CAS No.114615-82-6,TETRAPROPYLAMMONIUM PERRUTHENATE Suppliers

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Basic Information

CAS No.:

114615-82-6

Name:

TETRAPROPYLAMMONIUM PERRUTHENATE

Article Data:

Molecular Structure:

Formula:

C₁₂H₂₈O₄PRu

Molecular Weight:

351.429

Synonyms:

TETRAPROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII);TPAP;Tetrapropylammoniumperruthenate,min.97%TPAP;1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-);Tetrapropylammonium Perruthenate (TPAP);Tetra-n-propylammonium perruthenate(VII), 98+%

Density:

g/cm³

Melting Point:

~160 °C (dec.)(lit.)

Boiling Point:

°Cat760mmHg

Flash Point:

°C

Solubility:

Insoluble in water.

Hazard Symbols:

Risk Codes:

5-8-36/37/38

Safety:

Hazard Codes	O,Xi
Risk Statements	5-8-36/37/38
Safety Statements	17-26-36
RIDADR	UN 1479 5.1/PG 2
WGK Germany	3
F	3-10
HazardClass	5.1
PackingGroup	III

PSA:

74.27000

LogP:

2.96800

Synthetic route

: rhodium(III) chloride hydrate

: 4499-86-9
tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 30 - 40℃; for 5h; Stage #2: tetrapropylammonium hydroxide at 30℃; for 5h; Temperature;	99.7%
Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h; Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h;	67%

: sodium bromate

: ruthenium trichloride hydrate

: tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
With sodium carbonate In water mixt. of RuCl3 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4; elem. anal.;	99%

...Expand

: 20427-56-9
ruthenium tetroxide

: tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
With K2CO3 stirred at 0°C for 3 h; washed with ice-cold H2O, dried in vac.; elem. anal.;	96%

: 7790-28-5
sodium periodate

: ruthenium trichloride hydrate

: tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
In water stirring of hydrated RuCl3 and NaIO4 in H2O overnight; addn. to an aq. soln. of n-Pr4NOH containing NaOH at 0-5°C under an atmosphere of O2;; ppt. was removed every 20 min, washed with ice-cold water, and dried under vac.;;	87%

...Expand

: 7790-28-5
sodium periodate

: ruthenium(III) chloride trihydrate

: 4499-86-9
tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
Stage #1: tetrapropylammonium hydroxide With sodium hydroxide In water Stage #2: sodium periodate; ruthenium(III) chloride trihydrate In water at 20℃; for 16h;	33%

...Expand

: ruthenium(III) trichloride hydrate

: 4499-86-9
tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
With sodium periodate; sodium hydroxide In water at 20℃; for 16h;	33%

: sodium bromate

: tetrapropylammonium hydroxide

: ruthenium dioxide hydrate

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
With sodium carbonate In water mixt. of RuO2 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4;

...Expand

: ruthenium(III) chloride trihydrate

: 4499-86-9
tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
Stage #1: ruthenium(III) chloride trihydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h; Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h;

: 114615-82-6
tetrapropylammonium perruthennate

: 3618-04-0, 75877-66-6, 17159-80-7
4-hydroxycyclohexyl carboxylic acid ethyl ester

: 7529-22-8
4-methylmorpholine N-oxide

: 17159-79-4
ethyl 4-oxocyclohexane-1-carboxylate

Conditions

Conditions	Yield
In ethyl acetate; acetonitrile	98%
In dichloromethane	13.46 g (85%)

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 277334-43-7
(2Z)-3-(4-hydroxy-2-buten-2-yl)-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-(n-propyloxy)naphthalene

: 180861-54-5
(2Z)-3-[5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-(n-propyloxy)naphthalen-3-yl]but-2-en-1-al

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide In dichloromethane	98%

Downstream Products

128-23-4

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Chemistry

Molecular Structure of Tetrapropylammonium tetraoxoruthenate (CAS No.114615-82-6):

Molecular Formula: C₁₂H₂₈N.RuO₄
Molecular Weight: 351.425
CAS No: 114615-82-6
H bond acceptors: 5
H bond donors: 1
Freely Rotating Bonds: 8
Polar Surface Area: 74.27 Å²
InChI: InChI=1/C₁₂H₂₈N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;/rC12H28N.O4Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;1-5(2,3)4/h5-12H2,1-4H3;/q+1;-1
InChIKey: NQSIKKSFBQCBSI-DQAXOFGLAB
Std. InChI: InChI=1S/C₁₂H₂₈N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
Std. InChIKey: NQSIKKSFBQCBSI-UHFFFAOYSA-N
Product Categories: Boron, Nitrile, Thio, TM-Cpds;Ammonium Polyhalides, etc. (Quaternary);Catalysts for Organic Synthesis;Classes of Metal Compounds;Environmentally-friendly Oxidation;Homogeneous Catalysts;Metal Complexes;Oxidation;Quaternary Ammonium Compounds;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Complexes (Environmentally-friendly Oxidation);Transition Metal Compounds
Systematic Name: Oxido-trioxo-ruthenium ; Etrapropylammonium

Safety Profile

Hazard Codes: Oxidizing O, Irritant Xi
Risk Statements: 5-8-36/37/38
R5 :Heating may cause an explosion.
R8 :Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 17-26-36
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
RIDADR: UN 1479 5.1/PG 2
WGK Germany: 3
F: 3-10
HazardClass: 5.1
PackingGroup: III

Specification

Tetrapropylammonium tetraoxoruthenate (CAS No.114615-82-6), its synonyms are Tetrapropylammonium perruthenate ; N,N,N-Tripropylpropan-1-aminium oxido(trioxo)ruthenium .