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4773-96-0

Basic Information
CAS No.: 4773-96-0
Name: 9H-Xanthen-9-one, 2-b-D-glucopyranosyl-1,3,6,7-tetrahydroxy-
Article Data: 7
Cas Database
Molecular Structure:
Molecular Structure of 4773-96-0 (9H-Xanthen-9-one, 2-b-D-glucopyranosyl-1,3,6,7-tetrahydroxy-)
Formula: C19H18O11
Molecular Weight: 422.345
Synonyms: Mangiferin(6CI,7CI,8CI);1,3,6,7-Tetrahydroxyxanthone-C2-b-D-glucoside;2-C-b-D-Glucopyranosyl-1,3,6,7-tetrahydroxyxanthone;Alpizarin;Alpizarine;Aphloiol;Chinomin;Chinonin;Hedysarid;NSC 248870;Shamimin;
EINECS: 624-757-7
Density: 1.843 g/cm3
Melting Point: 269-270°C
Boiling Point: 842.7 °C at 760 mmHg
Flash Point: 303.6 °C
Solubility: N/A
Appearance: Light yellow powder
Hazard Symbols: VeryT+,DangerousN
Risk Codes: 28-36/37/38
Safety: 22-28-36/37-45-36-26
Transport Information: UN 3462 6.1/PG 1
PSA: 201.28000
LogP: -0.71650
Synthetic route
1239694-50-8

2-C-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-6-methoxy-1,3,7-trihydroxyxanthone

4773-96-0

mangiferin

Conditions
ConditionsYield
With boron tribromide In dichloromethane at 0 - 20℃;94%

1,6,7-trihydroxy-2-C-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-3-O-benzylxanthone

4773-96-0

mangiferin

Conditions
ConditionsYield
With 10% palladium hydroxide on charcoal; hydrogen In methanol at 20℃; under 760.051 Torr; for 48h;90%
92631-83-9

3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone

A

24699-16-9

4-β-D-glucopyranosyl-1,3-6,7-tetrahydroxy-9H-xanthen-9-one

B

4773-96-0

mangiferin

Conditions
ConditionsYield
With sodium carbonate; potassium hexacyanoferrate(III) In water for 1.5h; Ambient temperature;A 12 mg
B 7 mg
With sodium carbonate; potassium hexacyanoferrate(III) In water for 1.5h; Product distribution; Ambient temperature;A 12 mg
B 7 mg
92631-82-8

6′-O-galloyl-mangiferin

A

149-91-7

3,4,5-trihydroxybenzoic acid

B

4773-96-0

mangiferin

Conditions
ConditionsYield
In water at 37℃; tannase;

6′-O-acetyl mangiferin

4773-96-0

mangiferin

Conditions
ConditionsYield
With hydrogenchloride In water at 100℃; for 1h; Product distribution; other reagent (2N NaOH); other temp.;
92665-82-2

maclurin 3-C-(6''-O-p-hydroxybenzoyl)-β-D-glucoside

4773-96-0

mangiferin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 20 mg / H2O / 35 °C / hesperidinase
2: 7 mg / K3, Na2CO3 / H2O / 1.5 h / Ambient temperature
View Scheme
92631-85-1

maclurin 3-C-(2''-O-p-hydroxybenzoyl-6''-O-galloyl)-β-D-glucoside

4773-96-0

mangiferin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 40 mg / H2O / 37 °C / hesperidinase
2: 7 mg / K3, Na2CO3 / H2O / 1.5 h / Ambient temperature
View Scheme
92631-84-0

maclurin 3-C-(2''-O-galloyl-6''-O-p-hydroxybenzoyl)-β-D-glucoside

4773-96-0

mangiferin

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: H2O / 0.5 h / 37 °C / tannase
2: 20 mg / H2O / 35 °C / hesperidinase
3: 7 mg / K3, Na2CO3 / H2O / 1.5 h / Ambient temperature
View Scheme

C19H18O11*C42H70O35

A

4773-96-0

mangiferin

B

7585-39-9

β‐cyclodextrin

Conditions
ConditionsYield
In ethanol at 25℃; for 2h; Kinetics; Wavelength;
92631-83-9

3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone

4773-96-0

mangiferin

Conditions
ConditionsYield
With ethylenediaminetetraacetic acid; NADPH at 30℃; for 2h; Enzymatic reaction;
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2054-37-7
3542-72-1
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    4773-96-0

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    Name:Mangiferin Alias: Mango glycoside 、 Damuning English Name:Mangiferin CSA:4773-96-0 Molecular formula:C19H18O11 Molecular weight:422.35 Packaging Specification: 25kg/drum high purity 99%min stock Hubei DiBo Chemical Co., Ltd. was foun

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    4773-96-0

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  • Casno:

    4773-96-0

    Mangiferin

    Min.Order: 1 Kilogram

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  • Monad--Factory Supply Mango Extract / Mango Powder CAS 4773-96-0

  • Casno:

    4773-96-0

    Monad--Factory Supply Mango Extract / Mango Powder CAS 4773-96-0

    Min.Order: 1 Kilogram

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  • Mangiferin CAS 4773-96-0

  • Casno:

    4773-96-0

    MSDS/COA Download

    Mangiferin CAS 4773-96-0

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Chemistry

Molecular Formula: C19H18O11
Molar mass: 422.34 g/mol
EINECS: 223-096-8
Density: 1.843 g/cm3
Flash Point: 303.6 °C
Index of Refraction: 1.788
Boiling Point: 842.7 °C at 760 mmHg
Vapour Pressure: 3.67E-30 mmHg at 25°C
Melting point: 269-270°C
Product categories of Mangiferin (4773-96-0): Xanthones;The group of Danshen
Structure of Mangiferin (4773-96-0):

XLogP3-AA: -0.4
H-Bond Donor: 8
H-Bond Acceptor: 11
Systematic Name: 1,3,6,7-Tetrahydroxy-2-[(2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-yl]xanthen-9-one 
SMILES: O=C1c3c(O)c(c(O)cc3Oc2cc(O)c(O)cc12)[C@@H]4O[C@@H]([C@@H](O)[C@H](O)[C@H]4O)CO 
InChI: InChI=1/C19H18O11/c20-4-11-15(25)17(27)18(28)19(30-11)12-8(23)3-10-13(16(12)26)14(24)5-1-6(21)7(22)2-9(5)29-10/h1-3,11,15,17-23,25-28H,4H2/t11-,15-,17+,18-,19+/m1/s1 
InChIKey: AEDDIBAIWPIIBD-ZJKJAXBQBF 
Std. InChI: InChI=1S/C19H18O11/c20-4-11-15(25)17(27)18(28)19(30-11)12-8(23)3-10-13(16(12)26)14(24)5-1-6(21)7(22)2-9(5)29-10/h1-3,11,15,17-23,25-28H,4H2/t11-,15-,17+,18-,19+/m1/s1 
Std. InChIKey: AEDDIBAIWPIIBD-ZJKJAXBQSA-N

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 2300ug/kg (2.3mg/kg)   Problemi na Vutreshnata Meditsina. Problems of Internal Medicine. Vol. 8(2), Pg. 109, 1980.
rat LD50 intraperitoneal 365mg/kg (365mg/kg)   Journal of Pharmaceutical Sciences. Vol. 61, Pg. 1838, 1972.
 

Safety Profile

Hazard Codes: T+,Xi
Risk Statements:
28:  Very Toxic if swallowed
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
Safety Statements:
22:  Do not breathe dust
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

Specification

 Mangiferin (4773-96-0) is belong to the group of Anemarrhenae, and also can be called Alpizarin ; 9H-Xanthen-9-one, 2-.beta.-D-glucopyranosyl-1,3,6,7-tetrahydroxy- ; D-glucitol, 1,5-anhydro-1-C-(1,3,6,7-tetrahydroxy-9-oxo-9H-xanthen-2-yl)-, (1S)- ;and (1S)-1,5-Anhydro-1-(1,3,6,7-tetrahydroxy-9-oxo-9H-xanthen-2-yl)-D-glucitol .