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109-07-9

Basic Information
CAS No.: 109-07-9
Name: Piperazine,2-methyl-
Molecular Structure:
Molecular Structure of 109-07-9 (Piperazine,2-methyl-)
Formula: C5H12N2
Molecular Weight: 100.16
Synonyms: Piperazine,2-methyl-, (?à)-;(?à)-2-Methylpiperazine;2-Methylpiperazine;NSC 5277;
EINECS: 203-644-2
Density: 0.845 g/cm3
Melting Point: 61-63 °C(lit.)
Boiling Point: 153.2 °C at 760 mmHg
Flash Point: 45.1 °C
Solubility: 78 g/100 mL (25 °C) in water
Appearance: white to yellow crystalline powder and chunks
Hazard Symbols: FlammableF,IrritantXi
Risk Codes: 11-36/37/38
Safety: 16-26-36/37/39-36
Transport Information: UN 1325 4.1/PG 2
PSA: 24.06000
LogP: 0.22530
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Chemistry

MF: C5H12N2
MW: 100.16
mp of 2-METHYLPIPERAZINE (109-07-9): 61-63 °C(lit.)
bp of 2-METHYLPIPERAZINE (109-07-9): 155 °C 763 mm Hg(lit.)
density: 0.817 g/cm3
Fp of 2-METHYLPIPERAZINE (109-07-9): 149 °F
storage temp.: Flammables area
Water Solubility: 78 g/100 mL (25 oC)
PHYSICAL STATE: white crystal

Uses

2-METHYLPIPERAZINE (109-07-9) is used as pharmaceutical intermediates, synthetic Lomefloxacin raw materials. It is used in the synthesis of drugs like quinolone class antibiotics, agrochemicals and other chemical compounds.

Toxicity Data With Reference

1.   

orl-rat LD50:2030 mg/kg

   JACTDZ    Journal of the American College of Toxicology. 1 (1990),58.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: F,Xi (Highly Flammable; Irritant)
Risk Statements: 11-36/37/38 (Highly Flammable; Irritating to eyes, respiratory system and skin)
Safety Statements: 16-26-36/37/39-36 (Keep away from sources of ignition - No smoking; In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; Wear suitable protective clothing, gloves and eye/face protection; Wear suitable protective clothing)
RIDADR: UN 1325 4.1/PG 2
WGK Germany: 2
RTECS: TM1225020
F: 10 (Keep under argon)
HazardClass: 4.1
PackingGroup: III
Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NOx.

Standards and Recommendations

PURITY: 99.0% min
WATER: 0.5% max
INDIVIDUAL IMPURITY: 0.5% max

Specification

Storage: Store away from water/moisture. Do not store together with oxidizing and acidic materials. Keep container tightly sealed. Store in cool, dry conditions in well sealed containers.