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5345-47-1

Basic Information
CAS No.: 5345-47-1
Name: 2-Aminonicotinic acid
Article Data: 25
Molecular Structure:
Molecular Structure of 5345-47-1 (2-Aminonicotinic acid)
Formula: C6H6N2O2
Molecular Weight: 138.126
Synonyms: 3-Pyridinecarboxylic acid, 2-amino-;Nicotinic acid, 2-amino- (8CI);2-Amino-nicotinic acid;2-animonicotinic acid;2-aminopyridine-3-carboxylic acid;2-Amino-3-pyridinecarboxylic acid;Nicotinic acid, 2-amino-;
EINECS: 226-296-3
Density: 1.417 g/cm3
Melting Point: 295-297 °C (dec.)(lit.)
Boiling Point: 342.311 °C at 760 mmHg
Flash Point: 160.824 °C
Solubility: Soluble in water
Appearance: Off-white to light yellow crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 22-24/25-36/37/39-26
PSA: 76.21000
LogP: 0.94320
Synthetic route
2-Aminocarbonylnicotinic acid

2-Aminocarbonylnicotinic acid

5345-47-1

2-aminopyridin-3-carboxylic acid

Conditions
ConditionsYield
With bromine; sodium hydroxide at 5 - 85℃; for 2.5h;98.2%
23411-03-2

2-hydroxycarbamoyl-nicotinic acid

5345-47-1

2-aminopyridin-3-carboxylic acid

Conditions
ConditionsYield
In formamide at 130 - 150℃; for 20h;83.5%
88423-10-3

Pyridine-2,3-dicarboxylic acid bis-hydroxyamide

5345-47-1

2-aminopyridin-3-carboxylic acid

Conditions
ConditionsYield
In formamide at 130 - 150℃; for 20h;80%
2942-59-8

2-chloronicotinic acid

5345-47-1

2-aminopyridin-3-carboxylic acid

Conditions
ConditionsYield
With ammonium hydroxide; L-2-O-methyl-chiro-inositol; copper(II) acetate monohydrate In 1-methyl-pyrrolidin-2-one at 110℃; for 12h;72%
2942-59-8

2-chloronicotinic acid

A

609-71-2

2-hydroxy-3-carboxypyridine

B

5345-47-1

2-aminopyridin-3-carboxylic acid

Conditions
ConditionsYield
With ammonium hydroxide at 155℃; for 20h;A n/a
B 60%
24517-64-4

2-amino-3-pyridinecarbonitrile

5345-47-1

2-aminopyridin-3-carboxylic acid

Conditions
ConditionsYield
With hydrogenchloride at 175℃;
7463-30-1

N-(2-pyridyl-3-methyl)acetamide

5345-47-1

2-aminopyridin-3-carboxylic acid

Conditions
ConditionsYield
With potassium permanganate Erwaermen des Reaktionsprodukts mit wss. HCl;
861045-11-6

2-benzenesulfonylamino-nicotinic acid

5345-47-1

2-aminopyridin-3-carboxylic acid

Conditions
ConditionsYield
With hydrogenchloride at 175℃;
7664-93-9

sulfuric acid

3-hydroxy-1-nitroso-1H-pyrrolo[2,3-b]pyridine-2-carboxylic acid

5345-47-1

2-aminopyridin-3-carboxylic acid

1000681-77-5

6H-12H-dipyrido[2,3-b:2',3'-f][1,5]diazocine-5,11-dione

acids

acids

5345-47-1

2-aminopyridin-3-carboxylic acid

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Chemistry

IUPAC Name: 2-Aminopyridine-3-carboxylic acid
Synonyms of 2-Amino nicotinic acid (CAS NO.5345-47-1): 2-Amino-3-pyridinecarboxylic acid ; 3-Pyridinecarboxylic acid, 2-amino- ; Nicotinic acid, 2-amino- (8CI)
CAS NO: 5345-47-1
Molecular Formula: C6H6N2O2
Molecular Weight:138.12
Molecular Structure: 
EINECS: 226-296-3 
H bond acceptors: 4
H bond donors: 3
Freely Rotating Bonds: 1
Polar Surface Area: 42.43 Å2
Index of Refraction: 1.649
Molar Refractivity: 35.51 cm3
Molar Volume: 97.4 cm3
Surface Tension: 77.7 dyne/cm
Density: 1.417 g/cm3
Flash Point: 160.8 °C
Enthalpy of Vaporization: 61.85 kJ/mol
Boiling Point: 342.3 °C at 760 mmHg
Vapour Pressure: 2.92E-05 mmHg at 25°C 
Melting point: 295-297 °C (dec.)(lit.)
Water Solubility: soluble
Appearance: Off-white to light yellow crystalline powder
Product Categories of 2-Amino nicotinic acid (CAS NO.5345-47-1): AMINOACID;Amines;blocks;Carboxes;Pyridines;Amino Acids and Derivatives;Heterocycles;Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Carboxylic Acids;Pyridine;Pyridines derivates;Carboxylic Acids

Safety Profile

Safety Information about 2-Amino nicotinic acid (CAS NO.5345-47-1):
Hazard Codes:  Xi
The Risk Statements: 36/37/38
36/37/38: Irritating to eyes, respiratory system and skin 
The Safety Statements: 22-24/25-36/37/39-26
22: Do not breathe dust 
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
24/25: Avoid contact with skin and eyes  
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany:3
Hazard Note:Irritant
TSCA:T

Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.