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157-06-2

Basic Information
CAS No.: 157-06-2
Name: D(-)-Arginine
Article Data: 26
Molecular Structure:
Molecular Structure of 157-06-2 (D(-)-Arginine)
Formula: C6H14N4O2
Molecular Weight: 174.203
Synonyms: Arginine,D- (8CI);(R)-Arginine;D-2-Amino-5-guanidinovalerate;(2R)-2-amino-5-(carbamimidamido)pentanoic acid;
EINECS: 205-866-5
Density: 1.46 g/cm3
Melting Point: 226 °C (dec.)(lit.)
Boiling Point: 409.1 °C at 760 mmHg
Flash Point: 201.2 °C
Solubility: soluble in water
Appearance: white to light yellow crystal powder
Hazard Symbols: IrritantXi
Risk Codes: 36-36/37/38-20/21/22
Safety: 26-36
PSA: 125.22000
LogP: 0.55280
Synthetic route
2389-86-8

(2R)-2-acetamido-5-guanidino-pentanoate

157-06-2

D-arginine

Conditions
ConditionsYield
With hydrogenchloride

A

157-06-2

D-arginine

B

74-79-3

L-arginine

(R)-5-Guanidino-2-[(1H-indole-3-carbonyl)-amino]-pentanoic acid

A

771-50-6

1H-indole-3-carboxylic acid

B

157-06-2

D-arginine

Conditions
ConditionsYield
With hydrogenchloride at 120℃; for 12h; Product distribution;
DL-arginine

DL-arginine

157-06-2

D-arginine

Conditions
ConditionsYield
With arginase
copper (II)-compound of D-ornithine

copper (II)-compound of D-ornithine

O-methyl-isothiourea

O-methyl-isothiourea

157-06-2

D-arginine

Conditions
ConditionsYield
With sodium hydroxide anschliessend mit H2S;
carbonate dl-arginine

carbonate dl-arginine

A

157-06-2

D-arginine

B

d-ornithine , urea

d-ornithine , urea

Conditions
ConditionsYield
With water at 37℃; bei der Einwirkung von Leberpresssaft (Arginase) bleibt das l-Arginin bestehen, waehrend das d-Arginin gespalten wird;

neamphamide A

157-06-2

D-arginine

Conditions
ConditionsYield
With hydrogenchloride In water at 107℃; for 18.5h;

(-)-leptoclinidamine B trifluoroacetic acid salt

157-06-2

D-arginine

Conditions
ConditionsYield
With hydrogenchloride In water at 100℃; for 8h;

neamphamide B

A

24830-94-2

D-allo-threonine

B

61-90-5

L-leucine

C

70-47-3

L-asparagine

D

157-06-2

D-arginine

E

gamma-Glutamylmethylamide

F

3105-95-1

pipecolinic acid

Conditions
ConditionsYield
With hydrogenchloride In water at 120℃; for 16h;

neamphamide C

A

24830-94-2

D-allo-threonine

B

61-90-5

L-leucine

C

70-47-3

L-asparagine

D

157-06-2

D-arginine

E

6753-62-4

N-methyl-L-glutamic acid

F

3105-95-1

pipecolinic acid

Conditions
ConditionsYield
With hydrogenchloride In water at 120℃; for 16h;
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Chemistry

Molecular Structure of D-Arginine (CAS NO.157-06-2):

Empirical Formula: C6H14N4O2
Molecular Weight: 174.201
IUPAC Name: 2-amino-5-(diaminomethylideneamino)pentanoic acid 
H bond acceptors: 6
H bond donors: 7
Freely Rotating Bonds: 6
Polar Surface Area: 48.38 Å2
Index of Refraction: 1.601
Molar Refractivity: 40.69 cm3
Molar Volume: 118.7 cm3
Surface Tension: 66.1 dyne/cm
Density: 1.46 g/cm3
Flash Point: 201.2 °C
Enthalpy of Vaporization: 72.55 kJ/mol
Boiling Point: 409.1 °C at 760 mmHg
Vapour Pressure: 7.7E-08 mmHg at 25°C
EINECS: 205-866-5
Melting point: 226 °C (dec.)(lit.)
Storage temp.: Store at 0-5
Water Solubility: Soluble
Sensitive: Air Sensitive
Appearance: white to light yellow crystal powder
Product Categories: Amino Acids Derivatives; chiral; Protected amino acid & peptides; Arginine [Arg, R]; Amino Acids and Derivatives; alpha-Amino Acids; Amino Acids; Biochemistry; for Resolution of Acids; Optical Resolution; Synthetic Organic Chemistry; Amino Acids

Safety Profile

The Hazard Codes: IrritantXi,HarmfulXn
The Risk Statements information of D-Arginine (CAS NO.157-06-2):
36: Irritating to the eyes
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
WGK Germany: 3
RTECS: CF1934220
F: 9

Specification

  D-Arginine , with CAS number of 157-06-2, can be called R-(-)-arginine ; (r)-2-amino-5-guanidinopentanoic acid ; arginine, d- ; h-d-arg-oh ; d-arg ; d-(-)-arginine ; d-arginine . It is a white to light yellow crystal powde. D-Arginine (CAS NO.157-06-2) is used for biochemical research.