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CAS No.: | 3829-86-5 |
---|---|
Name: | o-Phenanthroline monohydrochloride monohydrate |
Molecular Structure: | |
Formula: | C12H8N2.HCl |
Molecular Weight: | 216.67 |
Synonyms: | 1,10-Phenanthroline,monohydrochloride (8CI,9CI);1,10-Diazaphenanthrene hydrochloride;1,10-Phenanthroline hydrochloride;NSC 4265; |
EINECS: | 223-325-1 |
Density: | 1.385 g/cm3 (-100.15 C) |
Melting Point: | 224-225 °C(lit.) |
Boiling Point: | 365.1 °C at 760 mmHg |
Flash Point: | 164.8 °C |
Solubility: | soluble in water |
Appearance: | white to light yellow or slightly purple powder |
Hazard Symbols: | T, N |
Risk Codes: | 25-50/53 |
Safety: | 45-60-61 |
Transport Information: | UN 2811 6.1/PG 3 |
PSA: | 25.78000 |
LogP: | 3.58500 |
1,10-phenanthroline hydrochloride
Conditions | Yield |
---|---|
In water from aq. soln. of CuCl2 and soln. of phenanthroline hydrochloride in 2:1, 1:1 molar ratio at pH 6.5 maintained by an alkali soln.; solvent evapd. in a water bath; ppt. washed (H2O); dried (air); elem. anal.; | 96% |
1,10-phenanthroline hydrochloride
Conditions | Yield |
---|---|
In water from aq. soln. of CuCl2 and soln. of phenanthroline hydrochloride in 1:2, 1:3 molar ratio at pH 6.5 maintained by an alkali soln.; solvent evapd. in a water bath; ppt. washed (H2O); dried (air); elem. anal.; | 90% |
1,10-phenanthroline hydrochloride
bis(trifluoromethane)sulfonimide lithium
C2HF6NO4S2*C12H8N2
Conditions | Yield |
---|---|
With water at 20℃; for 2h; | 90% |
Conditions | Yield |
---|---|
In methanol for 1h; | 88% |
potassium permanganate
water
1,10-phenanthroline hydrochloride
copper
Conditions | Yield |
---|---|
In methanol byproducts: Mn(2+); stirring 1:1:2:2 mixt. of copper, permanganate salt, phenanthroline deriv., NH4Cl in methanol at 50-60°C in air for 2 h; addn. of isopropanol, isolation of crystals, elem. anal.; | 87% |
potassium permanganate
1,10-phenanthroline hydrochloride
copper
N,N-dimethyl-formamide
Conditions | Yield |
---|---|
In methanol; N,N-dimethyl-formamide byproducts: Mn(2+); stirring 1:1:2:2 mixt. of copper, permanganate salt, phenanthroline deriv., NH4Cl in methanol and DMF at 50-60°C in air for 2 h; addn. of isopropanol, isolation of crystals, elem. anal.; | 82% |
1,10-phenanthroline hydrochloride
Conditions | Yield |
---|---|
In methanol; water; butan-1-ol dissolving of amine hydrochloride in water, addn. of the phosphine-complex in methanol-butanol; filtn. after 10-15 min, washing (methanol), drying at room temp. in air, elem. anal.; | 72% |
1,10-phenanthroline hydrochloride
nitridoperoxo 1,10-phenanthroline technetium(VII)
Conditions | Yield |
---|---|
elem. anal.; | 70% |
1,10-phenanthroline hydrochloride
Conditions | Yield |
---|---|
In water dissolving of amine hydrochloride in water, addn. of Cr complex; addn. of methanol-butanol, filtn. after 10-15 min, washing (methanol), drying at room temp. in air, elem. anal.; | 65% |
1,10-phenanthroline hydrochloride
Conditions | Yield |
---|---|
In water under anaerobic conditions; water soln. of ligand (1 equiv.) added slowly to aq. soln. of V complex; left to stand for 4 d; crystals collected; elem. anal.; | 53% |
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The Molecular Structure of 1,10-Phenanthroline, hydrochloride (1:1) (CAS NO.3829-86-5):
Empirical Formula: C12H9ClN2
Molecular Weight: 216.6663
IUPAC: 1,10-phenanthroline hydrochloride
Nominal Mass: 216 Da
Average Mass: 216.6663 Da
Monoisotopic Mass: 216.045426 Da
Flash Point: 164.8 °C
Enthalpy of Vaporization: 58.73 kJ/mol
Boiling Point: 365.1 °C at 760 mmHg
Melting Point: 224-225 °C(lit.)
Solubility H2O: 0.1 g/mL, clear
Water Solubility: soluble
BRN: 4007967
Appearance: white to light yellow or slightly purple powder
Vapour Pressure: 3.38E-05 mmHg at 25°C
InChI
InChI=1/C12H8N2.ClH/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h1-8H;1H
Smiles
c12c3ncccc3ccc2cccn1.Cl
Product Categories: Aromatic Hydrocarbons (substituted) & Derivatives;Heterocyclic Compounds;Analytical Chemistry;Chelating Reagents;Phenanthrolines
Hazard Codes: TN
Risk Statements: 25-50/53
R25 :Toxic if swallowed
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 45-60-61
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste
S61:Avoid release to the environment. Refer to special instructions / safety data sheets
RIDADR UN: 2811 6.1/PG 3
WGK Germany: 3
F 8:Photosensitive
HazardClass: 6.1
PackingGroup :III
1,10-Phenanthroline, hydrochloride (1:1) (CAS NO.3829-86-5) is also called as 1,10-Diazaphenanthrene hydrochloride ; 1,10-Phenanthroline hydrochloride ; EINECS 223-325-1 ; NSC 4265 ; Phenanthroline hydrochloride ; 1,10-Phenanthroline monohydrochloride monohydrate ; 1,10-Phenanthroline, monohydrochloride .