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124-30-1

Basic Information
CAS No.: 124-30-1
Name: Octadecanamine
Molecular Structure:
Molecular Structure of 124-30-1 (Octadecanamine)
Formula: C18H39N
Molecular Weight: 269.52 .
Synonyms: Armeen 18;Armeen 18D;Armeen 18D-FLK;Armofilm;Farmin 80;Genamin SH 100;Kemamine P 990D;Monooctadecylamine;NSC 9857;Nissan Amine AB;ODA;Stearamine;Stearylamine;n-Octadecylamine;n-Stearylamine;1-Aminooctadecane;1-Octadecylamine;Adogenen 142;Alamine 7;Alamine7D;Amine 18D;Amine AB;
EINECS: 204-695-3
Density: 0.818 g/cm3
Melting Point: 50-60 °C
Boiling Point: 348.875 °C at 760 mmHg
Flash Point: 154.077 °C
Solubility: practically insoluble in water
Appearance: white solid
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38-41-38
Safety: 26-36-37/39-28B
Transport Information: UN 3259
PSA: 26.02000
LogP: 6.90690
Synthetic route
638-65-3

stearonitrile

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With sodium hydroxide; hydrogen; nickel In water at 135℃; under 14251.4 Torr; for 3h;98.2%
With [Ru(H)(BH4)(CO)(PPh3)(3-(di-tert-butylphosphino)-N-((1-methyl-1H-imidazol-2 yl)methyl)propylamine)]; hydrogen In isopropyl alcohol at 70℃; for 3h; Inert atmosphere; Autoclave;88%
With [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); {[(phenylphosphinediyl)bis(2,1-phenylene)]bis(methylene)}bis(di-tert-butylphosphine); hydrogen In isopropyl alcohol at 70℃; under 11251.1 Torr; for 17h; Inert atmosphere; Autoclave;72%
20332-12-1

2-octadecylisoindoline-1,3-dione

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With hydrazine hydrate In methanol at 95℃; for 1h; Gabriel Amine Synthesis;95%
1262670-57-4

N-trityloctadecan-1-amine

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With ammonium cerium (IV) nitrate; water; acetic acid In dichloromethane at 20℃; for 40h; Inert atmosphere;93%
38428-49-8

N-Boc-octadecylamine

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With 3-butyl-l-methyl-1H-imidazol-3-iumtrifloroacetate In 1,4-dioxane; water at 80℃; for 1.5h;92%
With methanol; Amberlyst 15; ammonia 1.) CH2Cl2, 25 deg C, 14 h, 2.) 50 min; Yield given. Multistep reaction;
3906-22-7

N-octadecylacetamide

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
Stage #1: N-octadecylacetamide With Schwartz's reagent In tetrahydrofuran at 20℃; for 0.0333333h; Inert atmosphere;
Stage #2: With water In tetrahydrofuran Inert atmosphere;
91%
112-92-5

1-octadecanol

A

112-99-2

Dioctadecylamine

B

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With ammonia; hydrogen; catalyst formed by supporting 2percent by mass of ruthenium on zirconia surface-treated with sulfur at 220℃; under 120012 Torr; for 2.8h; Product distribution / selectivity; Autoclave;A 7.4%
B 84.8%
Stage #1: 1-octadecanol With hydrogen; catalyst with 35weight percent Ni, 6weight percent Cu, 27weight percent Zr, 0.4weight percent La at 200℃; for 2h; Gas phase;
Stage #2: With ammonia; hydrogen; catalyst with 35weight percent Ni, 6weight percent Cu, 27weight percent Zr, 0.4weight percent La at 220℃; for 6h; Product distribution / selectivity;
Stage #1: 1-octadecanol With hydrogen; catalyst with 31weight percent Ni, 12weight percent Cu at 200℃; for 2h; Gas phase;
Stage #2: With ammonia; hydrogen; catalyst with 31weight percent Ni, 12weight percent Cu at 220℃; for 9h; Product distribution / selectivity;
3386-33-2

1-chlorooctadecane

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With ammonia at 50℃;
112-61-8

Methyl stearate

A

112-99-2

Dioctadecylamine

B

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With ammonia; hydrogen; cobalt at 270℃; under 147102 - 183877 Torr;
With ammonia; hydrogen; cobalt; decalin at 270℃; under 147102 - 183877 Torr;
With ammonia; cobalt at 270℃; under 147102 - 183877 Torr; Hydrogenation;
112-99-2

Dioctadecylamine

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With aluminium oxide hydrate-kaolin; ammonia at 380℃; under 147102 Torr;
124-26-5

stearamide

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
With lithium aluminium tetrahydride In tetrahydrofuran
With lithium aluminium tetrahydride In tetrahydrofuran for 1h;
638-65-3

stearonitrile

A

112-99-2

Dioctadecylamine

B

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With copper manganese; cyclohexane; ammonia at 270℃; under 220652 Torr; Hydrogenation;
With copper manganese; cyclohexane; ammonia at 270℃; under 220652 Torr; Hydrogenation;
94377-17-0

octadecanal oxime

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With sodium bis(2-methoxyethoxy)aluminium dihydride In toluene at 140℃; for 4h;
136918-14-4

phthalimide

octadecyl halide

octadecyl halide

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With potassium carbonate und Erwaermen des Reaktionsprodukts mit Hydrazin-hydrat und Aethanol;
112-92-5

1-octadecanol

A

124-30-1

1-aminooctadecane

B

dioctadecylamine and trioctadecylamine

dioctadecylamine and trioctadecylamine

Conditions
ConditionsYield
With silica-alumina; ammonia at 360℃;
7664-41-7

ammonia

638-65-3

stearonitrile

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
at 90℃; under 29420.3 Torr; an Raney-Nickel.Hydrogenation;
67-56-1

methanol

ammonium chloride

7664-41-7

ammonia

638-65-3

stearonitrile

Raney nickel

Raney nickel

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
at 35 - 77℃; bei der Reduktion an Kupfer-Kathoden verschiedener Stromdichte und verschiedenen Reaktionszeite;
638-65-3

stearonitrile

aq.-ethanolic NaOH-solution

aq.-ethanolic NaOH-solution

Raney nickel

Raney nickel

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
at 65℃; under 15200 Torr; Hydrogenation;
7664-41-7

ammonia

638-65-3

stearonitrile

nickel sulfide tungsten disulfide

nickel sulfide tungsten disulfide

A

112-99-2

Dioctadecylamine

B

102-88-5

trioctadecylamine

C

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
at 280℃; under 110326 Torr; Hydrogenation;
3386-33-2

1-chlorooctadecane

7664-41-7

ammonia

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
at 50℃;
112-99-2

Dioctadecylamine

7664-41-7

ammonia

aluminium oxide hydrate-kaolin

aluminium oxide hydrate-kaolin

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
at 380℃;
13144-71-3

thiostearamide

71-36-3

butan-1-ol

sodium

sodium

124-30-1

1-aminooctadecane

112-61-8

Methyl stearate

7664-41-7

ammonia

hydrogen

hydrogen

cobalt

cobalt

Al2O3-catalyst

Al2O3-catalyst

A

112-99-2

Dioctadecylamine

B

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
at 270℃; under 147102 Torr;
112-61-8

Methyl stearate

7664-41-7

ammonia

hydrogen

hydrogen

copper + manganese

copper + manganese

Al2O3-catalyst

Al2O3-catalyst

A

112-99-2

Dioctadecylamine

B

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
at 270℃; under 147102 Torr;
oleic acid nitrile

oleic acid nitrile

A

112-99-2

Dioctadecylamine

B

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With cobalt-aluminium barium at 130 - 140℃; under 110326 Torr; Hydrogenation;
57-11-4

stearic acid

zinc stearate

zinc stearate

A

124-30-1

1-aminooctadecane

B

CS2

CS2

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: SOCl2
2: NH3
3: LiAlH4 / tetrahydrofuran
View Scheme
112-76-5

Stearoyl chloride

glycerol-2-palmitate-1-stearate

glycerol-2-palmitate-1-stearate

A

124-30-1

1-aminooctadecane

B

CS2

CS2

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NH3
2: LiAlH4 / tetrahydrofuran
View Scheme
112-90-3

(Z)-9-octadecen-1-amine

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethanol at 30℃; under 6000.6 Torr; for 4h;
With platinum; hydrogen under 750.075 Torr;
122336-85-0

1-octadecylammonium 1-octadecylcarbamate

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
for 0.166667h; Inert atmosphere; Heating;
57-11-4

stearic acid

124-30-1

1-aminooctadecane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: oxalyl dichloride / benzene / 72 h
2: ammonia / benzene
3: lithium aluminium tetrahydride / tetrahydrofuran / 1 h
View Scheme
128-69-8

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

124-30-1

1-aminooctadecane

25834-02-0

N,N’-bis(octadecyl)-3,4:9,10-perylenebis(dicarboximide)

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 8h; Reflux;100%
With 1H-imidazole at 140℃; for 3h;89%
63%
59565-09-2

2-(vinyloxy)ethyl isothiocyanate

124-30-1

1-aminooctadecane

1-Octadecyl-3-(2-vinyloxy-ethyl)-thiourea

Conditions
ConditionsYield
at 45℃; for 2h; other primary and secondary amines;100%
In tetrachloromethane at 45℃; for 2h;100%
59288-36-7

3-Thietanyl isothiocyanate

124-30-1

1-aminooctadecane

1-octadecyl-3-thietan-3-yl-thiourea

Conditions
ConditionsYield
100%
Selfheating;91%
76529-42-5

methyl 15-hydroxypentadecanoate

124-30-1

1-aminooctadecane

273737-78-3

15-hydroxy-pentadecanoic acid octadecylamide

Conditions
ConditionsYield
at 148℃;100%
948995-62-8

4-[3,5-dimethyl-4-(4-nitro-benzyloxy)-phenyl]-4-oxo-butyric acid 2,5-dioxo-pyrrolidin-1-yl ester

124-30-1

1-aminooctadecane

4-[3,5-dimethyl-4-(4-nitrobenzyloxy)phenyl]-N-(octadecyl)-4-oxobutyramide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 3h;100%
5124-30-1

4,4'-bis(diisocyanato)dicyclohexylmethane

124-30-1

1-aminooctadecane

C51H100N4O2

Conditions
ConditionsYield
With Desmodur W In hexane for 1h; Reflux;100%
In hexane for 1h; Reflux;100%

C20H20BrNO4

124-30-1

1-aminooctadecane

C38H58N2O4

Conditions
ConditionsYield
for 72h; Heating;100%
617-09-4

di-o-tolyl carbonate

124-30-1

1-aminooctadecane

38428-44-3

n-octadecylcarbamate methyl ester

Conditions
ConditionsYield
With hydrogenchloride In toluene99.5%
2420-87-3

3,3',4,4'-biphenyltetracarboxylic anhydride

124-30-1

1-aminooctadecane

3,3',4,4'-biphenyltetracarboxylic acid tetra-n-octadecylamine

Conditions
ConditionsYield
at 150℃; for 18.5h; Temperature; Green chemistry;99.4%
110-13-4

2,5-hexanedione

124-30-1

1-aminooctadecane

102809-09-6

2,5-dimethyl-1-n-octadecyl-1H-pyrrole

Conditions
ConditionsYield
With sulfated anatase In neat (no solvent) at 20℃; for 0.333333h; Paal-Knorr Pyrrole Synthesis; Milling; Green chemistry;99%
76521-35-2

N-<2-(acetylamino)-2-deoxy-3,4,6-triacetyl-β-D-glucopyranosyl>-N2-<(1,1-dimethylethoxy)carbonyl>-L-asparagine

124-30-1

1-aminooctadecane

128154-59-6

N4-(2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-N2-(tert-butoxycarbonyl)-L-asparagine octadecylamide

Conditions
ConditionsYield
With N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline In chloroform for 48h; Ambient temperature;99%
77976-79-5

4-(N,N-dimethylamino)-1,8-naphthalic anhydride

124-30-1

1-aminooctadecane

89394-00-3

4-N,N-dimethylamino-N'-octadecylnaphthalimide

Conditions
ConditionsYield
In xylene Heating;99%
124-30-1

1-aminooctadecane

1796-84-5

4-ethoxy-3-nitropyridine

120759-82-2

3-nitro-4-octadecylaminopyridine

Conditions
ConditionsYield
at 150 - 155℃; for 2h;99%
124-30-1

1-aminooctadecane

255870-35-0

4-fluorocarbonyltetrathiafulvalene

[2,2']bi[[1,3]dithiolylidene]-4-carboxylic acid octadecylamide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.25h; Substitution;99%
124-30-1

1-aminooctadecane

235083-47-3

BocNHCys[S-S-cholesteryl]-OH

235083-53-1

BocNHCys[S-S-cholesteryl]-NH(CH2)17CH3

Conditions
ConditionsYield
With (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 2h;99%
510-39-4

maleopimaric acid

124-30-1

1-aminooctadecane

1233690-97-5

C42H69NO4

Conditions
ConditionsYield
at 130 - 160℃; Inert atmosphere;99%
1331848-61-3

S-dodecyl heptanethioate

124-30-1

1-aminooctadecane

1331848-63-5

N-octadecylheptanamide

Conditions
ConditionsYield
In water for 3h; Reflux;99%
6914-79-0

1-cyano-cyclopropanecarboxylic acid

124-30-1

1-aminooctadecane

1266666-38-9

1-cyano-N-octadecylcyclopropanecarboxamide

Conditions
ConditionsYield
With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 4h; Inert atmosphere;99%
532-55-8

Benzoyl isothiocyanate

124-30-1

1-aminooctadecane

1-benzoyl-3-octadecylthiourea

Conditions
ConditionsYield
In ethyl acetate at 5℃; Inert atmosphere;99%
In ethyl acetate at 5 - 50℃; Inert atmosphere;99%
2033-24-1

cycl-isopropylidene malonate

124-30-1

1-aminooctadecane

149-73-5

trimethyl orthoformate

2,2-dimethyl-5-((octadecylamino)methylene)-1,3-dioxane-4,6-dione

Conditions
ConditionsYield
Stage #1: cycl-isopropylidene malonate; trimethyl orthoformate for 1h; Reflux;
Stage #2: 1-aminooctadecane for 2h; Reflux;
99%
292638-85-8

acrylic acid methyl ester

124-30-1

1-aminooctadecane

36341-82-9

methyl 3-(octadecylamino)propionate

Conditions
ConditionsYield
at 65℃; for 7h; Michael Addition;98.55%
124-30-1

1-aminooctadecane

L-lysine methyl ester diisocyanate

Nα,Nε-bis(octadecylaminocarbonyl)-L-lysine methyl ester

Conditions
ConditionsYield
In toluene at 100℃; for 0.166667h;98%

18α-glycyrrhizic acid

124-30-1

1-aminooctadecane

C42H62O16*C18H39N

Conditions
ConditionsYield
In methanol Reflux;98%
124-30-1

1-aminooctadecane

13710-19-5

tolfenamic Acid

tolfenamic acid octadecylammonium salt

Conditions
ConditionsYield
In methanol at 65℃; for 2h;98%
3852-09-3

methyl 3-methoxypropionate

124-30-1

1-aminooctadecane

β-methoxy-N-stearylamide

Conditions
ConditionsYield
With iron(II) triflate In N,N-dimethyl-formamide at 80℃; for 2h;98%

2-(5'-formyl-2'-hydroxy-3'-methylphenyl)benzoxazole

124-30-1

1-aminooctadecane

(E)-1-(3-(benzo[d]oxazol-2-yl)-4-hydroxy-5-methylphenyl)-N-octadecylmethanimine

Conditions
ConditionsYield
With acetic acid In isopropyl alcohol at 80℃; pH=Ca. 4;98%
124-30-1

1-aminooctadecane

235083-46-2

BocNHCys[S-S-(CH2)17CH3]-OH

235083-50-8

BocNHCys[S-S-(CH2)17CH3]-NH(CH2)17CH3

Conditions
ConditionsYield
With (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 2h;97%
107-13-1

acrylonitrile

124-30-1

1-aminooctadecane

1555-64-2

N-octadecyl-bis(2-cyanoethyl)amine

Conditions
ConditionsYield
In butan-1-ol at 70℃; for 19h;97%
124-30-1

1-aminooctadecane

5222-73-1

3,4-dimethoxy-3-cyclobutene-1,2-dione

1428906-21-1

C40H76N2O2

Conditions
ConditionsYield
In methanol at 20℃; Inert atmosphere;96.9%
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    124-30-1

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    Octadecylamine Product attributes Product name:  Octadecylamine Alias:  stearylamine; 1-Octadedecylamine; 1-Octadecylamine; 1-Aminooctadecane; EINECS NO:204-695-3 Molecular formula: C18H39N

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Chemistry

Product Name: Octadecanamine (CAS NO.124-30-1)

Molecular Formula: C18H39N
Molar mass: 269.51  g/mol
Flash Point: 148 °C
Melting point: 50-60 °C
Boiling Point: 349°C
Vapour Pressure: 10 mm Hg ( 72 °C)
Density: 0.862 g/cm3
Refractive index  1.4522
FreezingPoint:  53.1°C
Water solubility:  practically insoluble
Appearance: White prills
Surface Tension: 31 dyne/cm
Enthalpy of Vaporization: 59.33 kJ/mol
Vapour Pressure: 4.88E-05 mmHg at 25°C
Index of Refraction: 1.452 
Molar Refractivity: 88.97 cm3 
Molar Volume: 329.3 cm3 
XLogP3-AA: 8.5
H-Bond Donor: 1
H-Bond Acceptor: 1
Structure Descriptors of Octadecanamine (CAS NO.124-30-1):
  IUPAC Name: octadecan-1-amine 
  Canonical SMILES: CCCCCCCCCCCCCCCCCCN
  InChI: InChI=1S/C18H39N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h2-19H2,1H3 
  InChIKey: REYJJPSVUYRZGE-UHFFFAOYSA-N
Product Categories: Alkylamines; Monofunctional & alpha,omega-Bifunctional Alkanes; Monofunctional Alkanes

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 250mg/kg (250mg/kg)   National Technical Information Service. Vol. AD691-490,
mouse LD50 oral 3gm/kg (3000mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 38(11), Pg. 31, 1973.
rat LD50 oral 2395mg/kg (2395mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 38(11), Pg. 31, 1973.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Safety Information of Octadecanamine (CAS NO.124-30-1):
Hazard Codes:Xi
Risk Statements:
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin 
41:  Risk of serious damage to eyes
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
39:  Wear eye/face protection
RIDADR: 3259
WGK Germany: 2
RTECS: RG4150000
HazardClass: 8
PackingGroup: III
HS Code: 29211980

Specification

 Octadecanamine , its CAS NO. is 124-30-1, the synonyms are Adogenen 142 ; 1-Octadecanamine ; adogenen142 ; Alamine 7 ; Alamine 7D ; Amine 18-90 .