Products Categories
CAS No.: | 3524-68-3 |
---|---|
Name: | Pentaerythritol triacrylate |
Article Data: | 8 |
Molecular Structure: | |
Formula: | C14H18O7 |
Molecular Weight: | 298.293 |
Synonyms: | 2-Propenoicacid, 2-(hydroxymethyl)-2-[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester(9CI);Acrylic acid, triester with pentaerythritol (7CI,8CI);Pentaerythritol,triacrylate (8CI);A-TMM 3OHV122;A-TMMA;Agi Syn 2884;Aronix M 30;Aronix M305;Aronix M 306;Gafgard 233;Hipenny;Kayarad PET 30;Light Acrylate PE 3A;Light Ester PE 3A;M 305;NK Ester A-TMN 3LM-N;NK Ester TMM 50T;NewfrontierPET 3;P 300;P 300 (acrylate);PE 3A;PET 30;PETA;PETIA;Pentaerythrityltriacrylate;SR 444;SR 444C;SR 444D;Sartomer 444;Sartomer SR 444;SetaluxUV 2242;Tetramethylolmethane triacrylate;Viscoat 300PETA;2-Propenoic acid,1,1'-[2-(hydroxymethyl)-2-[[(1-oxo-2-propen-1-yl)oxy]methyl]-1,3-propanediyl]ester; |
EINECS: | 222-540-8 |
Density: | 1.179 g/cm3 |
Melting Point: | 15℃ |
Boiling Point: | 427.9 ºC at 760 mmHg |
Flash Point: | 153.5 °C |
Solubility: | insoluble in water |
Appearance: | viscous yellow liquid |
Hazard Symbols: | Xi |
Risk Codes: | 36/38-43 |
Safety: | 39 |
Transport Information: | UN 3265 |
PSA: | 99.13000 |
LogP: | 0.15270 |
Conditions | Yield |
---|---|
Stage #1: Pentaerythritol; acrylic acid With IR-120 strong acid type ion exchange resin at 100℃; for 0.5h; Stage #2: In benzene at 100℃; for 3h; Temperature; | 88% |
Conditions | Yield |
---|---|
With triethylamine; trichlorophosphate In (2S)-N-methyl-1-phenylpropan-2-amine hydrate |
Pentaerythritol
2-methoxyethyl acrylate
B
pentaerythritol tetraacrylate
C
pentaerythritol triacrylate
Conditions | Yield |
---|---|
With zinc diacetate; oxygen; 4-methoxy-phenol; 1,8-diazabicyclo[5.4.0]undec-7-ene at 105 - 120℃; for 5h; Reagent/catalyst; Inert atmosphere; Overall yield = 48 %; |
Pentaerythritol
2-methoxyethyl acrylate
A
pentaerythritol tetraacrylate
B
pentaerythritol triacrylate
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Inert atmosphere; Overall yield = 96 %; | |
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %; | |
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %; |
Conditions | Yield |
---|---|
With triphenylphosphine at 90℃; for 8h; | 99.9% |
Conditions | Yield |
---|---|
In toluene for 3h; Diels-Alder Cycloaddition; Inert atmosphere; Schlenk technique; | 97% |
pentaerythritol triacrylate
Conditions | Yield |
---|---|
With acetic acid butyl ester; hydroxyethyl cellulose; dibenzoyl peroxide In water at 80℃; for 8h; Product distribution; Further Variations:; Reagents; | 96.6% |
Conditions | Yield |
---|---|
With 4-methoxy-phenol; triphenylphosphine at 95℃; for 14h; | 94.58% |
Conditions | Yield |
---|---|
With 4-methoxy-phenol; triphenylphosphine at 90℃; for 8h; | 91.2% |
Conditions | Yield |
---|---|
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 20h; | 85% |
What can I do for you?
Get Best Price
IUPAC Name: [2-(Hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate
Empirical Formula: C14H18O7
Molecular Weight: 298.2885
EINECS: 222-540-8
Product Categories: Functional Monomer; RAW material for negative PR
storage temp.: 2-8 °C
Sensitive: Hygroscopic
Stability: Stable at room temperature, but potentially explosive at elevated temperatures. Combustible, but may explode if involved in a fire.
Index of Refraction: 1.488
Molar Refractivity: 72.91 cm3
Molar Volume: 252.9 cm3
Surface Tension: 41.5 dyne/cm
Density: 1.179 g/cm3
Flash Point: 153.5 °C
Enthalpy of Vaporization: 78.86 kJ/mol
Boiling Point: 427.9 °C at 760 mmHg
Vapour Pressure: 4.08E-09 mmHg at 25 °C
Appearance: Thick clear yellow liquid.
Classification Code of Pentaerythritol triacrylate (CAS NO.3524-68-3): Mutation data; Reproductive Effect; Skin / Eye Irritant; Tumor data
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rabbit | LD50 | skin | 4mL/kg (4mL/kg) | Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974. | |
rat | LD50 | intraperitoneal | 25mg/kg (25mg/kg) | BEHAVIORAL: ATAXIA GASTROINTESTINAL: OTHER CHANGES SKIN AND APPENDAGES (SKIN): HAIR: OTHER | National Technical Information Service. Vol. OTS0555706, |
rat | LD50 | oral | 1830mg/kg (1830mg/kg) | GASTROINTESTINAL: ULCERATION OR BLEEDING FROM SMALL INTESTINE GASTROINTESTINAL: ULCERATION OR BLEEDING FROM LARGE INTESTINE GASTROINTESTINAL: OTHER CHANGES | National Technical Information Service. Vol. OTS0555713, |
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion and skin contact. Skin and severe eye irritant. Questionable carcinogen with experimental tumorigenic data. Used for radiation-cured adhesives, coatings, inks, textiles, photo resists, and coatings. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes: Xi
Risk Statements: 36/38-43
R36/38:Irritating to eyes and skin.
R43:May cause sensitization by skin contact.
Safety Statements: 39
S39:Wear eye / face protection.
RIDADR: UN3265
WGK Germany: 1
RTECS: UD3370000
HazardClass: 8
PackingGroup: III
Pentaerythritol triacrylate (CAS NO.3524-68-3), its Synonyms are Pentaerythrityl triacrylate ; Acrylic acid, triester with pentaerythritol ; Aronix M 305 ; Gafgard 233 ; Kayarad PET 30 ; Light Acrylate PE 3A ; NK Ester A-TMM 3 ; NK Ester A-TMM 3L ; NK Ester TMM 50T ; 2-(Hydroxymethyl)-2-(((1-oxoallyl)oxy)methyl)-1,3-propanediyl diacrylate ; 2-Propenoic acid, 1,1'-(2-(hydroxymethyl)-2-(((1-oxo-2-propen-1-yl)oxy)methyl)-1,3-propanediyl) ester ; 2-Propenoic acid, 2-(hydroxymethyl)-2-(((1-oxo-2-propenyl)oxy)methyl)-1,3-propanediyl ester .