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| CAS No.: | 110-94-1 |
|---|---|
| Name: | Glutaric acid |
| Article Data: | 476 |
| Molecular Structure: | |
|
|
|
| Formula: | C5H8O4 |
| Molecular Weight: | 132.116 |
| Synonyms: | Glutaricacid (8CI);1,3-Propanedicarboxylic acid;1,5-Pentanedioic acid;NSC 9238; |
| EINECS: | 203-817-2 |
| Density: | 1.316 g/cm3 |
| Melting Point: | 95-98 °C(lit.) |
| Boiling Point: | 302.894 °C at 760 mmHg |
| Flash Point: | 151.2 °C |
| Solubility: | 430 g/L (20 °C) in water |
| Appearance: | white or off-white crystals |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 26-37/39-36 |
| PSA: | 74.60000 |
| LogP: | 0.32590 |
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| Conditions | Yield |
|---|---|
| With dmap; triethylamine In dichloromethane | 100% |
| Conditions | Yield |
|---|---|
| With C24H33IrN4O3; water; sodium hydroxide for 18h; Catalytic behavior; Reagent/catalyst; Reflux; | 98% |
| In water for 48h; Ambient temperature; Gluconobacter roseus IAM 1841; | 97% |
| With sodium hydroxide In water at 20℃; Temperature; Concentration; Electrochemical reaction; | 91% |
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide; Na12[WZn3(H2O)2(ZnW9O34)2] at 75℃; for 7h; | 98% |
| Conditions | Yield |
|---|---|
| With ozone In tetrachloromethane; water at 20℃; for 1h; UV-irradiation; | 97% |
| With water; ozone at 25℃; under 760.051 Torr; for 1h; Irradiation; | 95% |
| With oxygen; sodium hydroxide In water at 90℃; under 3000.3 Torr; for 3h; pH=7; | 21% |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; sodium tungstate; phosphoric acid; dihydrogen peroxide at 90℃; for 5h; | 96% |
| Conditions | Yield |
|---|---|
| Stage #1: Cyclopentanol With Oxone; ruthenium(III) chloride monohydrate In water at 70℃; for 8h; Stage #2: In ethanol Cooling; | 95% |
| With nitric acid at 70 - 100℃; | |
| With nitric acid; vanadia at 70 - 100℃; |
| Conditions | Yield |
|---|---|
| With oxygen; trifluoroacetic acid; sodium nitrite at 0 - 20℃; for 5.25h; Product distribution / selectivity; | 95% |
| Stage #1: cyclopentanone With Oxone; ruthenium(III) chloride monohydrate In water at 20℃; for 5h; Stage #2: In ethanol Cooling; | 90% |
| With oxygen; copper dichloride In acetic acid at 80℃; for 6h; Oxidation; | 84% |
| Conditions | Yield |
|---|---|
| With potassium metaperiodate; potassium aquapentachlororuthenate(III) In dichloromethane; water; acetonitrile at 20℃; for 2h; Catalytic behavior; Sonication; | 94% |
| With potassium permanganate; H-montmorillonite In water; benzene at 25 - 30℃; for 1h; | 90% |
| With periodic acid; cis-[RuCl2(bipy)2]*2H2O In tetrachloromethane; water; acetonitrile at 20℃; for 2h; | 85% |
| Conditions | Yield |
|---|---|
| With triethylmethylammonium iodide; water; dihydrogen peroxide In acetonitrile at 55℃; for 23h; | 94% |
| With potassium carbonate In water at 25℃; Electrochemical reaction; | 81% |
| With iodine; oxygen In ethyl acetate for 10h; Mercury lamp irradiation; | 40% |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; sodium sulfate; OsO4 In ethyl acetate; N,N-dimethyl-formamide; tert-butyl alcohol | 92% |
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Chemistry
The Molecular Structure of Glutaric acid (CAS NO.110-94-1):
Empirical Formula: C5H8O4
Molecular Weight: 132.1146
IUPAC Name: pentanedioic acid
Appearance: white or off-white crystals
Nominal Mass: 132 Da
Average Mass: 132.1146 Da
Monoisotopic Mass: 132.042259 Da
Index of Refraction: 1.476
Molar Refractivity: 28.34 cm3
Molar Volume: 100.3 cm3
Surface Tension: 56.1 dyne/cm
Density: 1.316 g/cm3
Flash Point: 151.2 °C
Enthalpy of Vaporization: 59.74 kJ/mol
Boiling Point: 302.9 °C at 760 mmHg
Vapour Pressure: 0.000223 mmHg at 25°C
Product Categories: Pharmaceutical Intermediates;alpha,omega-Alkanedicarboxylic Acids;alpha,omega-Bifunctional Alkanes;Monofunctional & alpha,omega-Bifunctional Alkanes;C1 to C5;Carbonyl Compounds;Carboxylic Acids
Water Solubility: 430 g/L (20 ºC)
Stability: Stable. Incompatible with bases, oxidizing agents, reducing agents
Synonyms: 1,3-Propanedicarboxylic acid ; 1,5-Pentanedioic acid ; 4-02-00-01934 (Beilstein Handbook Reference) ; AI3-24247 ; BRN 1209725 ; EINECS 203-817-2 ; GLUTARIC ACID ; Pentandioic acid ; Pentanedioic acid ; n-Pyrotartaric acid ; Pentanedioic acid
Uses
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | oral | 6gm/kg (6000mg/kg) | Biochemical Journal. Vol. 34, Pg. 1196, 1940. |
LD50/LC50: RTECS:
CAS# 110-94-1: Oral, mouse: LD50 = 6 gm/kg;
Carcinogenicity: Glutaric acid - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: See actual entry in RTECS for complete information. The toxicological properties have not been fully investigated.
Safety Profile
Hazard Codes: 
Xi
Risk Statements: 36-36/37/38
R36: Irritating to eyes
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 26-37/39-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S37/39: Wear suitable gloves and eye/face protection
S36: Wear suitable protective clothing
WGK Germany: 1
RTECS: MA3740000
HS Code: 29171990
Specification
Personal Protection：
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Fire Fighting：Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Product Categories: Pharmaceutical Intermediates;alpha,omega-Alkanedicarboxylic Acids;alpha,omega-Bifunctional Alkanes;Monofunctional & alpha,omega-Bifunctional Alkanes;C1 to C5;Carbonyl Compounds;Carboxylic Acids