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CAS No.: | 13568-40-6 |
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Name: | Lithium molybdate(VI) |
Article Data: | 64 |
Molecular Structure: | |
Formula: | Li2MoO4 |
Molecular Weight: | 173.82 |
Synonyms: | Lithiummolybdate(VI) (Li2MoO4) (6CI,7CI);Molybdate (MoO42-), dilithium, (T-4)- (9CI);Molybdic acid (H2MoO4), dilithium salt (8CI);Dilithium molybdate (Li2MoO4);Dilithium molybdenum tetraoxide;Dilithium tetraoxomolybdate(2-);Lithiummolybdate;Lithium molybdate (Li2MoO4);Lithium molybdenum oxide (Li2MoO4); |
EINECS: | 236-977-7 |
Density: | 2.66 g/mL at 25 °C(lit.) |
Melting Point: | 705 °C |
Solubility: | soluble in water |
Appearance: | white to almost white crystalline powder |
Hazard Symbols: | Xi |
Risk Codes: | 36/37/38 |
Safety: | 26-37/39 |
PSA: | 80.26000 |
LogP: | -0.47520 |
Conditions | Yield |
---|---|
In water pH 7-7.5; 2 h boiling on water bath; filtering, drying; | 94% |
In water pH 7-7.5; 2 h boiling on water bath; filtering, drying; | 94% |
In neat (no solvent, solid phase) for 5 mo; not isolated, detected by XRD; | |
Heating; |
Conditions | Yield |
---|---|
In water H2MoO4*H2O (1 mmol) added to aq. soln. of LiOH*H2O (2 mmol), stirred for20 min; filtered, allowed to stant (air) at room temp. for 1 week; | 87% |
Conditions | Yield |
---|---|
MoO3:Li2CO3 (1:1); reaction begins at 300°C; | |
heating (823 K); |
Conditions | Yield |
---|---|
byproducts: Li; above 1150 °C, Li2O a Mo crucible; | |
at 1320°C, in Mo vessel; | |
at 1320°C, in Mo vessel; |
Conditions | Yield |
---|---|
In neat (no solvent) mixing, firing in air (740K) in a silica crucible fo 48 h with one intermediate grinding; | |
In neat (no solvent) mixing of powdered and dried stoichiometric amounts of starting materials, firing in air at around 740 K for 48 h; |
Conditions | Yield |
---|---|
at 350°C, Li2O:MoO3 mol ratio beetween 1:1 and 2:1; | |
at 350°C, Li2O:MoO3 mol ratio beetween 1:1 and 2:1; |
Conditions | Yield |
---|---|
In water standing (some d); recrystn. (H2O); | |
In neat (no solvent) byproducts: H2O; ground under ambient conditions in air for 1 min, allowed to dry at roomtemp. for ca 1 h; |
Conditions | Yield |
---|---|
With ammonium molybdate In water | |
With ammonium molybdate In water |
Conditions | Yield |
---|---|
above 1150°C; | |
above 1150°C; |
Conditions | Yield |
---|---|
In not given byproducts: CaSO4; equilibrium react. at 25°C;; | |
In not given byproducts: CaSO4; equilibrium react. at 25°C;; |
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The CAS register number of Lithium molybdate(VI) is 13568-40-6. It also can be called as Dilithium molybdate and the IUPAC name about this chemical is dilithium dioxido(dioxo)molybdenum. The molecular formula about this chemical is Li2MoO4 and the molecular weight is 173.82. It belongs to the following product categories, such as Alternative Energy; Catalysis and Inorganic Chemistry; Electrode MaterialsChemical Synthesis; Materials Science; Molybdenum and so on.
Physical properties about Lithium molybdate(VI) are: (1)#H bond acceptors: 4; (2)#H bond donors: 2; (3)Polar Surface Area: 74.6Å2; (4)H-Bond Acceptor: 4; (5)Exact Mass: 175.917074; (6)MonoIsotopic Mass: 175.917074; (7)Topological Polar Surface Area: 80.3; (8)Heavy Atom Count: 7; (9)Complexit: 62.2; (10)Covalently-Bonded Unit Count: 3.
When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1)SMILES: [Li+].[Li+].[O-][Mo]([O-])(=O)=O
(2)InChI: InChI=1/2Li.Mo.4O/q2*+1;;;;2*-1/r2Li.MoO4/c;;2-1(3,4)5/q2*+1;-2
(3)InChIKey: NMHMDUCCVHOJQI-FFXFYZCHAF
(4)Std. InChI: InChI=1S/2Li.Mo.4O/q2*+1;;;;2*-1
(5)Std. InChIKey: NMHMDUCCVHOJQI-UHFFFAOYSA-N