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366-18-7

Basic Information
CAS No.: 366-18-7
Name: 2,2'-Dipyridyl
Molecular Structure:
Molecular Structure of 366-18-7 (2,2'-Dipyridyl)
Formula: C10H8N2
Molecular Weight: 156.19
Synonyms: 2,2'-Bipyridine;alpha,alpha'-Dipyridyl;2-(2-Pyridyl)pyridine;
EINECS: 206-674-4
Density: 1.106 g/cm3
Melting Point: 70-73 °C(lit.)
Boiling Point: 272.499 °C at 760 mmHg
Flash Point: 107.243 °C
Solubility: 5.5 g/L 22 ºC
Appearance: White crystalline powder
Hazard Symbols: ToxicT, IrritantXi
Risk Codes: 25-36/37/38-20/21-23/24/25
Safety: 36/37-45-36/37/39-26
Transport Information: UN 2811 6.1/PG 3
PSA: 25.78000
LogP: 2.14360
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    Synonyms: ,’-Dipyridyl;2-(2-Pyridyl)pyridine;2,2’-bipyridin;2,2’-dipyridine;2,2'-Bipyridin;2,2'-Dipyridine;AA-DP;alpha,alpha’-dipyridine CAS: 366-18-7 MF: C10H8N2 MW: 156.18 EINECS: 206-674-4 Product Categories:

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Specification

The 2,2'-Bipyridine, with the CAS registry number 366-18-7 and EINECS registry number 206-674-4, is also called 2-(2-pyridyl)pyridine. And the molecular formula of this chemical is C10H8N2. It is a kind of colorless solid, commonly abbreviated bipy or bpy, and is an important isomer of the bipyridine family. It is a bidentate chelating ligand, forming complexes with many transition metals. Ruthenium complex and platinum complexes of bipy exhibit intense luminescence, which may have practical applications.

The physical properties of 2,2'-Bipyridine are as following: (1)ACD/LogP: 1.69; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.661; (4)ACD/LogD (pH 7.4): 1.694; (5)ACD/BCF (pH 5.5): 10.576; (6)ACD/BCF (pH 7.4): 11.404; (7)ACD/KOC (pH 5.5): 184.252; (8)ACD/KOC (pH 7.4): 198.676; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 25.78 Å2; (13)Index of Refraction: 1.581; (14)Molar Refractivity: 47.027 cm3; (15)Molar Volume: 141.166 cm3; (16)Polarizability: 18.643×10-24cm3; (17)Surface Tension: 46.65 dyne/cm; (18)Density: 1.106 g/cm3; (19)Flash Point: 107.243 °C; (20)Enthalpy of Vaporization: 49.023 kJ/mol; (21)Boiling Point: 272.499 °C at 760 mmHg; (22)Vapour Pressure: 0.01 mmHg at 25°C.

Uses and preparation of 2,2'-Bipyridine: It is used as analytical reagent for the determination of iron, silver, cadmium, molybdenum. It is also used as redox indicator. What's more, it can be prepared by the dehydrogenation of pyridine using Raney nickel:

2,2'-Bipyridine can be prepared by the dehydrogenation of pyridine using Raney nickel

You should be cautious while dealing with this chemical. It is toxic if swallowed. Therefore, you had better take the following instructions: Wear suitable protective clothing and gloves, and in case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: c1ccnc(c1)c2ccccn2
(2)InChI: InChI=1/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H
(3)InChIKey: ROFVEXUMMXZLPA-UHFFFAOYAP

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 200mg/kg (200mg/kg) KIDNEY, URETER, AND BLADDER: OTHER CHANGES IN URINE COMPOSITION

KIDNEY, URETER, AND BLADDER: OTHER CHANGES
Journal of Pharmacology and Experimental Therapeutics. Vol. 196, Pg. 478, 1976.
mouse LD50 oral 330mg/kg (330mg/kg)   United States Patent Document. Vol. #3875163,
rat LD50 intraperitoneal 150mg/kg (150mg/kg)   Polish Journal of Pharmacology and Pharmacy. Vol. 27, Pg. 619, 1975.
rat LD50 oral 100mg/kg (100mg/kg) BEHAVIORAL: MUSCLE WEAKNESS

KIDNEY, URETER, AND BLADDER: OTHER CHANGES IN URINE COMPOSITION

BLOOD: HEMORRHAGE
Journal of Toxicology and Environmental Health. Vol. 10, Pg. 363, 1982.
rat LD50 subcutaneous 131mg/kg (131mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 135, Pg. 317, 1962.

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