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CAS No.: | 13760-02-6 |
---|---|
Name: | DIIODOSILANE |
Article Data: | 10 |
Molecular Structure: | |
Formula: | H2I2Si |
Molecular Weight: | 283.91 |
Synonyms: | Diiodosilane; |
Density: | 2.834 g/mL at 25 °C(lit.) |
Melting Point: | -1°C |
Boiling Point: | 153.7 °C at 760 mmHg |
Flash Point: | 101 °F |
Appearance: | Clear liquid |
Hazard Symbols: | C |
Risk Codes: | 10-14-20/21/22-34 |
Safety: | 16-26-27-28-36/37/39-45 |
PSA: | 0.00000 |
LogP: | 0.85520 |
Conditions | Yield |
---|---|
In pentane at -70 - 35℃; for 16h; Temperature; Solvent; Inert atmosphere; Large scale; | 77% |
at 40℃; under 1277.21 - 2311.54 Torr; for 0.08h; Temperature; | 45.3 g |
phosphorous
iodosilane
A
diiodosilane
B
P(SiH3)I2
C
monosilane
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: H2; heating in evacuated, sealed tube to 100°C;; |
phosphorus
iodosilane
A
diiodosilane
B
P(SiH3)I2
C
monosilane
Conditions | Yield |
---|---|
byproducts: H2; at 100°C; |
Conditions | Yield |
---|---|
byproducts: H2; at 20°C; | A <1 B n/a C n/a D n/a |
hydrogen iodide
monosilane
A
diiodosilane
B
triiodo silane
C
silicon tetraiodide
D
iodosilane
Conditions | Yield |
---|---|
aluminium(III) iodide In neat (no solvent) reaction at 80°C and 500 Torr;; fractional distillation and condensation;; | |
aluminium(III) iodide In neat (no solvent) reaction at 80°C and 500 Torr;; fractional distillation and condensation;; |
Conditions | Yield |
---|---|
In not given according to Fritz, G., Kummer D., Chem. Ber., 94 (1961) p. 1143; at -40°C; |
Conditions | Yield |
---|---|
In toluene at 20 - 29℃; for 18h; Temperature; Solvent; |
diiodosilane
bis(trifluoromethylseleno)mercury
bis(trifluoromethylseleno)silane
Conditions | Yield |
---|---|
In decalin stirring, 20°C, 1 h; | 78% |
diiodosilane
2S-benzyloxymethyl-4S acetoxy-1,3 dioxolane
B
2S-benzyloxymethyl-4S-iodo-1,3 dioxolane
Conditions | Yield |
---|---|
In dichloromethane; toluene |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: SiH4, Si2H6, H2; at ambient temp.;; | |
In neat (no solvent) byproducts: SiH4, Si2H6, H2; at ambient temp.;; |
The Silane, diiodo-(7CI,8CI,9CI) is an organic compound with the formula H2I2Si. The systematic name of this chemical is diiodosilane. With the CAS registry number 13760-02-6, it is also named as silane, diiodo-. The product's categories are Protecting and Derivatizing Reagents; Protection and Derivatization; Silicon-Based.
Physical properties about Silane, diiodo-(7CI,8CI,9CI) are: (1)Boiling Point: 153.7 °C at 760 mmHg ; (2)Vapour Pressure: 4.21 mmHg at 25°C.
When you are using this chemical, please be cautious about it as the following:
It is flammable and harmful by inhalation, in contact with skin and if swallowed. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). Please keep away from sources of ignition - No smoking and take off immediately all contaminated clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical reacts violently with water and can cause burns. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: I[SiH2]I
(2)InChI: InChI=1/H2I2Si/c1-3-2/h3H2
(3)InChIKey: AIHCVGFMFDEUMO-UHFFFAOYAW
(4)Std. InChI: InChI=1S/H2I2Si/c1-3-2/h3H2
(5)Std. InChIKey: AIHCVGFMFDEUMO-UHFFFAOYSA-N