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4499-86-9

Basic Information
CAS No.: 4499-86-9
Name: Tetrapropylammonium hydroxide
Article Data: 3
Cas Database
Molecular Structure:
Molecular Structure of 4499-86-9 (Tetrapropylammonium hydroxide)
Formula: C12H29NO
Molecular Weight: 203.368
Synonyms: TPAOH;Tetra-n-propylammonium hydroxide;Tetrapropylammonium oxide;1-Propanaminium,N,N,N-tripropyl-, hydroxide (9CI);Ammonium, tetrapropyl-, hydroxide (8CI);Tetrapropylammonium hydroxide (6CI,7CI);Fluka 88110;
EINECS: 224-800-6
Density: 1.00 g/mL at 20 °C
Melting Point: N/A
Boiling Point: 100-102 °C
Flash Point: 102°C
Solubility: Miscible in water
Appearance: clear colourless solution
Hazard Symbols: Corrosive
Risk Codes: 34
Safety: 26-36/37/39-45
Transport Information: UN 3267 8
PSA: 23.06000
LogP: 3.26640
Synthetic route
1941-30-6

tetra-n-propylammonium bromide

4499-86-9

tetrapropylammonium hydroxide

Conditions
ConditionsYield
With potassium hydroxide In dichloromethane at 20℃; for 10h;82%
With potassium hydroxide In ethanol at 40℃; for 12h; Inert atmosphere;
593-85-1

diguanidine carbonate

4499-86-9

tetrapropylammonium hydroxide

cis,cis-1,3,5-trimethylcyclohexane-1,3,5-tricarboxylic acid

[(nC3H7)4N(+)]*2[C(NH2)3(+)]*[KTA(3-)]

Conditions
ConditionsYield
In water at 40℃;100%
594-45-6

ethanesulfonic acid

4499-86-9

tetrapropylammonium hydroxide

C2H5O3S(1-)*C12H28N(1+)

Conditions
ConditionsYield
In methanol Inert atmosphere;100%

rhodium(III) chloride hydrate

4499-86-9

tetrapropylammonium hydroxide

114615-82-6

tetrapropylammonium perruthennate

Conditions
ConditionsYield
Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 30 - 40℃; for 5h;
Stage #2: tetrapropylammonium hydroxide at 30℃; for 5h; Temperature;
99.7%
Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h;
Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h;
67%
151-21-3

sodium dodecyl-sulfate

4499-86-9

tetrapropylammonium hydroxide

tetrapropylammonium dodecyl sulfate

Conditions
ConditionsYield
In water using a strong cation-exchange resin;99%

C9H9F3N2O4S*C5H5N

4499-86-9

tetrapropylammonium hydroxide

C9H8F3N2O4S(1-)*C12H28N(1+)

Conditions
ConditionsYield
In water Inert atmosphere;97%
69509-35-9

RhI(tetraphenylporphyrin)

4499-86-9

tetrapropylammonium hydroxide

106161-22-2

[Rh(5,10,15,20-tetraphenylporphyrinato)(n-propyl)]

Conditions
ConditionsYield
With air In water; benzene at 120℃; for 2h; Sealed tube;90%
21204-44-4

p-cumenyl hydroperoxide

4499-86-9

tetrapropylammonium hydroxide

tetra-n-propylammonium cumyl peroxide

Conditions
ConditionsYield
In methanol; water for 0.25h;89.3%

C9H9F3N2O3S2*C5H5N

4499-86-9

tetrapropylammonium hydroxide

C9H8F3N2O3S2(1-)*C12H28N(1+)

Conditions
ConditionsYield
In water Inert atmosphere;88%
75-91-2

tert.-butylhydroperoxide

4499-86-9

tetrapropylammonium hydroxide

tetra-propylammonium tert-butyl peroxide

Conditions
ConditionsYield
In methanol; water for 0.25h;82.1%
Raw Materials
1941-30-6
Downstream Products
102-69-2
338-38-5
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Chemistry

Product Name: Tetrapropylammonium hydroxide (CAS NO.4499-86-9)

Molecular Formula: C12H29NO
Molar mass: 203.3648 g/mol
Density: 1.00 g/mL at 20 °C
Flash Point: 102°C
Index of Refraction: n20/D 1.370
Boiling Point: 100-102 °C
Vapour Pressure: 1.96E-0.8 mmHg at 25°C
Storage temp: 2-8°C
Sensitive: Air Sensitive
Stability: Stable under normal temperatures and pressures.   
H-Bond Donor: 1
H-Bond Acceptor: 1
Structure Descriptors of Tetrapropylammonium hydroxide (CAS NO.4499-86-9):
  IUPAC Name: tetrapropylazanium hydroxide
  Canonical SMILES: CCC[N+](CCC)(CCC)CCC.[OH-]
  InChI: InChI=1S/C12H28N.H2O/c1-5-9-13(10-6-2,11-7-3)12-8-4;/h5-12H2,1-4H3;1H2/q+1;/p-1 
  InChIKey: LPSKDVINWQNWFE-UHFFFAOYSA-M
Product Categories: Ammonium Hydroxides (Quaternary); Quaternary Ammonium Compounds; Organic Bases; Chemical Synthesis

Toxicity Data With Reference

1.    

scu-mus LDLo:52 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 28 (1926),367.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by subcutaneous route. A corrosive.When heated to decomposition it emits toxic fumes of NOx and NH3.
Safety Information of Tetrapropylammonium hydroxide (CAS NO.4499-86-9):
Hazard Codes: C
Risk Statements:
34:  Causes burns
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
39:  Wear eye/face protection
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

Specification

 Tetrapropylammonium hydroxide , its CAS NO. is 4499-86-9, the synonyms are TPAOH ; Tetrapropylammonium hydroxide solution ; Tetra-n-propylammonium hydroxide ; 1-Propanaminium,N,N,N-tripropyl-,hydroxide ; Fluka88110 .