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Basic Information
| CAS No.: | 1569-01-3 | |
|---|---|---|
| Name: | 1-PROPOXY-2-PROPANOL | |
| Molecular Structure: | ||
|
|
||
| Formula: | C6H14 O2 | |
| Molecular Weight: | 118.176 | |
| Synonyms: | 1,2-Propyleneglycol 1-propyl ether; 1-Propoxy-2-propanol; Arcosolv PNP | |
| EINECS: | 250-069-8 | |
| Density: | 0.885 g/mL at 25 °C(lit.) | |
| Melting Point: | -80 C | |
| Boiling Point: | 140 - 160 C | |
| Flash Point: | 48 C | |
| Solubility: | miscible | |
| Appearance: | clear liquid | |
| Hazard Symbols: | UN NO. | |
| Risk Codes: | R10; R36/37/38 | |
| Transport Information: | HAZARD | |
| PSA: | 29.46000 | |
| LogP: | 0.79380 | |
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Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With Al2O3/MgO composite at 120℃; Inert atmosphere; | 34.4% |
| With KAcMIMOH at 60℃; for 4h; | |
| With hematite at 160℃; for 8h; Autoclave; |
- 71-23-8
propan-1-ol
- 75-56-9, 16033-71-9
methyloxirane
A
- 10215-30-2
2-propoxy-1-propanol
B
- 1569-01-3
1-(1-propyloxy)propan-2-ol
Conditions
| Conditions | Yield |
|---|---|
| at 100 - 200℃; | |
| at 180 - 205℃; | |
| With sulfuric acid Yield given. Yields of byproduct given; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With hydrogen; 5percent Pd/C(en) In tetrahydrofuran at 20℃; for 2.5h; Catalytic hydrogenation; Title compound not separated from byproducts.; |
- 57-55-6
propylene glycol
A
- 71-23-8
propan-1-ol
B
- 111-43-3
Dipropyl ether
C
- 10215-30-2
2-propoxy-1-propanol
D
- 1569-01-3
1-(1-propyloxy)propan-2-ol
Conditions
| Conditions | Yield |
|---|---|
| With trifluorormethanesulfonic acid; hydrogen; [{CpRu(CO)2}2(μ-H)](+)*OTf(-); cyclopenta-1,3-diene In sulfolane at 110℃; under 39003.1 Torr; for 30h; Product distribution; | A 54 % Chromat. B 15 % Chromat. C n/a D n/a |
...Expand
- 57-55-6
propylene glycol
A
- 71-23-8
propan-1-ol
B
- 4359-46-0
2-ethyl-4-methyl-1,3-dioxolane
C
- 111-43-3
Dipropyl ether
D
- 10215-30-2
2-propoxy-1-propanol
E
- 1569-01-3
1-(1-propyloxy)propan-2-ol
F
- 123-38-6
propionaldehyde
Conditions
| Conditions | Yield |
|---|---|
| With bis(dicarbonyl)(μ-hydrido)(pentamethylcyclopentadiene)ruthenium trifluoromethanesulfonate; trifluorormethanesulfonic acid; hydrogen In sulfolane at 110℃; under 38787.1 Torr; for 30h; Mechanism; Kinetics; Solvent; Pressure; Concentration; Temperature; Time; regioselective reaction; | A 54 %Chromat. B n/a C n/a D n/a E n/a F n/a |
...Expand
- 57-55-6
propylene glycol
A
- 71-23-8
propan-1-ol
B
- 106-36-5
propyl propionate
C
- 74-98-6
propane
D
- 10215-30-2
2-propoxy-1-propanol
E
- 1569-01-3
1-(1-propyloxy)propan-2-ol
F
- 802294-64-0
propionic acid
G
- 108-67-8
1,3,5-trimethyl-benzene
Conditions
| Conditions | Yield |
|---|---|
| With [C6H3-2,6-(OP(tBu)2)2]IrH2; trifluorormethanesulfonic acid; hydrogen In 1,4-dioxane at 125℃; under 5171.62 Torr; Autoclave; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With water at 80℃; for 24h; Equilibrium constant; Sealed tube; |
- 1569-01-3
1-(1-propyloxy)propan-2-ol
- 1056233-21-6
N’-(5-bromo-6-hydroxy-2-methyl-3-pyridyl)-N-ethyl-N-methyl-formamidine
Conditions
| Conditions | Yield |
|---|---|
| With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20 - 40℃; for 1.66667h; Inert atmosphere; | 95% |
| With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere; | 95% |
Conditions
| Conditions | Yield |
|---|---|
| With [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II); methacrylic acid methyl ester In toluene at 140℃; under 13689.1 Torr; for 4h; Autoclave; Inert atmosphere; | 71% |
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1-PROPOXY-2-PROPANOL
Chemistry
Synonyms: PNP;2-Propanol, 1-propoxy-;PROPYLENE GLYCOL PROPYL ETHER;PROPYLENE GLYCOL MONOPROPYL ETHER;PROPYLENE GLYCOL NORMAL PROPYL ETHER;ethermonopropyliquenormaldupropyleneglycol ;1-propoxy-2-propano;1-propoxy-propan-2-ol;
The Molecular formula of 1-PROPOXY-2-PROPANOL(1569-01-3): C6H14O2
The Molecular Weight of 1-PROPOXY-2-PROPANOL(1569-01-3): 118.17
Molecular Structure :
EINECS: 216-372-4
Boiling point: 140-160 °C(lit.)
Flash point: 119 °F
density: 0.885 g/mL at 25 °C(lit.)
refractive index: n20/D 1.411(lit.)
The Molecular formula of 1-PROPOXY-2-PROPANOL(1569-01-3): C6H14O2
The Molecular Weight of 1-PROPOXY-2-PROPANOL(1569-01-3): 118.17
Molecular Structure :
EINECS: 216-372-4
Boiling point: 140-160 °C(lit.)
Flash point: 119 °F
density: 0.885 g/mL at 25 °C(lit.)
refractive index: n20/D 1.411(lit.)
Toxicity Data With Reference
| 1. | skn-rbt 500 mg | VHTODE Veterinary and Human Toxicology. 30 (1988),126. | ||
| 2. | eye-rbt 100 mg MOD | VHTODE Veterinary and Human Toxicology. 30 (1988),126. | ||
| 3. | orl-rat LD50:2504 mg/kg | VHTODE Veterinary and Human Toxicology. 30 (1988),126. | ||
| 4. | skn-rbt LD50:3550 mg/kg | 38MKAJ Pattys Industrial Hygiene and Toxicology. 2C (1982),3983. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Moderately toxic by ingestion and skin contact. A skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
The Hazard Codes of 1-PROPOXY-2-PROPANOL(1569-01-3):
Xi
The Risk Statements information of 1-PROPOXY-2-PROPANOL(1569-01-3):
10: Flammable
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of 1-PROPOXY-2-PROPANOL(1569-01-3):
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
RIDADR: UN 3271 3/PG 3
The Hazard Codes of 1-PROPOXY-2-PROPANOL(1569-01-3):
Xi The Risk Statements information of 1-PROPOXY-2-PROPANOL(1569-01-3):
10: Flammable
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of 1-PROPOXY-2-PROPANOL(1569-01-3):
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
RIDADR: UN 3271 3/PG 3