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CAS No.: | 594-70-7 |
---|---|
Name: | 2-Methyl-2-nitropropane |
Article Data: | 59 |
Molecular Structure: | |
Formula: | C4H9 N O2 |
Molecular Weight: | 103.121 |
Synonyms: | 1,1-Dimethyl-1-nitroethane;2-Methyl-2-nitropropane; 2-Nitro-2-methylpropane; 2-Nitroisobutane; NSC 3651;Trimethylnitromethane |
EINECS: | 209-851-4 |
Density: | 0.95 |
Melting Point: | 24 ºC |
Boiling Point: | 126-127 ºC |
Flash Point: | 19 ºC |
Solubility: | insoluble |
Appearance: | clear colourless liquid after melting |
Hazard Symbols: | |
Risk Codes: | R11;R36/37/38 |
Safety: | Potentially explosive when heated. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS. |
Transport Information: | UN 1993 |
PSA: | 45.82000 |
LogP: | 1.58480 |
Conditions | Yield |
---|---|
With dihydrogen peroxide; Na12[WZn3(H2O)2(ZnW9O34)2] at 75℃; for 7h; | 100% |
With potassium permanganate In water 1.) 11 deg C -> room temperature, 8 h, 2.) 55 deg C, 18 h; | 78% |
With sodium permanganate In hexane at 69℃; for 24h; | 76% |
Conditions | Yield |
---|---|
With nitronium tetrafluoborate; silver carbonate In N,N-dimethyl acetamide at 90℃; for 12h; Inert atmosphere; Schlenk technique; regioselective reaction; | 79% |
Conditions | Yield |
---|---|
With iodosylbenzene; meso-tetraphenylporphyrin iron(III) chloride In dichloromethane at 0℃; | 75% |
tert-butylmercury chloride
2-Methyl-2-nitropropane
Conditions | Yield |
---|---|
With potassium nitrite; 18-crown-6 ether In various solvent(s) for 2h; Irradiation; | 70% |
With potassium nitrite; 18-crown-6 ether In dimethyl sulfoxide at 35℃; Irradiation; | 71 % Spectr. |
t-butylnitrite
1-(trimethylsilyl)-2-methyl-1-propenyl triflate
A
2,2,4,4-tetramethyl-1,3-cyclobutanedione
B
dimethylacetylene
C
2-Methyl-2-nitropropane
D
N-tert-butylmethacrylamide
E
N-tert-butylisobutyramide
F
N-tert-butyl-2-hydroxy-2-methylpropanamide
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In 1,2-dimethoxyethane at -20℃; for 0.0333333h; Mechanism; | A 8.3% B 70% C n/a D 6.4% E 8.3% F 5.3% |
t-butyl azide
2-Methyl-2-nitropropane
Conditions | Yield |
---|---|
With HOF* CH3CN In chloroform at -78℃; | 70% |
Conditions | Yield |
---|---|
With N-hydroxyphthalimide; air; Nitrogen dioxide In various solvent(s) at 70℃; under 1520.1 Torr; for 14h; | 61% |
With N-hydroxyphthalimide; air; Nitrogen dioxide In various solvent(s) at 70℃; under 760 Torr; for 14h; | 46% |
With nitric acid at 150℃; |
Conditions | Yield |
---|---|
In methanol at 20℃; Solvent; | A 0.5% B 60% |
sodium 2-nitropropane
1N-methyl-2,4,6-triphenylpyridinium tetrafluoroborate
A
2-Methyl-2-nitropropane
B
2,4,6-triphenylpyridine
Conditions | Yield |
---|---|
In dimethyl sulfoxide at 80℃; | A 57% B n/a |
In dimethyl sulfoxide at 25℃; for 2h; Rate constant; Kinetics; |
N-tert-Butylhydroxylamine
2-Methyl-2-nitropropane
Conditions | Yield |
---|---|
With potassium permanganate In water at 45 - 55℃; | 52% |
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IUPAC Name: 2-Methyl-2-nitro-propane
Synonyms: 1, 1-Dimethyl-1-nitroethane ; 1,1-Dimethyl-1-nitroethane ; 2-Methyl-2-nitropropane ; 2-Nitro-2-methylpropane
Product Categories: Nitro Compounds;Nitrogen Compounds;Organic Building Blocks Molecular Structure :
Molecular Formula of tert-Nitrobutane (CAS NO.594-70-7) : C4H9NO2
Molecular Weight of tert-Nitrobutane (CAS NO.594-70-7) : 103.12
Molecular Structure of tert-Nitrobutane (CAS NO.594-70-7) :
CAS NO: 594-70-7
EINECS: 209-851-4
Index of Refraction: 1.409
Surface Tension: 27 dyne/cm
Density: 0.96 g/cm3
Flash Point: 19.4 °C
Enthalpy of Vaporization: 36.37 kJ/mol
Boiling Point: 125.9 °C at 760 mmHg
Vapour Pressure: 11.9 mmHg at 25°C
Melting point 24 ºC
Storage temp: Flammables area
Water solubility: insoluble
Appearance:clear colourless liquid after melting
Potentially explosive when heated. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS.
Hazard Codes F,Xi
Risk Statements 11-36/37/38
R11:Highly flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 16-26-36/37/39
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR UN 1993 3/PG 2
WGK Germany 3
HazardClass 4.1
PackingGroup II