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Basic Information
CAS No.: 13352-75-5
Name: 2,4,6,8,10-Pentaoxaundecane
Molecular Structure:
Molecular Structure of 13352-75-5 (2,4,6,8,10-Pentaoxaundecane )
Formula: C6H14O5
Molecular Weight: 166.174
Synonyms: Dimethoxy-tetraoxymethylen;bis-(methoxymethoxy-methyl) ether;Bis-(methoxymethoxy-methyl)-aether;CH3-(OCH2)4-OCH3;2,4,6,8,10-Pentaoxaundecane;Tetrakis-methylenglykol-dimethylaether;Tetrahydroxymethylenglycol dimethylether;
Density: 1.0671 g/cm3(Temp: 25 °C)
Melting Point: -8--6.5 °C
Boiling Point: 76-80℃/8Torr
PSA: 46.15000
LogP: 0.15900
Synthetic route
67-56-1

methanol

50-00-0

formaldehyd

A

13353-03-2

bis-methoxymethoxy-methane

B

628-90-0

bis(methoxymethyl)ether

Conditions
ConditionsYield
With ZrO2#dotLa2O3 at 130℃; under 6000.6 Torr; for 4h; Pressure; Reagent/catalyst;A 23%
B 23.3%
C 14.9%
50-00-0

formaldehyd

109-87-5

Dimethoxymethane

A

13353-03-2

bis-methoxymethoxy-methane

B

628-90-0

bis(methoxymethyl)ether

Conditions
ConditionsYield
With La2O3 doped titania at 130℃; under 4500.45 Torr; for 4h; Reagent/catalyst; Pressure; Autoclave;A 22.4%
B 17.5%
C 8.4%
With macroporous strong acidic styrene type cation exchange resin catalyst at 100℃; under 15001.5 Torr; for 10h; Temperature; Time; Overall yield = 51.66 %;
With Cl -/TiO2-La2O3/SBA-15 (Si/Al=38) at 130℃; under 4500.45 Torr; for 4h; Reagent/catalyst; Temperature; Pressure;
67-56-1

methanol

50-00-0

formaldehyd

109-87-5

Dimethoxymethane

Conditions
ConditionsYield
With sulfuric acid
67-56-1

methanol

50-00-0

formaldehyd

109-87-5

Dimethoxymethane

7664-93-9

sulfuric acid

A

13353-03-2

bis-methoxymethoxy-methane

B

628-90-0

bis(methoxymethyl)ether

110-88-3

1,3,5-Trioxan

534-15-6

1,1-dimethoxyethane

A

C11H24O10

B

C13H28O12

C

13353-03-2

bis-methoxymethoxy-methane

D

628-90-0

bis(methoxymethyl)ether

F

13352-78-8

CH3-(OCH2)8-OCH3

G

54261-86-8

Methoxymethoxymethoxymethoxymethoxy-methoxymethoxymethoxymethoxymethoxymethoxy-methane

I

13353-04-3

CH3-(OCH2)7-OCH3

J

13352-77-7

CH3-(OCH2)6-OCH3

Conditions
ConditionsYield
Amberlite IR 120 at 100℃; for 24h; Product distribution / selectivity;
trifluorormethanesulfonic acid at 100℃; for 40h; Product distribution / selectivity;
sulfuric acid In water at 100℃; for 12h; Product distribution / selectivity;
110-88-3

1,3,5-Trioxan

534-15-6

1,1-dimethoxyethane

A

13353-03-2

bis-methoxymethoxy-methane

B

628-90-0

bis(methoxymethyl)ether

Conditions
ConditionsYield
sulfuric acid In water at 100℃; for 16h; Product distribution / selectivity;
110-88-3

1,3,5-Trioxan

534-15-6

1,1-dimethoxyethane

628-90-0

bis(methoxymethyl)ether

A

C11H24O10

B

C13H28O12

C

13353-03-2

bis-methoxymethoxy-methane

E

13352-78-8

CH3-(OCH2)8-OCH3

F

54261-86-8

Methoxymethoxymethoxymethoxymethoxy-methoxymethoxymethoxymethoxymethoxymethoxy-methane

H

13353-04-3

CH3-(OCH2)7-OCH3

I

13352-77-7

CH3-(OCH2)6-OCH3

Conditions
ConditionsYield
sulfuric acid In water at 100℃; for 12h; Product distribution / selectivity;
110-88-3

1,3,5-Trioxan

628-90-0

bis(methoxymethyl)ether

A

C11H24O10

B

C13H28O12

C

534-15-6

1,1-dimethoxyethane

D

13353-03-2

bis-methoxymethoxy-methane

F

13352-78-8

CH3-(OCH2)8-OCH3

G

54261-86-8

Methoxymethoxymethoxymethoxymethoxy-methoxymethoxymethoxymethoxymethoxymethoxy-methane

I

13353-04-3

CH3-(OCH2)7-OCH3

J

13352-77-7

CH3-(OCH2)6-OCH3

Conditions
ConditionsYield
sulfuric acid In water at 100℃; for 12h; Product distribution / selectivity;
50-00-0

formaldehyd

534-15-6

1,1-dimethoxyethane

A

C11H24O10

B

C13H28O12

C

13353-03-2

bis-methoxymethoxy-methane

D

628-90-0

bis(methoxymethyl)ether

F

13352-78-8

CH3-(OCH2)8-OCH3

G

54261-86-8

Methoxymethoxymethoxymethoxymethoxy-methoxymethoxymethoxymethoxymethoxymethoxy-methane

I

13353-04-3

CH3-(OCH2)7-OCH3

J

13352-77-7

CH3-(OCH2)6-OCH3

Conditions
ConditionsYield
Amberlite IR 120 at 100℃; for 8h; Product distribution / selectivity;
50-00-0

formaldehyd

109-87-5

Dimethoxymethane

A

110-88-3

1,3,5-Trioxan

B

C11H24O10

C

C13H28O12

D

13353-03-2

bis-methoxymethoxy-methane

E

628-90-0

bis(methoxymethyl)ether

G

13352-78-8

CH3-(OCH2)8-OCH3

H

54261-86-8

Methoxymethoxymethoxymethoxymethoxy-methoxymethoxymethoxymethoxymethoxymethoxy-methane

I

13353-04-3

CH3-(OCH2)7-OCH3

J

C14H30O13

K

C15H32O14

L

13352-77-7

CH3-(OCH2)6-OCH3

Conditions
ConditionsYield
With sulfuric acid at 55 - 115℃; Inert atmosphere;
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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-21-31576854/57171705 / 57171706

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    Manufacturer,strong R&D,professional team Storage:Store in a cool, dry place. Store in a tightly closed container. Package:according to your requirement Application:ZhiShang Chemical is owned by ZhiShang Group, is a professional new-type chemicals en

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