mg/kg)		"Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 688, 1948.
rabbit	LDLo	intravenous	10mg/kg (10mg/kg)		"Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
rabbit	LDLo	subcutaneous	200mg/kg (200mg/kg)		"Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 688, 1948.
rat	LD50	oral	350mg/kg (350mg/kg)	GASTROINTESTINAL: OTHER CHANGES LIVER: OTHER CHANGES KIDNEY, URETER, AND BLADDER: OTHER CHANGES	Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 259, 1941.