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CAS No.: | 616-34-2 |
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Name: | methyl glycinate |
Article Data: | 80 |
Molecular Structure: | |
Formula: | C3H7 N O2 |
Molecular Weight: | 89.0941 |
Synonyms: | (Methoxycarbonyl)methylamine;Aminoacetate methyl ester; Aminoacetic acid methyl ester; Glycine O-methylester; Methyl 2-aminoacetate; Methyl aminoacetate; Methyl glycinate; Methylglycine |
Density: | 1.045±0.06 g/cm3(Predicted) |
Melting Point: | 196-197 °C (decomp) |
Boiling Point: | 66.5 °C |
PSA: | 52.32000 |
LogP: | -0.18160 |
Conditions | Yield |
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With chloro-trimethyl-silane at 0 - 4℃; for 24h; Inert atmosphere; | 100% |
With thionyl chloride at 0 - 65℃; for 4.25h; | 100% |
With thionyl chloride at 0 - 65℃; for 4.25h; | 100% |
N-(tert-butoxycarbonyl)glycine methyl ester
methoxycarbonylmethylamine
Conditions | Yield |
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With trifluoroacetic acid In dichloromethane at 20℃; for 0.5h; Inert atmosphere; | 100% |
With methanol; tetradecanoyl chloride; sodium iodide In acetonitrile at 25℃; for 0.333333h; |
Conditions | Yield |
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With hydrogen for 0.583333h; | 98% |
With samarium; cobalt(II) chloride In tetrahydrofuran at 40℃; for 1h; Reduction; | 79% |
With samarium; nickel dichloride In tetrahydrofuran at 40℃; for 3h; | 76% |
Conditions | Yield |
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With ammonia In diethyl ether for 2h; | 90% |
With ammonia | 85% |
With anion exchange resin In dichloromethane for 0.0833333h; | 83% |
Conditions | Yield |
---|---|
With ammonium cerium(IV) nitrate Heating; | 80% |
Conditions | Yield |
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With samarium; iodine for 6h; Ambient temperature; | 74% |
L-tryptophan methyl ester
A
Indole-3-carboxaldehyde
B
methoxycarbonylmethylamine
Conditions | Yield |
---|---|
With hydrogenchloride; pyrimido<5,4-g>pteridine N-oxide derivative In acetonitrile for 6h; Mechanism; Ambient temperature; Irradiation; analogeous reaction of 5 other tryptophan derivatives; | A 72% B n/a |
Conditions | Yield |
---|---|
With ammonia; water Erwaermen des Reaktionsprodukts mit methanol.HCl; das Hydrochlorid entsteht; | |
With ammonia; water Erwaermen des Reaktionsprodukts mit methanol.HCl; Gewinnung aus dem entstehenden Hydrochlorid mit Hilfe von Ag2O in wenig H2O enthaltendem Aether; |
Conditions | Yield |
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With trans- 2.) CH2Cl2, 0.2 M NBu4*BF4, electrolysis; Yield given. Multistep reaction; |
N-(2-methyl-3-oxoprop-1-enyl)glycine methyl ester
A
methylmalonaldehyde enol tautomer
B
methoxycarbonylmethylamine
Conditions | Yield |
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With water Rate constant; Equilibrium constant; Ambient temperature; acetate buffer (pH 4.2); enaminal hydrolysis; stereochemistry and kinetics of formation of enaminals from reactions of malondialdehydes with various amino acids; |