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110-94-1

Basic Information
CAS No.: 110-94-1
Name: Glutaric acid
Article Data: 476
Cas Database
Molecular Structure:
Molecular Structure of 110-94-1 (Glutaric acid)
Formula: C5H8O4
Molecular Weight: 132.116
Synonyms: Glutaricacid (8CI);1,3-Propanedicarboxylic acid;1,5-Pentanedioic acid;NSC 9238;
EINECS: 203-817-2
Density: 1.316 g/cm3
Melting Point: 95-98 °C(lit.)
Boiling Point: 302.894 °C at 760 mmHg
Flash Point: 151.2 °C
Solubility: 430 g/L (20 °C) in water
Appearance: white or off-white crystals
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-37/39-36
Transport Information: N/A
PSA: 74.60000
LogP: 0.32590
Synthetic route
13246-39-4

(+-)-1-(trimethylsilyl)ethanol

53715-97-2

5,5'-oxybis(5-oxopentanoic acid)

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane100%
111-29-5

1 ,5-pentanediol

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With C24H33IrN4O3; water; sodium hydroxide for 18h; Catalytic behavior; Reagent/catalyst; Reflux;98%
In water for 48h; Ambient temperature; Gluconobacter roseus IAM 1841;97%
With sodium hydroxide In water at 20℃; Temperature; Concentration; Electrochemical reaction;91%
5057-98-7

cis-1,2-cyclopentanediol

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With dihydrogen peroxide; Na12[WZn3(H2O)2(ZnW9O34)2] at 75℃; for 7h;98%
765-87-7

cyclohexane-1,2-dione

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With ozone In tetrachloromethane; water at 20℃; for 1h; UV-irradiation;97%
With water; ozone at 25℃; under 760.051 Torr; for 1h; Irradiation;95%
With oxygen; sodium hydroxide In water at 90℃; under 3000.3 Torr; for 3h; pH=7;21%
5057-99-8

trans-cyclopentane-1,2-diol

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium tungstate; phosphoric acid; dihydrogen peroxide at 90℃; for 5h;96%
96-41-3

Cyclopentanol

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
Stage #1: Cyclopentanol With Oxone; ruthenium(III) chloride monohydrate In water at 70℃; for 8h;
Stage #2: In ethanol Cooling;
95%
With nitric acid at 70 - 100℃;
With nitric acid; vanadia at 70 - 100℃;
120-92-3

cyclopentanone

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With oxygen; trifluoroacetic acid; sodium nitrite at 0 - 20℃; for 5.25h; Product distribution / selectivity;95%
Stage #1: cyclopentanone With Oxone; ruthenium(III) chloride monohydrate In water at 20℃; for 5h;
Stage #2: In ethanol Cooling;
90%
With oxygen; copper dichloride In acetic acid at 80℃; for 6h; Oxidation;84%
142-29-0

cyclopentene

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With potassium metaperiodate; potassium aquapentachlororuthenate(III) In dichloromethane; water; acetonitrile at 20℃; for 2h; Catalytic behavior; Sonication;94%
With potassium permanganate; H-montmorillonite In water; benzene at 25 - 30℃; for 1h;90%
With periodic acid; cis-[RuCl2(bipy)2]*2H2O In tetrachloromethane; water; acetonitrile at 20℃; for 2h;85%
504-02-9

1,3-cylohexanedione

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With triethylmethylammonium iodide; water; dihydrogen peroxide In acetonitrile at 55℃; for 23h;94%
With potassium carbonate In water at 25℃; Electrochemical reaction;81%
With iodine; oxygen In ethyl acetate for 10h; Mercury lamp irradiation;40%
930-68-7

cyclohexenone

oxone

oxone

Os(VIII)

Os(VIII)

110-94-1

1,5-pentanedioic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium sulfate; OsO4 In ethyl acetate; N,N-dimethyl-formamide; tert-butyl alcohol92%
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    Product Name: Glutaric acid Synonyms: a,-Propanedicarboxylicacid;glutaric;Glutarsaure;1,3-PROPANEDICARBOXYLIC ACID;1,5-PENTADIOIC ACID;1,5-PENTANEDIOIC ACID;GLUTARIC ACID AND ANHYDRIDE;GLUTARIC ACID CAS: 110-94-1 MF: C5H8O4 MW: 132.11 EINECS:

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    Product Name: Glutaric acid MF: C5H8O4 MW: 132.11 EINECS: 203-817-2 Mol File: 110-94-1.mol Glutaric acid Structure Glutaric acid Chemical Properties Melting point 95-98 °C (lit.) Boiling point 200 °C/20 mmHg (lit.) de

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    Glutaric acid CAS NO.110-94-1

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Chemistry

The Molecular Structure of Glutaric acid (CAS NO.110-94-1):

Empirical Formula: C5H8O4
Molecular Weight: 132.1146 
IUPAC Name: pentanedioic acid  
Appearance: white or off-white crystals
Nominal Mass: 132 Da
Average Mass: 132.1146 Da
Monoisotopic Mass: 132.042259 Da 
Index of Refraction: 1.476
Molar Refractivity: 28.34 cm3
Molar Volume: 100.3 cm3
Surface Tension: 56.1 dyne/cm
Density: 1.316 g/cm3
Flash Point: 151.2 °C
Enthalpy of Vaporization: 59.74 kJ/mol
Boiling Point: 302.9 °C at 760 mmHg
Vapour Pressure: 0.000223 mmHg at 25°C 
Product Categories: Pharmaceutical Intermediates;alpha,omega-Alkanedicarboxylic Acids;alpha,omega-Bifunctional Alkanes;Monofunctional & alpha,omega-Bifunctional Alkanes;C1 to C5;Carbonyl Compounds;Carboxylic Acids 
Water Solubility: 430 g/L (20 ºC) 
Stability: Stable. Incompatible with bases, oxidizing agents, reducing agents 
Synonyms: 1,3-Propanedicarboxylic acid ; 1,5-Pentanedioic acid ; 4-02-00-01934 (Beilstein Handbook Reference) ; AI3-24247 ; BRN 1209725 ; EINECS 203-817-2 ; GLUTARIC ACID ; Pentandioic acid ; Pentanedioic acid ; n-Pyrotartaric acid ; Pentanedioic acid  

Uses

 Glutaric acid (CAS NO.110-94-1), a common plasticizer and precursor to polyesters is manufactored by hydrogenation of Glutaric acid (CAS NO.110-94-1) and its derivatives. Glutaric acid (NO.110-94-1) itself has been used in the production of polymers such as polyester polyols, polyamides. The odd number of carbon atoms (i.e. 5) is useful in decreasing polymer elasticity.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 6gm/kg (6000mg/kg)   Biochemical Journal. Vol. 34, Pg. 1196, 1940.
RTECS#: CAS# 110-94-1: MA3740000
LD50/LC50: RTECS:
CAS# 110-94-1: Oral, mouse: LD50 = 6 gm/kg;
Carcinogenicity: Glutaric acid - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: See actual entry in RTECS for complete information. The toxicological properties have not been fully investigated. 

Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36-36/37/38 
R36: Irritating to eyes
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 26-37/39-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S37/39: Wear suitable gloves and eye/face protection
S36: Wear suitable protective clothing
WGK Germany: 1
RTECS: MA3740000
HS Code: 29171990

Specification

Personal Protection:
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Fire Fighting:Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Product Categories: Pharmaceutical Intermediates;alpha,omega-Alkanedicarboxylic Acids;alpha,omega-Bifunctional Alkanes;Monofunctional & alpha,omega-Bifunctional Alkanes;C1 to C5;Carbonyl Compounds;Carboxylic Acids