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607-35-2

Basic Information
CAS No.: 607-35-2
Name: 8-Nitroquinoline
Article Data: 37
Molecular Structure:
Molecular Structure of 607-35-2 (8-Nitroquinoline)
Formula: C9H6N2O2
Molecular Weight: 174.159
Synonyms: 8-Nitroqunioline;quinoline, 8-nitro-;5-20-07-00327 (Beilstein Handbook Reference);
EINECS: 210-135-9
Density: 1.354 g/cm3
Melting Point: 89-91 °C(lit.)
Boiling Point: 323.1 °C at 760 mmHg
Flash Point: 149.2 °C
Solubility: Soluble in ethanol, ethyl ether and benzene, slightly soluble in cold water.
Appearance: white to light yellow crystal powder
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 20/21/22-36/37/38-40-68
Safety: 26-27-36/37/39-36
PSA: 58.71000
LogP: 2.66620
Synthetic route
86-58-8

8-quinolinylboronic acid

607-35-2

8-nitroquinoline

Conditions
ConditionsYield
With N-Bromosuccinimide; [bis(trifluoroacetoxy)iodo]benzene; sodium nitrite In acetonitrile at 20℃; for 3h; regioselective reaction;84%
88-74-4

2-nitro-aniline

56-81-5

glycerol

607-35-2

8-nitroquinoline

Conditions
ConditionsYield
Stage #1: 2-nitro-aniline; glycerol With sodium iodide at 20℃; for 0.0833333h;
Stage #2: With sulfuric acid for 0.166667h; Cooling with ice;
Stage #3: at 140℃; for 2h;
81%
Stage #1: 2-nitro-aniline With sulfuric acid at 70 - 80℃;
Stage #2: glycerol at 70 - 80℃; Temperature; Further stages;
79%
With sulfuric acid In water for 4h; Reflux;72%
39217-93-1

8-nitro-1,2,3,4-tetrahydroquinoline

607-35-2

8-nitroquinoline

Conditions
ConditionsYield
With iodine; oxygen In 1,2-dichloro-benzene; toluene at 160℃; for 30h;77%
88-74-4

2-nitro-aniline

127-68-4

sodium 3-nitrobenzenesulfonate

607-35-2

8-nitroquinoline

Conditions
ConditionsYield
With sulfuric acid In water; glycerol Reflux;44%
91-22-5

quinoline

A

607-35-2

8-nitroquinoline

B

607-34-1

5-nitroquinoline

Conditions
ConditionsYield
Stage #1: quinoline With sulfuric acid; nitric acid at 20℃; for 1h;
Stage #2: With sodium carbonate In water
A 34%
B 38%
With sulfuric acid; nitric acid In water at 0 - 20℃; for 1h;A 35%
B n/a
With sulfuric acid; nitric acid
91-22-5

quinoline

607-35-2

8-nitroquinoline

Conditions
ConditionsYield
durch Nitrieren;

2-methoxy-3-nitro-cinnamaldehyde

607-35-2

8-nitroquinoline

Conditions
ConditionsYield
With ammonia at 130 - 140℃; im Rohr;
51741-75-4

1-methyl-8-nitro-quinolinium; iodide

A

607-35-2

8-nitroquinoline

B

74-88-4

methyl iodide

88-74-4

2-nitro-aniline

107-02-8

acrolein

607-35-2

8-nitroquinoline

Conditions
ConditionsYield
With phosphoric acid; water; orthoarsenic acid
With hydrogenchloride; phosphoric acid In water at 80 - 95℃; for 7h;
85-48-3

8-quinolinesulfonic acid

607-35-2

8-nitroquinoline

Conditions
ConditionsYield
With nitric acid at 160℃; im Rohr;
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    Product Name 8-Nitroquinoline CAS Registry Number 607-35-2 Molecular Structure [ Structure image courtesy of chemBlink ]

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    8-Nitroquinoline Chemical Properties Melting point 89-91 °C (lit.) Boiling point 305.12°C (rough estimate) density 1.2190 (estimate) refractive index 1.6820 (rough estimate) pka 1.20±0.17(Predicted) color Monocli

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    Name 8-Nitroquinoline Molecular Structure Molecular Formula C9H6N2O2 Molecular Weight 174

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Chemistry

The molecular formula of 8-Nitroquinoline(607-35-2) is C9H6N2O2 and its formula weight is 174.16.
8-Nitroquinoline(607-35-2) has a melting point of  89-91 °C(lit.).
The chemical synonyms of 8-Nitroquinoline(607-35-2) are 8-nitro-quinolin;Quinoline, 8-nitro-;Quinoline,8-nitro-;AKOS 214-03;8-NITROQUINOLINE;8-Nitroqunioline;8-Nitroquinoline,98%;8-Nitrochinolin
The molecular structure of 8-Nitroquinoline(607-35-2):

Toxicity Data With Reference

1.   

mmo-sat 50 µg/plate

   MUREAV    Mutation Research. 39 (1977),285.
2.   

mma-sat 100 nmol/plate

   MUREAV    Mutation Research. 58 (1978),11.
3.   

dnr-sat 350 µg/disc

   MUREAV    Mutation Research. 39 (1977),285.
4.   

orl-rat TD:36,400 mg/kg/2Y-C:CAR,REP

   CALEDQ    Cancer Letters (Shannon, Ireland). 14 (1981),115.
5.   

ipr-mus LDLo:125 mg/kg

   CBCCT*    “Summary Tables of Biological Tests“ National Research Council Chemical-Biological Coordination Center. 6 (1954),149.

Consensus Reports

EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also 2-NITROQUINOLINE; 5-NITROQUINOLINE; 6-NITROQUINOLINE; 4-NITROQUINOLINE-N-OXIDE.
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38-40-68
Safety Statements  26-27-36/37/39-36
WGK Germany  3
RTECS  VC1925000
Hazard Note  Harmful/Irritant

Specification

Chemical Stability: Not available 
Conditions to Avoid: Incompatible materials. 
Incompatibilities with Other Materials Strong oxidizing agents, strong acids, strong bases. 
Hazardous Decomposition Products Nitrogen oxides, carbon monoxide, carbon dioxide. 
Hazardous Polymerization Has not been reported.