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CAS No.: | 3008-40-0 |
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Name: | cyclooctane-1,2-dione |
Article Data: | 38 |
Molecular Structure: | |
Formula: | C5H6 O2 |
Molecular Weight: | 98.1014 |
Synonyms: | cyclooctane-1,2-dione |
Density: | 1.038g/cm3 |
Melting Point: | 56 °C |
Boiling Point: | 234.5°C at 760 mmHg |
Flash Point: | 86.9°C |
PSA: | 34.14000 |
LogP: | 1.47880 |
Conditions | Yield |
---|---|
With aluminum (III) chloride; Oxone In water at 20℃; for 1.5h; | 97% |
2-chlorocyclopentane-1-ol
cyclopentane-1,2-dione
Conditions | Yield |
---|---|
With iron(III) chloride hexahydrate In water at 100℃; for 0.166667h; | 80% |
2-keto cyclopentanone acetal
cyclopentane-1,2-dione
Conditions | Yield |
---|---|
With sulfuric acid; silica gel In dichloromethane for 24h; Ambient temperature; | 73% |
With sulfuric acid; silica gel In dichloromethane | 60% |
1-nitrocyclopentene oxide
cyclopentane-1,2-dione
Conditions | Yield |
---|---|
With chloro-trimethyl-silane; triethylamine Mechanism; 1.) DMSO, dichloromethane, 0 deg C, 5 h; 2.) dichloromethane, 0 -> 30 deg C, 1 h; further α-nitroepoxides; | 72% |
With triethylamine; tetrakis(triphenylphosphine) palladium(0) In benzene for 7h; Heating; | 50% |
With chloro-trimethyl-silane; triethylamine 1.) DMSO, dichloromethane, 0 deg C, 5 h; 2.) dichloromethane, 0 -> 30 deg C, 1 h; Yield given. Multistep reaction; | |
With chloro-trimethyl-silane; triethylamine 1.) CH2Cl2, 0 deg C, 5 h, 2.) CH2Cl2, 0 deg C to r.t., 1 h; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With iron(III) chloride In water at 100℃; for 0.333333h; | 66.47% |
4,5-dioxo-cyclopentane-1,3-dicarboxylic acid diethyl ester
cyclopentane-1,2-dione
Conditions | Yield |
---|---|
With hydrogenchloride Heating; | 61.7% |
With sulfuric acid man giesst auf Eis; | |
With sulfuric acid | |
With sulfuric acid |
2-(methylthio)cyclopentanone
cyclopentane-1,2-dione
Conditions | Yield |
---|---|
With CuCl2-CuO In water; acetone at 35℃; for 0.5h; | 60% |
With copper(II) oxide; copper dichloride In water; acetone at 35℃; for 0.5h; | 60% |
Conditions | Yield |
---|---|
With oxygen; copper(II) bis(trifluoromethanesulfonate); dimethyl sulfoxide; bismuth at 100℃; for 2h; | 52% |
1,2-bis((trimethylsilyl)oxy)cyclopent-1-ene
A
cyclopentane-1,2-dione
B
3-bromo-2-hydroxycyclopent-2-en-1-one
Conditions | Yield |
---|---|
With bromine In tetrachloromethane | A 15% B 40% |
cyclopentane-1,2-dione
Conditions | Yield |
---|---|
With hydrogenchloride |