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| CAS No.: | 114615-82-6 | ||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Name: | TETRAPROPYLAMMONIUM PERRUTHENATE | ||||||||||||||||
| Molecular Structure: | |||||||||||||||||
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| Formula: | C12H28O4PRu | ||||||||||||||||
| Molecular Weight: | 351.429 | ||||||||||||||||
| Synonyms: | TETRAPROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII);TPAP;Tetrapropylammoniumperruthenate,min.97%TPAP;1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-);Tetrapropylammonium Perruthenate (TPAP);Tetra-n-propylammonium perruthenate(VII), 98+% | ||||||||||||||||
| Density: | g/cm3 | ||||||||||||||||
| Melting Point: |
~160 °C (dec.)(lit.) |
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| Boiling Point: | °Cat760mmHg | ||||||||||||||||
| Flash Point: | °C | ||||||||||||||||
| Solubility: | Insoluble in water. | ||||||||||||||||
| Hazard Symbols: |
 
|
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| Risk Codes: | 5-8-36/37/38 | ||||||||||||||||
| Safety: |
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| PSA: | 74.27000 | ||||||||||||||||
| LogP: | 2.96800 | ||||||||||||||||
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- 4499-86-9
tetrapropylammonium hydroxide
- 114615-82-6
tetrapropylammonium perruthennate
| Conditions | Yield |
|---|---|
| Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 30 - 40℃; for 5h; Stage #2: tetrapropylammonium hydroxide at 30℃; for 5h; Temperature; | 99.7% |
| Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h; Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h; | 67% |
- 114615-82-6
tetrapropylammonium perruthennate
| Conditions | Yield |
|---|---|
| With sodium carbonate In water mixt. of RuCl3 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4; elem. anal.; | 99% |
- 20427-56-9
ruthenium tetroxide
- 114615-82-6
tetrapropylammonium perruthennate
| Conditions | Yield |
|---|---|
| With K2CO3 stirred at 0°C for 3 h; washed with ice-cold H2O, dried in vac.; elem. anal.; | 96% |
- 7790-28-5
sodium periodate
- 114615-82-6
tetrapropylammonium perruthennate
| Conditions | Yield |
|---|---|
| In water stirring of hydrated RuCl3 and NaIO4 in H2O overnight; addn. to an aq. soln. of n-Pr4NOH containing NaOH at 0-5°C under an atmosphere of O2;; ppt. was removed every 20 min, washed with ice-cold water, and dried under vac.;; | 87% |
- 7790-28-5
sodium periodate
- 4499-86-9
tetrapropylammonium hydroxide
- 114615-82-6
tetrapropylammonium perruthennate
| Conditions | Yield |
|---|---|
| Stage #1: tetrapropylammonium hydroxide With sodium hydroxide In water Stage #2: sodium periodate; ruthenium(III) chloride trihydrate In water at 20℃; for 16h; | 33% |
- 4499-86-9
tetrapropylammonium hydroxide
- 114615-82-6
tetrapropylammonium perruthennate
| Conditions | Yield |
|---|---|
| With sodium periodate; sodium hydroxide In water at 20℃; for 16h; | 33% |
- 114615-82-6
tetrapropylammonium perruthennate
| Conditions | Yield |
|---|---|
| With sodium carbonate In water mixt. of RuO2 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4; |
- 4499-86-9
tetrapropylammonium hydroxide
- 114615-82-6
tetrapropylammonium perruthennate
| Conditions | Yield |
|---|---|
| Stage #1: ruthenium(III) chloride trihydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h; Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h; |
- 114615-82-6
tetrapropylammonium perruthennate
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4-hydroxycyclohexyl carboxylic acid ethyl ester
- 7529-22-8
4-methylmorpholine N-oxide
- 17159-79-4
ethyl 4-oxocyclohexane-1-carboxylate
| Conditions | Yield |
|---|---|
| In ethyl acetate; acetonitrile | 98% |
| In dichloromethane | 13.46 g (85%) |
- 114615-82-6
tetrapropylammonium perruthennate
- 277334-43-7
(2Z)-3-(4-hydroxy-2-buten-2-yl)-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-(n-propyloxy)naphthalene
- 180861-54-5
(2Z)-3-[5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-(n-propyloxy)naphthalen-3-yl]but-2-en-1-al
| Conditions | Yield |
|---|---|
| With 4-methylmorpholine N-oxide In dichloromethane | 98% |
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Chemistry
Molecular Structure of Tetrapropylammonium tetraoxoruthenate (CAS No.114615-82-6):
Molecular Formula: C12H28N.RuO4
Molecular Weight: 351.425
CAS No: 114615-82-6
H bond acceptors: 5
H bond donors: 1
Freely Rotating Bonds: 8
Polar Surface Area: 74.27 Å2
InChI: InChI=1/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;/rC12H28N.O4Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;1-5(2,3)4/h5-12H2,1-4H3;/q+1;-1
InChIKey: NQSIKKSFBQCBSI-DQAXOFGLAB
Std. InChI: InChI=1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
Std. InChIKey: NQSIKKSFBQCBSI-UHFFFAOYSA-N
Product Categories: Boron, Nitrile, Thio, TM-Cpds;Ammonium Polyhalides, etc. (Quaternary);Catalysts for Organic Synthesis;Classes of Metal Compounds;Environmentally-friendly Oxidation;Homogeneous Catalysts;Metal Complexes;Oxidation;Quaternary Ammonium Compounds;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Complexes (Environmentally-friendly Oxidation);Transition Metal Compounds
Systematic Name: Oxido-trioxo-ruthenium ; Etrapropylammonium
Safety Profile
Hazard Codes: 
O,
Xi
Risk Statements: 5-8-36/37/38
R5 :Heating may cause an explosion.
R8 :Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 17-26-36
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
RIDADR: UN 1479 5.1/PG 2
WGK Germany: 3
F: 3-10
HazardClass: 5.1
PackingGroup: III
Specification
Tetrapropylammonium tetraoxoruthenate (CAS No.114615-82-6), its synonyms are Tetrapropylammonium perruthenate ; N,N,N-Tripropylpropan-1-aminium oxido(trioxo)ruthenium .