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1669-98-3

Basic Information
CAS No.: 1669-98-3
Name: ETHYLMETHYLSULPHOXIDE
Article Data: 38
Molecular Structure:
Molecular Structure of 1669-98-3 (ETHYLMETHYLSULPHOXIDE)
Formula: C3H8 O S
Molecular Weight: 92.1619
Synonyms: Sulfoxide,ethyl methyl (6CI,7CI,8CI); (?à)-Ethyl methyl sulfoxide; Ethyl methyl sulfoxide; Methyl ethyl sulfoxide
Density: 1.052g/cm3
Boiling Point: 198.2°Cat760mmHg
Flash Point: 73.7°C
PSA: 36.28000
LogP: 1.25050
Synthetic route
624-89-5

Ethyl methyl sulfide

1669-98-3

Ethyl methyl sulfoxide

Conditions
ConditionsYield
With dihydrogen peroxide In neat (no solvent) at 20℃; for 1h; chemoselective reaction;97%
With dihydrogen peroxide In neat (no solvent) at 20℃; for 0.383333h; chemoselective reaction;92%
With dihydrogen peroxide In neat (no solvent) at 20℃; for 0.416667h; Green chemistry; chemoselective reaction;91%
35453-05-5

methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane

A

1669-98-3

Ethyl methyl sulfoxide

B

7715-02-8

(2-methylsulfanylvinyl)benzene

Conditions
ConditionsYield
With ethylmagnesium chloride In tetrahydrofuran for 1h; Ambient temperature;A n/a
B 82%
84918-82-1

(E)-1-(p-chlorophenyl)-2-(methylsulfinyl)-2-(methylthio)ethene

A

1669-98-3

Ethyl methyl sulfoxide

B

82525-10-8

1-chloro-4-(2-methylsulfanylvinyl)benzene

Conditions
ConditionsYield
With ethylmagnesium chloride In tetrahydrofuran for 1h; Ambient temperature;A 37%
B 79%
624-89-5

Ethyl methyl sulfide

A

1669-98-3

Ethyl methyl sulfoxide

B

594-43-4

ethyl methyl sulfone

Conditions
ConditionsYield
With C30H24N2O7W; dihydrogen peroxide In dichloromethane; water for 1h; Reflux;A 30%
B 70%
With dihydrogen peroxide; [MoO(O2)2(C9H6ON)][PPh4] In dichloromethane at 40℃; for 1h; Product distribution; Further Variations:; Catalysts; Reagents;A 50 % Chromat.
B 48 % Chromat.
With tert.-butylhydroperoxide; aluminum tri-tert-butoxide In benzeneA n/a
B 20 % Chromat.

1-((E)-2-Methanesulfinyl-2-methylsulfanyl-vinyl)-4-methyl-benzene

A

1669-98-3

Ethyl methyl sulfoxide

B

69153-05-5

1-Methyl-4-((Z)-2-methylsulfanyl-vinyl)-benzene

Conditions
ConditionsYield
With ethylmagnesium chloride In tetrahydrofuran for 1h; Ambient temperature;A n/a
B 60%

1-methylsulfinyl-1-methylthio-2-(p-dimethylaminophenyl)ethylene

A

1669-98-3

Ethyl methyl sulfoxide

B

Dimethyl-[4-((Z)-2-methylsulfanyl-vinyl)-phenyl]-amine

Conditions
ConditionsYield
With ethylmagnesium chloride In tetrahydrofuran for 1h; Ambient temperature;A n/a
B 41%
126218-83-5, 146235-11-2, 7321-58-6

1-bromo-2-(methylsulfinyl)benzene

925-90-6

ethylmagnesium bromide

A

573-57-9

1,4-dihydronaphthalene-1,4-epoxide

B

1669-98-3

Ethyl methyl sulfoxide

Conditions
ConditionsYield
1.) THF, 60 deg C, 11 h; Yield given. Multistep reaction. Yields of byproduct given;
108-24-7

acetic anhydride

61272-23-9, 130767-77-0, 130767-78-1

3-O-(β-D-galactopyranosyl)-D-arabinose

74-88-4

methyl iodide

A

1669-98-3

Ethyl methyl sulfoxide

B

100758-68-7

1,3,4-tri-O-acetyl-2,5-di-O-methyl-D-arabinitol

D

19318-22-0, 19318-27-5, 84885-38-1, 84925-47-3, 100758-67-6

1,3,5-tri-O-acetyl-2,4-di-O-methyl-D-arabinitol

E

1774-47-6

trimethylsulfoxonium iodide

Conditions
ConditionsYield
With sodium tetrahydroborate; perchloric acid; trimethylsulfoxonium iodide; trifluoroacetic acid In dimethyl sulfoxide Product distribution; Improved methylation analysis; other saccharides;
92695-35-7

(η5-cyclopentadienyl)Re(NO)(P(C6H5)3)(CF3SO3)

1669-98-3

Ethyl methyl sulfoxide

351533-36-3, 351533-37-4

[(η5-C5H5)Re(NO)(PPh3)(S(=O)(Me)Et)]TfO

Conditions
ConditionsYield
In chlorobenzene stirred for 5 h at room temp.; ppt. filtered off, washed (PhCl, ether), dried (vac.); obtained as a mixt. of diastereomers;93%
10025-99-7

potassium tetrachloroplatinate(II)

1669-98-3

Ethyl methyl sulfoxide

1005350-90-2

K[Pt(ethylmethylsulfoxide)Cl3]

Conditions
ConditionsYield
In water byproducts: KCl; aq. soln. of Pt compd. mixed with ligand (1:1), stirred at room temp. for 24 h; filtered, evapd., treated (acetone), filtered, evapd., washed (Et2O), dried (vac.);75%
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