CAS No.142-22-3,Diallyl 2,2'-oxydiethyl dicarbonate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	142-22-3
Name:	Diallyl 2,2'-oxydiethyl dicarbonate
Article Data:	7

Formula:	C12H18 O7
Molecular Weight:	274.271
Synonyms:	2,5,8,10-Tetraoxatridec-12-enoicacid, 9-oxo-, 2-propenyl ester (9CI); Carbonic acid, allyl ester, diester withdiethylene glycol (6CI,7CI); Carbonic acid, oxydiethylene diallyl ester (8CI);01M; Allyl diglycol carbonate; Brite 55; CR 39R; Carbonic acid,oxydi-2,1-ethanediyl di-2-propenyl ester; Diallyl diglycol carbonate; Diallyloxydiethylene dicarbonate; Diethylene glycol diallyl dicarbonate; Diethyleneglycol, bis(allyl carbonate); High ADC-CR 39; Hoya HL; NSC 5246; Nouryset 200;RAV 7; RAV 7AT; RAV 7N; TS 16; Transallyl CR 39
EINECS:	205-528-7
Density:	1.129g/cm³
Melting Point:	−4 °C(lit.)
Boiling Point:	161 °C2 mm Hg(lit.)
Flash Point:	145.3°C
Solubility:	2.36g/L at 20℃
Appearance:	liquid
Hazard Symbols:
Risk Codes:	22-36/37/38
Safety:	Poison by intraperitoneal route. A human skin irritant. The allyl compounds are generally toxic. Experimental reproductive effects. Combustible when exposed to heat or flame; can react with oxidizing material. To fight fire, use water mist or spray, foam, CO₂, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.
PSA:	80.29000
LogP:	1.68140

Synthetic route

: 14666-78-5
Peroxydikohlensaeure-diethylester

: 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester

Conditions

Conditions	Yield
at 40℃; Equilibrium constant; Zersetzung;
at 50℃; Equilibrium constant; Zersetzung;
at 60℃; Equilibrium constant; Zersetzung;

: 105-64-6
diisopropyl peroxydicarbonate

: 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester

Conditions

Conditions	Yield
at 40℃; Zersetung;
at 50℃; Zersetung;
at 60℃; Zersetung;

: 106-75-2
diethylene glycol bischloroformate

: 107-18-6
allyl alcohol

: 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester

Conditions

Conditions	Yield
With calcium carbonate at 50 - 90℃;

: 2937-50-0
Allyl chloroformate

: 111-46-6
diethylene glycol

: 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester

Conditions

Conditions	Yield
With pyridine
With pyridine

: 124-38-9
carbon dioxide

: 107-05-1
3-chloroprop-1-ene

: 111-46-6
diethylene glycol

: 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester

Conditions

Conditions	Yield
With 2-cyclohexyl-1,1,3,3-tetramethylguanidine 1.) CH3CN 80 psi, 2.) 80 psi, 55 deg C, 14 h; Yield given. Multistep reaction;

...Expand

: 142-22-3
2,5,8-Trioxanonanedioic acid di-2-propenyl ester

Reaxys ID: 15741496: Reaxys ID: 15741496

Conditions

Conditions	Yield
1,1-bis(tert-hexylperoxy)-3,3,5-trimethycyclohexane at 110 - 130℃; for 4h; Product distribution / selectivity;

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Chemistry

Molecular Formula: C₁₂H₁₈O₇
Molar mass: 274.27 g/mol
EINECS: 205-528-7
Density: 1.129 g/cm³
Flash Point: 145.3 °C
Index of Refraction: 1.454
Boiling Point: 337.4 °C at 760 mmHg
Vapour Pressure: 0.000105 mmHg at 25°C
Melting point: -4 °C(lit.)
Appearance: Liquid
Stable: SStability Combustible. Incompatible with strong oxidizing agents
Product categories of Allyl diglycol carbonate (142-22-3): Monomer
Structure of Allyl diglycol carbonate (142-22-3):

XLogP3-AA: 2
H-Bond Donor: 0
H-Bond Acceptor: 7
Systematic Name: Allyl 2-(2-allyloxycarbonyloxyethoxy)ethyl carbonate
SMILES: O=C(OCCOCCOC(=O)OC\C=C)OC\C=C
InChI: InChI=1/C12H18O7/c1-3-5-16-11(13)18-9-7-15-8-10-19-12(14)17-6-4-2/h3-4H,1-2,5-10H2
InChIKey: JHQVCQDWGSXTFE-UHFFFAOYAG
Std. InChI: InChI=1S/C12H18O7/c1-3-5-16-11(13)18-9-7-15-8-10-19-12(14)17-6-4-2/h3-4H,1-2,5-10H2
Std. InChIKey: JHQVCQDWGSXTFE-UHFFFAOYSA-N

Uses

Allyl diglycol carbonate (142-22-3) can be used for the production of eyeglasses.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	270mg/kg (270mg/kg)	LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES KIDNEY, URETER, AND BLADDER: "CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)"	Journal of Pharmacology and Experimental Therapeutics. Vol. 90, Pg. 338, 1947.
mouse	LD50	oral	279mg/kg (279mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	Toksikologicheskii Vestnik. Vol. (2), Pg. 35, 1999.
rat	LC50	inhalation	1205mg/m3 (1205mg/m3)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION	Toksikologicheskii Vestnik. Vol. (2), Pg. 35, 1999.
rat	LD50	oral	426mg/kg (426mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	Toksikologicheskii Vestnik. Vol. (2), Pg. 35, 1999

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. A human skin irritant. The allyl compounds are generally toxic. Experimental reproductive effects. Combustible when exposed to heat or flame; can react with oxidizing material. To fight fire, use water mist or spray, foam, CO₂, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.

Hazard Codes: Xn
Risk Statements:
22: Harmful if swallowed
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection

Specification

Allyl diglycol carbonate (142-22-3) also can be called Diallyl oxydi-2,1-ethanediyl biscarbonate ; Baryotrak ; Seiko Plax ; Oxydiethane-2,1-diyl diprop-2-en-1-yl biscarbonate and carbonic acid, oxydi-2,1-ethanediyl di-2-propen-1-yl ester .