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4091-50-3

Basic Information
CAS No.: 4091-50-3
Name: [2-(4-METHOXY-PHENYL)-ETHYL]-METHYL-AMINE
Article Data: 22
Molecular Structure:
Molecular Structure of 4091-50-3 ([2-(4-METHOXY-PHENYL)-ETHYL]-METHYL-AMINE)
Formula: C10H15 N O
Molecular Weight: 165.235
Synonyms: Phenethylamine,p-methoxy-N-methyl- (6CI,8CI); (p-Methoxyphenethyl)methylamine;4-Methoxy-N-methylbenzeneethanamine; 4-Methoxy-N-methylphenethylamine;N-(p-Methoxyphenethyl)methylamine; N-Methyl-(p-methoxyphenethyl)amine;N-Methyl-2-(4-methoxyphenyl)ethylamine; N-Methyl-4-methoxy-b-phenethylamine;N-Methyl-4-methoxyphenethylamine; N-Methyl-N-(4-methoxyphenethyl)amine; N-Methyl-b-(4-methoxyphenyl)ethylamine;[2-(4-Methoxyphenyl)ethyl]methylamine; p-Methoxy-N-methylphenethylamine
Density: 0.963g/cm3
Boiling Point: 251.2°Cat760mmHg
Flash Point: 99.3°C
Safety: Poison by intravenous route. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
PSA: 21.26000
LogP: 1.84800
Synthetic route
136390-01-7

ethyl-N-<2-(4-methoxyphenyl)ethyl>-carbamate

4091-50-3

N-methylhomoanisylamine

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran Heating;99%
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 50℃; Inert atmosphere;27%
91247-71-1

2-4-methoxyphenylethylcarbamic acid methyl ester

4091-50-3

N-methylhomoanisylamine

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; Reflux;93%
With lithium aluminium tetrahydride
74-89-5

methylamine

18217-00-0

1-(2-Chloroethyl)-4-methoxybenzene

4091-50-3

N-methylhomoanisylamine

Conditions
ConditionsYield
In methanol for 168h; Ambient temperature;73%
Stage #1: methylamine; 1-(2-Chloroethyl)-4-methoxybenzene In ethanol at 20℃; for 1h;
Stage #2: With triisobutylaluminum In ethanol at 60℃; for 24h;
72%
74-89-5

methylamine

768-60-5

4-methoxyphenylacetylen

A

4091-50-3

N-methylhomoanisylamine

B

41684-13-3

4-methoxy-N-methyl-α-methylbenzylamine

Conditions
ConditionsYield
Stage #1: methylamine; 4-methoxyphenylacetylen; Ind2TiMe2 In toluene at 80℃; under 760 Torr; for 7h;
Stage #2: With sodium cyanoborohydride; zinc(II) chloride In methanol; toluene at 25℃; for 16h;
A 20%
B 19%
100-52-7

benzaldehyde

55-81-2

4-Methoxyphenethylamine

4091-50-3

N-methylhomoanisylamine

Conditions
ConditionsYield
anschliessend mit Dimethylsulfat und dann mit wss. Aethanol;
14425-64-0

4-methoxyphenethyl bromide

74-89-5

methylamine

4091-50-3

N-methylhomoanisylamine

Conditions
ConditionsYield
With methanol at 100℃;
59907-36-7

2-(4-methoxyphenyl)-N-methylacetamide

4091-50-3

N-methylhomoanisylamine

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran
With borane-THF In tetrahydrofuran for 4h; Inert atmosphere; Reflux;
56100-69-7

N-[2-(4-methoxyphenyl)ethyl]formamide

4091-50-3

N-methylhomoanisylamine

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran
55-81-2

4-Methoxyphenethylamine

7693-46-1

4-Nitrophenyl chloroformate

4091-50-3

N-methylhomoanisylamine

Conditions
ConditionsYield
With 4-methyl-morpholine; lithium aluminium tetrahydride; N-ethyl-N,N-diisopropylamine; Wang resin 1.) 0 deg C, 2 h; room temp., overnight, 2.) DMF, room temp., overnight, 3.) THF, 60 deg C, 14 h; Yield given. Multistep reaction;
13139-86-1

4-methoxyphenyl magnesium bromide

methyl-<2-chloro-ethyl>-amine hydrochloride

methyl-<2-chloro-ethyl>-amine hydrochloride

4091-50-3

N-methylhomoanisylamine

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  • N-Methyl4-Methoxyphenethylamine

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  • 4-methoxy-N-methylBenzeneethanamine

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    4-methoxy-N-methylBenzeneethanamine

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  • Benzeneethanamine,4-methoxy-N-methyl-

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    Benzeneethanamine,4-methoxy-N-methyl-

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  • [2-(4-Methoxyphenyl)ethyl]methylamine

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    4091-50-3

    [2-(4-Methoxyphenyl)ethyl]methylamine

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Chemistry

Product Name: Compound 48/80 (CAS NO.4091-50-3)


Molecular Formula: C10H15NO
Molecular Weight: 165.23g/mol
Mol File: 4091-50-3.mol
Boiling point: 251.2 °C at 760 mmHg
Storage Temperature:
Flash Point: 99.3 °C
Density: 0.963 g/cm3
Surface Tension: 32 dyne/cm
Enthalpy of Vaporization: 48.85 kJ/mol
Vapour Pressure: 0.0208 mmHg at 25°C
XLogP3-AA: 1.7
H-Bond Donor: 1
H-Bond Acceptor: 2
Product Categories: Amines and Anilines

Uses

 Compound 48/80 (CAS NO.4091-50-3) promotes histamine release. In biochemical research, compound 48/80 is used to promote mast cell degranulation.

Production

 Compound 48/80 (CAS NO.4091-50-3) is a polymer produced by the condensation of N-methyl-p-methoxyphenethylamine with formaldehyde.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 intravenous 1290ug/kg (1.29mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 120, Pg. 353, 1959.
mouse LD50 intravenous 1950ug/kg (1.95mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 120, Pg. 353, 1959.
rabbit LD50 intravenous 1500ug/kg (1.5mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 120, Pg. 353, 1959.
rat LD50 intravenous 2400ug/kg (2.4mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 120, Pg. 353, 1959.

Safety Profile

Poison by intravenous route. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.

Specification

 Compound 48/80 ,its CAS NO. is 4091-50-3,the synonyms is 4-Methoxy-n-methyl-benzeneethanamin ; p-Methoxy-n-methyl-phenethylamin ; [2-(4-Methoxy-phenyl)-ethyl]-methyl-amine ; p-Methoxy-n-methylphenethylamine ; n-Methyl 4-methoxyphenethylamine ; 2-(4-Methoxyphenyl)-n-methylethanamine ; 4-Methoxy-n-methylbenzeneethanamine ; n-Methyl-2-(4-methoxyphenyl)ethylamine .