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| CAS No.: | 1669-98-3 |
|---|---|
| Name: | ETHYLMETHYLSULPHOXIDE |
| Molecular Structure: | |
|
|
|
| Formula: | C3H8 O S |
| Molecular Weight: | 92.1619 |
| Synonyms: | Sulfoxide,ethyl methyl (6CI,7CI,8CI); (?à)-Ethyl methyl sulfoxide; Ethyl methyl sulfoxide; Methyl ethyl sulfoxide |
| Density: | 1.052g/cm3 |
| Boiling Point: | 198.2°Cat760mmHg |
| Flash Point: | 73.7°C |
| PSA: | 36.28000 |
| LogP: | 1.25050 |
- 483366-12-7(2S,4R)-1-Boc-2-cyano-4-hydroxypyrrolidine
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- 50288-62-5threo-Phenyl-2-piperidyl acetamide
- 82993-81-5D-threo-Ritalinic acid hydrochloride
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- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 211914-50-0N-[[2-[[[4-(Aminoiminomethyl)phenyl]amino]methyl]-1-methyl-1H-benzimidazol-5-yl]carbonyl]-N-(2-pyridinyl)-beta-alanine ethyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide In neat (no solvent) at 20℃; for 1h; chemoselective reaction; | 97% |
| With dihydrogen peroxide In neat (no solvent) at 20℃; for 0.383333h; chemoselective reaction; | 92% |
| With dihydrogen peroxide In neat (no solvent) at 20℃; for 0.416667h; Green chemistry; chemoselective reaction; | 91% |
- 35453-05-5
methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane
A
- 1669-98-3
Ethyl methyl sulfoxide
B
- 7715-02-8
(2-methylsulfanylvinyl)benzene
| Conditions | Yield |
|---|---|
| With ethylmagnesium chloride In tetrahydrofuran for 1h; Ambient temperature; | A n/a B 82% |
- 84918-82-1
(E)-1-(p-chlorophenyl)-2-(methylsulfinyl)-2-(methylthio)ethene
A
- 1669-98-3
Ethyl methyl sulfoxide
B
- 82525-10-8
1-chloro-4-(2-methylsulfanylvinyl)benzene
| Conditions | Yield |
|---|---|
| With ethylmagnesium chloride In tetrahydrofuran for 1h; Ambient temperature; | A 37% B 79% |
| Conditions | Yield |
|---|---|
| With C30H24N2O7W; dihydrogen peroxide In dichloromethane; water for 1h; Reflux; | A 30% B 70% |
| With dihydrogen peroxide; [MoO(O2)2(C9H6ON)][PPh4] In dichloromethane at 40℃; for 1h; Product distribution; Further Variations:; Catalysts; Reagents; | A 50 % Chromat. B 48 % Chromat. |
| With tert.-butylhydroperoxide; aluminum tri-tert-butoxide In benzene | A n/a B 20 % Chromat. |
A
- 1669-98-3
Ethyl methyl sulfoxide
B
- 69153-05-5
1-Methyl-4-((Z)-2-methylsulfanyl-vinyl)-benzene
| Conditions | Yield |
|---|---|
| With ethylmagnesium chloride In tetrahydrofuran for 1h; Ambient temperature; | A n/a B 60% |
A
- 1669-98-3
Ethyl methyl sulfoxide
| Conditions | Yield |
|---|---|
| With ethylmagnesium chloride In tetrahydrofuran for 1h; Ambient temperature; | A n/a B 41% |
- 110-00-9
furan
- 126218-83-5, 146235-11-2, 7321-58-6
1-bromo-2-(methylsulfinyl)benzene
- 925-90-6
ethylmagnesium bromide
A
- 573-57-9
1,4-dihydronaphthalene-1,4-epoxide
B
- 1669-98-3
Ethyl methyl sulfoxide
| Conditions | Yield |
|---|---|
| 1.) THF, 60 deg C, 11 h; Yield given. Multistep reaction. Yields of byproduct given; |
- 108-24-7
acetic anhydride
- 61272-23-9, 130767-77-0, 130767-78-1
3-O-(β-D-galactopyranosyl)-D-arabinose
- 74-88-4
methyl iodide
A
- 1669-98-3
Ethyl methyl sulfoxide
B
- 100758-68-7
1,3,4-tri-O-acetyl-2,5-di-O-methyl-D-arabinitol
C
- 19285-93-9, 19318-49-1, 20316-14-7, 25665-99-0, 53403-07-9, 81600-01-3, 83290-15-7, 103729-41-5, 114183-58-3, 25521-30-6
1,5-di-O-acetyl-2,3,4,6-tetra-O-methyl-D-galactitol
D
- 19318-22-0, 19318-27-5, 84885-38-1, 84925-47-3, 100758-67-6
1,3,5-tri-O-acetyl-2,4-di-O-methyl-D-arabinitol
E
- 1774-47-6
trimethylsulfoxonium iodide
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate; perchloric acid; trimethylsulfoxonium iodide; trifluoroacetic acid In dimethyl sulfoxide Product distribution; Improved methylation analysis; other saccharides; |
- 92695-35-7
(η5-cyclopentadienyl)Re(NO)(P(C6H5)3)(CF3SO3)
- 1669-98-3
Ethyl methyl sulfoxide
- 351533-36-3, 351533-37-4
[(η5-C5H5)Re(NO)(PPh3)(S(=O)(Me)Et)]TfO
| Conditions | Yield |
|---|---|
| In chlorobenzene stirred for 5 h at room temp.; ppt. filtered off, washed (PhCl, ether), dried (vac.); obtained as a mixt. of diastereomers; | 93% |
- 10025-99-7
potassium tetrachloroplatinate(II)
- 1669-98-3
Ethyl methyl sulfoxide
- 1005350-90-2
K[Pt(ethylmethylsulfoxide)Cl3]
| Conditions | Yield |
|---|---|
| In water byproducts: KCl; aq. soln. of Pt compd. mixed with ligand (1:1), stirred at room temp. for 24 h; filtered, evapd., treated (acetone), filtered, evapd., washed (Et2O), dried (vac.); | 75% |
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