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Basic Information
CAS No.: 6074-84-6
Name: TANTALUM ETHOXIDE
Molecular Structure:
Molecular Structure of 6074-84-6 (TANTALUM ETHOXIDE)
Formula: C2H6 O . 1/5 Ta
Molecular Weight: 406.253
Synonyms: Ethanol,tantalum(5+) salt (9CI); Ethyl alcohol, tantalum(5+) salt (8CI); Tantalumethoxide (6CI,7CI); Ditantalum decaethoxide; Pentaethoxytantalum; Pentaethyltantalate; Tantalum ethylate; Tantalum pentaethoxide; Tantalum pentaethylate;Tantalum pentethoxide; Tantalum(5+) ethoxide; Tantalum(V) ethoxide
EINECS: 228-010-2
Density: 1.566
Melting Point: 21 °C(lit.)
Boiling Point: 155 °C0.01 mm Hg(lit.)
Flash Point: 87 °F
Solubility: Decomposes in water. Soluble in organic solvents.
Hazard Symbols:
Risk Codes: R10;R34   
Safety: 16-26-36/37/39-45
Transport Information: UN 2920
PSA: 46.15000
LogP: 2.43600
Synthetic route

Ta(5+)*N(C3H7)(2-)*3N(C3H7)2(1-)=Ta(NC3H7){N(C3H7)2}3

6074-84-6

tantalum(V) ethoxide

Conditions
ConditionsYield
With ethanol In benzene reaction with ethanol in benzene at ambient temp.;;100%
With ethanol In benzene reaction with ethanol in benzene at ambient temp.;;100%

tantalum(V) oxide

6074-84-6

tantalum(V) ethoxide

Conditions
ConditionsYield
In gas

tantalum

64-17-5

ethanol

lithium chloride

A

LiTa9H(μ3-O)4(μ-O)9(μ-OEt)6(OEt)15(EtOH)

B

6074-84-6

tantalum(V) ethoxide

Conditions
ConditionsYield
In ethanol Electrolysis; anodic dissolution of the metal in anhyd. alcohol in presence of LiCl assupporting electrolite; EtOH was evapd. from resulting electrolyte, the Ta(OEt)5 was extd. from residue with hexane, on prolonged storage of liquid crude Ta(OEt)5 the second Ta-Li complex crystllized in minor yield; elem. anal.;

tantalum

64-17-5

ethanol

6074-84-6

tantalum(V) ethoxide

Conditions
ConditionsYield
With LiCl In ethanol Electrochem. Process; dry Ar atmosphere; anodic oxidation of Ta in LiCl2 soln.; distillation;
7721-01-9

tantalum pentachloride

6074-84-6

tantalum(V) ethoxide

Conditions
ConditionsYield
With ethanol; ammonia In benzene byproducts: NH4Cl; TaCl5 was treated with ethanol in benzene in presence of excess NH3, the NH4Cl was separated, the filtrate was evaporated under reduced pressure;; distillation under reduced pressure;;
With ethanol; NH3 In benzene byproducts: NH4Cl; TaCl5 was treated with ethanol in benzene in presence of excess NH3, the NH4Cl was separated, the filtrate was evaporated under reduced pressure;; distillation under reduced pressure;;
3385-94-2

hexamethyldisilathiane

110-18-9

N,N,N,N,-tetramethylethylenediamine

865-34-9

lithium methanolate

6074-84-6

tantalum(V) ethoxide

3Li(1+)*TaS4(3-)*2(CH3)2NCH2CH2N(CH3)2=Li3{TaS4}*2(CH3)2NCH2CH2N(CH3)2

Conditions
ConditionsYield
In diethyl ether; acetonitrile byproducts: Me3SiOEt, Me3SiOMe; under N2; a soln. of Ta(OEt)5 in ether added to a soln. of LiOMe and (Me3Si)2S in CH3CN; mixt. stirred at room temp.; TMEDA added;; elem. anal.;;80%
188612-43-3, 47904-22-3

1,3,5,7,9,11,14-heptacyclohexyltricyclo[7.3.3.1(5,11)]heptasiloxaneendo-3,7,14-triol

6074-84-6

tantalum(V) ethoxide

[Cy7Si7O12Ta(OEt)(μ-OEt)]2

Conditions
ConditionsYield
In toluene for 26h; Reflux;80%
6074-84-6

tantalum(V) ethoxide

603-33-8

triphenylbismuthane

69-72-7

salicylic acid

BiTa4(μ-O)4(sal)4(Hsal)3(Oi-Pr)4

Conditions
ConditionsYield
With Mg(OOCCH3)2 In toluene under Ar; suspn. of Bi deriv. and salicylic acid in PhMe refluxed for 1 h, concd. in vac., redissolved in 2-propanol, added Mg salt, added dropwise Ta ethoxide, left at room temp. for 14 d; filtered, redissolved in CH2Cl2, filtered (Celite), added hexane; elem. anal.;62%
In toluene under Ar; react. of Bi deriv. with Ta ethoxide and ligand;0%
With NaOOCCH3 In toluene under Ar; react. of Bi deriv. with Ta ethoxide and ligand;0%
6074-84-6

tantalum(V) ethoxide

603-33-8

triphenylbismuthane

69-72-7

salicylic acid

Bi2Ta2(μ-O)(sal)4(Hsal)4(OEt)2

Conditions
ConditionsYield
In toluene under Ar; suspn. of Bi deriv. and salicylic acid in PhMe refluxed for 1 h, cooled to room temp., added dropwise Ta ethoxide, stirred at room temp. for 24 h; concd. in vac., washed (Et2O), dried in vac., recrystd. from CH2Cl2/hexane; elem. anal.;58%
1104-93-4

1,1,3,3-tetraphenyldisiloxane-1,3-diol

6074-84-6

tantalum(V) ethoxide

[{μ-(Ph2OSiO)2O}Ta(OEt)2(μ-OEt)]2

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 48h;34%
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Chemistry

Molecule structure of Tantalum(V) ethoxide (CAS NO.6074-84-6):

IUPAC Name: Ethanolate; tantalum(5+) 
Molecular Weight: 406.2504 [g/mol]
Molecular Formula: C10H25O5Ta 
Density: 1.566 g/cm3 
Boiling point: 155 ºC
Refractive index: 1.487 
Melting Point: 21 °C(lit.)
Flash Point: 87 °F
Storage Temp.: 2-8 °C
Sensitive: moisture sensitive/air sensitive
H-Bond Acceptor: 5 
Exact Mass: 406.118195
MonoIsotopic Mass: 406.118195
Topological Polar Surface Area: 115
Heavy Atom Count: 16
Complexity: 2.8
Canonical SMILES: CC[O-].CC[O-].CC[O-].CC[O-].CC[O-].[Ta+5]
InChI: InChI=1S/5C2H5O.Ta/c5*1-2-3;/h5*2H2,1H3;/q5*-1;+5
InChIKey: HSXKFDGTKKAEHL-UHFFFAOYSA-N
EINECS: 228-010-2
Product Categories of Tantalum(V) ethoxide (CAS NO.6074-84-6): Catalysis and Inorganic Chemistry; Chemical Synthesis; Solution Deposition Precursors; Tantalum; TantalumMicro/Nanoelectronics

Safety Profile

Hazard Codes: CorrosiveC, FlammableF
Risk Statements: 10-34 
R10:Flammable. 
R34:Causes burns.
Safety Statements: 16-26-36/37/39-45 
S16:Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2920 8/PG 2
WGK Germany: 3
F: 3-8-10-21
TSCA: No
HazardClass: 3
PackingGroup: III

Specification

 Tantalum(V) ethoxide (CAS NO.6074-84-6) is also named as Ethanol, tantalum(5+) salt ; Ethanol, tantalum(5+) salt (5:1) ; Tantalum(5+) ethanolate ; Tantalum ethylate ; Tantalum pentethoxide ; Pentaethoxytantalum ; Ethanol,tantalum(5+) salt (9CI) ; Ethyl alcohol, tantalum(5+) salt (8CI) ; Tantalumethoxide (6CI,7CI) ; Ditantalum decaethoxide ; Pentaethyltantalate ; Tantalum pentaethoxide ; Tantalum pentaethylate ; Tantalum(5+) ethoxide ; Tantalum(V) ethoxide . Tantalum(V) ethoxide (CAS NO.6074-84-6) is clear colorless to almost colorless liquid.