3008-40-0Relevant articles and documents
Regioselective reductions of 23-epoxy acetals with lithium aluminum hydride: A reinvestigation
Ferraz, Helena M. C.,Sasahara, Regina M.,Losco, Pellegrino
, p. 8131 - 8132 (1992)
Treatment of 2,3-epoxy acetals with lithium aluminum hydride gave the corresponding 2-hydroxy acetals, instead of the previously reported 3-hydroxy acetals.
Koetz,Neukom
, p. 365 (1975)
Oxone-mediated oxidative cleavage of β-keto esters and 1,3-diketones to α-keto esters and 1,2-diketones in aqueous medium
Stergiou, Anastasios,Bariotaki, Anna,Kalaitzakis, Dimitris,Smonou, Ioulia
, p. 7268 - 7273 (2013/08/15)
A versatile and highly efficient method for the direct synthesis of α-keto esters and 1,2-diketones has been developed. This approach utilizes the oxidative cleavage of a variety of β-keto esters and 1,3-diketones mediated by an Oxone/aluminum trichloride system. The simple one-step oxidation reaction proceeded selectively in aqueous media to afford products in high yields, short reaction times, and environmentally benign conditions.
Method for preparing chiral diphosphines
-
, (2008/06/13)
The invention concerns a method for preparing a compound of formula (1) wherein: A represents naphthyl or phenyl optionally substituted; and Ar1, Ar2independently represent a saturated or aromatic carbocyclic group, optionally substituted.