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CAS No.: | 22551-24-2 |
---|---|
Name: | A-(METHYLTHIO)ACETAMIDE |
Article Data: | 8 |
Molecular Structure: | |
Formula: | C3H7NOS |
Molecular Weight: | 105.161 |
Synonyms: | (Methylthio)acetamide; |
Density: | 1.132 g/cm3 |
Melting Point: | 99-102 °C |
Boiling Point: | 258.8 °C at 760 mmHg |
Flash Point: | 110.3 °C |
Appearance: | white solid |
PSA: | 68.39000 |
LogP: | 0.53500 |
(methylthio)acetyl chloride
2-(methylthio)acetamide
Conditions | Yield |
---|---|
With ammonia In diethyl ether at 0℃; | 97% |
With ammonia In benzene for 0.0833333h; |
methyl 2-(methylthio)acetate
2-(methylthio)acetamide
Conditions | Yield |
---|---|
With ammonium hydroxide at 20 - 25℃; for 2.25h; | 76.2% |
methylthioacetic acid ethyl ester
2-(methylthio)acetamide
Conditions | Yield |
---|---|
With ammonia |
Conditions | Yield |
---|---|
With ethanol |
methylthioacetonitrile
A
2-(methylthio)acetamide
B
methylsulfanyl-acetic acid
Conditions | Yield |
---|---|
With potassium phosphate buffer; lyophilized Zea mays nitrilase ZmNIT2 EC 3.5.5.1 In water at 30℃; for 14h; pH=7.15; Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
Stage #1: methyl chloroacetate; sodium thiomethoxide With tetramethylammonium bromide at 20 - 50℃; for 1h; Stage #2: With ammonium hydroxide at 0 - 5℃; | 55.85 g |
(E)-1-Bromo-2-butene
2-(methylthio)acetamide
3-Methyl-2-methylsulfanyl-pent-4-enoic acid amide
Conditions | Yield |
---|---|
With potassium carbonate for 48h; | 95% |
2-(methylthio)acetamide
1-bromomethylcyclohexene
2-(2-Methylene-cyclohexyl)-2-methylsulfanyl-acetamide
Conditions | Yield |
---|---|
With potassium carbonate for 48h; | 92% |
2-(methylthio)acetamide
α-(Methylsulfinyl)-acetamide
Conditions | Yield |
---|---|
With NaJO4 In methanol; water Ambient temperature; overnight; | 90% |
With dihydrogen peroxide; acetone |
2-(methylthio)acetamide
(2-aminophenyl)(phenyl)methanone
2-amino-3-benzoyl-α-(methylthio)benzeneacetamide
Conditions | Yield |
---|---|
Stage #1: 2-(methylthio)acetamide; (2-aminophenyl)(phenyl)methanone With N-chloro-succinimide In dichloromethane at -45 - 8℃; Stage #2: With triethylamine In dichloromethane Product distribution / selectivity; | 86.4% |
Stage #1: (2-aminophenyl)(phenyl)methanone With N-chloro-succinimide In dichloromethane at -35 - -25℃; for 0.5h; Stage #2: 2-(methylthio)acetamide In dichloromethane at 0 - 10℃; for 2h; Solvent; | 80.27% |
Stage #1: 2-(methylthio)acetamide; (2-aminophenyl)(phenyl)methanone With N-chlorophthalimide In dichloromethane at -20 - -5℃; for 3.5h; Stage #2: With triethylamine In dichloromethane Stage #3: With potassium hydroxide In dichloromethane; water Temperature; Concentration; | 63.1% |
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The 2-(Methylthio)acetamide ,its cas register number is 22551-24-2.It also can be called as Acetamide,2-(methylthio)- and the Systematic name about this chemicals is 2-(Methylsulfanyl)acetamide .It is a white solid and can be used as Pharmaceutical Intermediates.If you want to sotre this chemicals, please keep containers tightly sealed, and store in cool, dry place in tighely closed containers.
Following are the chemical properties about 2-(Methylthio)acetamide : (1)#H bond acceptors: 2 ; (2)#H bond donors: 2 ; (3)#Freely Rotating Bonds: 2 ; (4)Polar Surface Area: 45.61 Å ; (5)Index of Refraction: 1.504 ; (6)Molar Refractivity: 27.5 cm3 ; (7)Molar Volume: 92.8 cm3 ; (8)Surface Tension: 41.9 dyne/cm; (9)Enthalpy of Vaporization: 49.64 kJ/mol ; (10)Vapour Pressure: 0.0135 mmHg at 25°C .
This chemicals can be described computed from structure:
(1)SMILES: O=C(N)CSC
(2)InChI: InChI=1/C3H7NOS/c1-6-2-3(4)5/h2H2,1H3,(H2,4,5)
(3)InChIKey: OBENGAMZEGRSIC-UHFFFAOYAN